Condensed Matter Physics Commons^™

A Study Of Magnetism And Possible Mixed-State Superconductivity In Phosphorus-Doped Graphene, Julian E. Gil Pinzon

FIU Electronic Theses and Dissertations

Evidence of superconducting vortices, and consequently mixed-state superconductivity, has been observed in phosphorus-doped graphene at temperatures as high as 260 K. The evidence includes transport measurements in the form of resistance versus temperature curves, and magnetic measurements in the form of susceptibility and magnetic Nernst effect measurements. The drops in resistance, periodic steps in resistance, the appearance of Nernst peaks and hysteresis all point to phosphorus-doped graphene having a broad resistive region due to flux flow as well as a Berezinskii-Kosterlitz-Thouless (BKT) transition at lower temperatures.

The observation of irreversible behavior in phosphorus-doped graphene under the influence of a thermal …

Electron Field Emission And Electrochemical Lithiation Properties Of Vertically Aligned Carbon Nanotube Arrays Grown Directly On Metal Substrates, Arun Thapa

FIU Electronic Theses and Dissertations

Carbon nanotubes (CNTs) represent one of the critical inventions that have triggered new science and technology in many fields because of their distinctive mechanical, thermal, electrical, electrochemical, and optical properties. Despite the tremendous potential of CNTs, challenges in synthesizing and processing continue to hinder their applications. This dissertation is devoted to synthesizing vertically aligned CNT arrays on metal substrates via plasma-enhanced chemical vapor deposition and the study of their electron field emission (FE) and electrochemical lithiation properties.

Vertically aligned CNTs (VACNTs) are promising electron field emitters for vacuum micro/nano-electronics. Improved control over the morphology and a successful direct-growth of the …

Organic-Inorganic Halide Perovskite Nanocrystals And Solar Cells, Rui Guo

FIU Electronic Theses and Dissertations

A great challenge facing humanity in the 21^st century is finding inexhaustible and inexpensive energy sources to power the planet. Renewable energies are the best solutions because of their abundance, diversity, and pollution-free emission. Solar energy is the cleanest and most abundant renewable energy source available. In the continuing quest for efficient and low-cost solar cells, perovskite solar cells (PSCs) have emerged as a potential replacement for silicon solar cells. Since 2009, the record efficiencies of PSCs have been skyrocketing from 3.8 % to 25.2 % and are now approaching the theoretical limit. Along with the three-dimensional perovskites used …

Multifunctional Nanopipette For Single Nanoparticles And Proteins Analysis, Popular Pandey

FIU Electronic Theses and Dissertations

Complex biological processes occur in the nanoscale (1-100 nm) regime. ‘DNA’ which is just 2 nm in dimension is a fundamental building block of all life. ‘Hemoglobin’, a blood protein that transports oxygen throughout our body is only 5 nm in diameter. Importantly, the structure, composition, and dynamics of these nanoscale entities determine their biological function. A slight alteration in the structure and composition can lead to the malfunction of the protein which is key to various diseases including cancer. Therefore, the single-molecule measurement approach is essential to characterize both the average properties and the rare …

Multimode Analysis Of Nanoscale Biomolecular Interactions, Purushottam Babu Tiwari

FIU Electronic Theses and Dissertations

Biomolecular interactions, including protein-protein, protein-DNA, and protein-ligand interactions, are of special importance in all biological systems. These interactions may occer during the loading of biomolecules to interfaces, the translocation of biomolecules through transmembrane protein pores, and the movement of biomolecules in a crowded intracellular environment. The molecular interaction of a protein with its binding partners is crucial in fundamental biological processes such as electron transfer, intracellular signal transmission and regulation, neuroprotective mechanisms, and regulation of DNA topology. In this dissertation, a customized surface plasmon resonance (SPR) has been optimized and new theoretical and label free experimental methods with related analytical …

Synthesis And Characterization Of Thermoelectric Nanomaterials, Kamal Kadel

FIU Electronic Theses and Dissertations

As existing energy sources have been depleting at a fast pace, thermoelectric (TE) materials have received much attention in recent years because of their role in clean energy generation and conversion. Thermoelectric materials hold promise in terrestrial applications such as waste heat recovery. Bismuth selenide (Bi₂Se₃), lead telluride (PbTe), skutterudites CoSb₃, and Bi-Sb alloys are among the widely investigated thermoelectric materials.

Synthesis of above mentioned thermoelectric materials in nanostructured form and their characterization were investigated. Highly crystalline Bi₂Se₃, undoped and indium (In) doped PbTe, unfilled and ytterbium (Yb) filled CoSb …

Synthesis And Electron Emission Properties Of Aligned Carbon Nanotube Arrays, Suman Neupane

FIU Electronic Theses and Dissertations

Carbon nanotubes (CNTs) have become one of the most interesting allotropes of carbon due to their intriguing mechanical, electrical, thermal and optical properties. The synthesis and electron emission properties of CNT arrays have been investigated in this work. Vertically aligned CNTs of different densities were synthesized on copper substrate with catalyst dots patterned by nanosphere lithography. The CNTs synthesized with catalyst dots patterned by spheres of 500 nm diameter exhibited the best electron emission properties with the lowest turn-on/threshold electric fields and the highest field enhancement factor. Furthermore, CNTs were treated with NH₃ plasma for various durations and the …

Mechanical And Electrical Properties Of Single-Walled Carbon Nanotubes Synthesized By Chemical Vapor Deposition, Yuehai Yang

FIU Electronic Theses and Dissertations

Despite the tremendous application potentials of carbon nanotubes (CNTs) proposed by researchers in the last two decades, efficient experimental techniques and methods are still in need for controllable production of CNTs in large scale, and for conclusive characterizations of their properties in order to apply CNTs in high accuracy engineering. In this dissertation, horizontally well-aligned high quality single-walled carbon nanotubes (SWCNTs) have been successfully synthesized on St-cut quartz substrate by chemical vapor deposition (CVD). Effective radial moduli (E_radial) of these straight SWCNTs have been measured by using well-calibrated tapping mode and contact mode atomic force microscopy (AFM). It …