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Doctoral Dissertations

University of Massachusetts Amherst

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Full-Text Articles in Probability

Characterization Of The Anomalous Ph Of Aqueous Nanoemulsions, Kieran P. Ramos Oct 2019

Characterization Of The Anomalous Ph Of Aqueous Nanoemulsions, Kieran P. Ramos

Doctoral Dissertations

Aqueous water-in-oil nanoemulsions have emerged as a versatile tool for use in microfluidics, drug delivery, single-molecule measurements, and other research. Nanoemulsions are often prepared with perfluorocarbons which are remarkably biocompatbile due to their stability, low surface tension, lipophobicity, and hydrophobicity. Therefore it is often assumed that droplet contents are unperturbed by the perfluorinated surface. However, in microemulsions, which are similar to nanoemulsions, it is known that either the pH of the aqueous phase or the ionization constants of encapsulated molecules are different from bulk solution. There is also recent evidence of low pH in perfluorinated aqueous nanoemulsions. The current underlying …


Function And Dissipation In Finite State Automata - From Computing To Intelligence And Back, Natesh Ganesh Oct 2019

Function And Dissipation In Finite State Automata - From Computing To Intelligence And Back, Natesh Ganesh

Doctoral Dissertations

Society has benefited from the technological revolution and the tremendous growth in computing powered by Moore's law. However, we are fast approaching the ultimate physical limits in terms of both device sizes and the associated energy dissipation. It is important to characterize these limits in a physically grounded and implementation-agnostic manner, in order to capture the fundamental energy dissipation costs associated with performing computing operations with classical information in nano-scale quantum systems. It is also necessary to identify and understand the effect of quantum in-distinguishability, noise, and device variability on these dissipation limits. Identifying these parameters is crucial to designing …


Allocative Poisson Factorization For Computational Social Science, Aaron Schein Jul 2019

Allocative Poisson Factorization For Computational Social Science, Aaron Schein

Doctoral Dissertations

Social science data often comes in the form of high-dimensional discrete data such as categorical survey responses, social interaction records, or text. These data sets exhibit high degrees of sparsity, missingness, overdispersion, and burstiness, all of which present challenges to traditional statistical modeling techniques. The framework of Poisson factorization (PF) has emerged in recent years as a natural way to model high-dimensional discrete data sets. This framework assumes that each observed count in a data set is a Poisson random variable $y ~ Pois(\mu)$ whose rate parameter $\mu$ is a function of shared model parameters. This thesis examines a specific …


Asymptotic Behavior Of The Random Logistic Model And Of Parallel Bayesian Logspline Density Estimators, Konstandinos Kotsiopoulos Jul 2018

Asymptotic Behavior Of The Random Logistic Model And Of Parallel Bayesian Logspline Density Estimators, Konstandinos Kotsiopoulos

Doctoral Dissertations

This dissertation is comprised of two separate projects. The first concerns a Markov chain called the Random Logistic Model. For r in (0,4] and x in [0,1] the logistic map fr(x) = rx(1 - x) defines, for positive integer t, the dynamical system xr(t + 1) = f(xr(t)) on [0,1], where xr(1) = x. The interplay between this dynamical system and the Markov chain xr,N(t) defined by perturbing the logistic map by truncated Gaussian noise scaled by N-1/2, where N -> infinity, is studied. A natural question is …


Inference In Networking Systems With Designed Measurements, Chang Liu Mar 2017

Inference In Networking Systems With Designed Measurements, Chang Liu

Doctoral Dissertations

Networking systems consist of network infrastructures and the end-hosts have been essential in supporting our daily communication, delivering huge amount of content and large number of services, and providing large scale distributed computing. To monitor and optimize the performance of such networking systems, or to provide flexible functionalities for the applications running on top of them, it is important to know the internal metrics of the networking systems such as link loss rates or path delays. The internal metrics are often not directly available due to the scale and complexity of the networking systems. This motivates the techniques of inference …


Stochastic Network Design: Models And Scalable Algorithms, Xiaojian Wu Nov 2016

Stochastic Network Design: Models And Scalable Algorithms, Xiaojian Wu

Doctoral Dissertations

Many natural and social phenomena occur in networks. Examples include the spread of information, ideas, and opinions through a social network, the propagation of an infectious disease among people, and the spread of species within an interconnected habitat network. The ability to modify a phenomenon towards some desired outcomes has widely recognized benefits to our society and the economy. The outcome of a phenomenon is largely determined by the topology or properties of its underlying network. A decision maker can take management actions to modify a network and, therefore, change the outcome of the phenomenon. A management action is an …


Wind Power Capacity Value Metrics And Variability: A Study In New England, Frederick W. Letson Nov 2015

Wind Power Capacity Value Metrics And Variability: A Study In New England, Frederick W. Letson

Doctoral Dissertations

Capacity value is the contribution of a power plant to the ability of the power system to meet high demand. As wind power penetration in New England, and worldwide, increases so does the importance of identifying the capacity contribution made by wind power plants. It is critical to accurately characterize the capacity value of these wind power plants and the variability of the capacity value over the long term. This is important in order to avoid the cost of keeping extra power plants operational while still being able to cover the demand for power reliably. This capacity value calculation is …