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Theses and Dissertations--Physics and Astronomy

Organic semiconductors

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Full-Text Articles in Condensed Matter Physics

Transverse And Longitudinal Thermal Diffusivity Measurements Of Polymer And Small Molecule Organic Semiconductors With Different Techniques, Maryam Shahi Jan 2020

Transverse And Longitudinal Thermal Diffusivity Measurements Of Polymer And Small Molecule Organic Semiconductors With Different Techniques, Maryam Shahi

Theses and Dissertations--Physics and Astronomy

The main thrust of this research was to develop new probes to measure thermal conductivities (κ) of small-molecule crystals, as well as polymer blends of organic semiconductors, both to screen these for possible applications, e.g. as thermoelectric power generators, and to gain an understanding of thermal transport in them. Emphasis has been on the crystals of “TIPS pentacene” [TIPS = 6,13 bis(triisopropylsilylethynyl), and free-standing films of PEDOT:PSS [poly(3,4-ethylenedioxythiophene) polystyrene sulfonate] for different electrochemical and thermoelectric applications. Separate techniques were used for in-plane and transverse thermal conductivities in which 𝜅𝜅 is determined indirectly from measurements of the thermal diffusivity (D ≡ …


Thermal Conductivities Of Organic Semiconductors, Yulong Yao Jan 2017

Thermal Conductivities Of Organic Semiconductors, Yulong Yao

Theses and Dissertations--Physics and Astronomy

Organic semiconductors have gained a lot of interest due to their ease of processing, low-cost and inherent mechanical flexibility. Although most of the research has been on their electronic and optical properties, knowledge of the thermal properties is important in the design of electronic devices as well. Our group has used ac-calorimetric techniques to measure both in-plane and transverse thermal conductivities of a variety of organic semiconductors including small-molecule crystals and polymer blends. For layered crystals composed of molecules with planar backbones and silylethynyl (or germylethynyl) sidegroups projecting between the layers, very high interplanar thermal conductivities have been observed, presumably …


Voltage Modulated Infrared Reflectance Study Of Soluble Organic Semiconductors In Thin Film Transistors, Emily Geraldine Bittle Jan 2013

Voltage Modulated Infrared Reflectance Study Of Soluble Organic Semiconductors In Thin Film Transistors, Emily Geraldine Bittle

Theses and Dissertations--Physics and Astronomy

Soluble organic semiconductors have attracted interest due to their potential in making flexible and cheap electronics. Though their use is being implemented in electronics today, the conduction mechanism is still under investigation. In order to study the charge transport, this study examines the position, voltage, and frequency dependence of charge induced changes in far infrared absorption in soluble organic semiconductors in thin-film transistor structures. Measurements are compared to a simple model of a one-dimensional conductor which gives insight into the charge distribution and timing in devices. Main results of the study are dynamic measurements of charge taken by varying the …