Condensed Matter Physics Commons^™

Effects Of High Pressure On Photochemical Reactivity Of Organic Molecular Materials Probed By Vibrational Spectroscopy, Jiwen Guan

Electronic Thesis and Dissertation Repository

Chemical transformations of molecular materials induced by high pressure and light radiation exhibit novel and intriguing aspects that have attracted much attention in recent years. Particularly, under the two stimuli, entire transformations of molecular species can be realized in condensed phases without employing additional chemical constraints, e.g., the need of solvents, catalysts or radical initiators. This new synthetic approach in chemistry therefore satisfies increasing need for production methods with reduced environmental impacts. Motivated by these promises, my Ph. D thesis focuses on this state-of-the-art branch of high-pressure photochemistry. Specifically, high pressure is employed to create the necessary reaction conditions to …

Emergent Phenomena In Quantum Critical Systems, Kun Chen

Doctoral Dissertations

A quantum critical point (QCP) is a point in the phase diagram of quantum matter where a continuous phase transition takes place at zero temperature. Low-dimensional quantum critical systems are strongly correlated, therefore hosting nontrivial emergent phenomena. In this thesis, we first address two decades-old problems on quantum critical dynamics. We then reveal two novel emergent phenomena of quantum critical impurity problems. In the first part of the thesis, we address the linear response dynamics of the $(2+1)$-dimensional $O(2)$ quantum critical universality class, which can be realized in the ultracold bosonic system near the superfluid (SF) to Mott insulator (MI) …

Simulating The Electrical Properties Of Random Carbon Nanotube Networks Using A Simple Model Based On Percolation Theory, Roberto Abril Valenzuela

Physics

Carbon nanotubes (CNTs) have been subject to extensive research towards their possible applications in the world of nanoelectronics. The interest in carbon nanotubes originates from their unique variety of properties useful in nanoelectronic devices. One key feature of carbon nanotubes is that the chiral angle at which they are rolled determines whether the tube is metallic or semiconducting. Of main interest to this project are devices containing a thin film of randomly arranged carbon nanotubes, known as carbon nanotube networks. The presence of semiconducting tubes in a CNT network can lead to a switching effect when the film is electro-statically …

An Analysis Of Frenkel Defects And Backgrounds Modeling For Supercdms Dark Matter Searches, Matthew Stein

Physics Theses and Dissertations

Years of astrophysical observations suggest that dark matter comprises more than ~80 % of all matter in the universe. Particle physics theories favor a weakly-interacting particle that could be directly detected in terrestrial experiments. The Super Cryogenic Dark Matter Search (SuperCDMS) Collaboration operates world-leading experiments to directly detect dark matter interacting with ordinary matter. The SuperCDMS Soudan experiment searched for weakly interacting massive particles (WIMPs) via their elastic-scattering interactions with nuclei in low-temperature germanium detectors.

During the operation of the SuperCDMS Soudan experiment, ²¹⁰Pb sources were installed to study background rejection of the Ge detectors. Data from these sources …

Vibrational Relaxation Theory For Systems Embedded In Microscopically Specified Reservoirs, Anastasia Aemilia Ierides

Physics & Astronomy ETDs

This dissertation is a study of the theoretical framework of the practical as well as fundamental problem of the process of relaxation to equilibrium of quantum mechanical systems. The fundamental aspect is concerned with the simultaneous occurrence of decoherence and population equilibration. The practical aspect deals with experimental observations of vibrational relaxation of molecules embedded in liquids or solids. The systems include, but are not limited to, the nondegenerate dimer and harmonic oscillator, in one case weak and in the other strong, interaction with a thermal bath. The time dependence of the energy and the temperature dependence of the relaxation …