Statistical, Nonlinear, and Soft Matter Physics Commons^™

Quantifying Confinement Of Chain Dynamics For Chains Tethered To Self-Assembling Crystalline Nanodomains Using Neutron Spin Echo Spectroscopy, Logan Benninghoff

Williams Honors College, Honors Research Projects

Polyisobutylene (PIB) rubbers can be reinforced with crystalline β-alanine nanodomains. Progress has been made in understanding the morphology of the nanodomains, but the dynamics of the PIB molecule chains attached to the surface of the nanodomains and in the matrix are not well understood. It is possible to observe the motion of these PIB chains using Neutron Spin Echo (NSE) experiments, since the experimental technique can give data for smaller timescales. Data collection for reinforced rubber samples has already been performed, but the data still need to be analyzed. For my honors project I will be comparing the data to …

Structural Dynamics And Charge Transport In Room Temperature Ionic Liquids, Philip James Griffin

Doctoral Dissertations

Room temperature ionic liquids are an important class of materials due to their chemical tunability and numerous advantageous physicochemical properties. As a result, ionic liquids are currently being investigated for use in a wide array of chemical and electrochemical applications. Despite their great potential, however, the relationship between the chemical structure and physicochemical properties of ionic liquids is not well understood.

To this end, this dissertation presents experimental studies of the reorientational structural dynamics and charge transport properties of a variety of room temperature ionic liquids using quasielastic light scattering spectroscopy and broadband dielectric spectroscopy.

Studies of a series of …