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Full-Text Articles in Condensed Matter Physics

Hyperpolarization Of Silicon Nanoparticles With Tempo Radicals, Jingzhe Hu, Nicholas Whiting, Pratip Bhattacharya Mar 2018

Hyperpolarization Of Silicon Nanoparticles With Tempo Radicals, Jingzhe Hu, Nicholas Whiting, Pratip Bhattacharya

Nicholas Whiting

Silicon-based particles can be hyperpolarized via dynamic nuclear polarization to enhance 29Si magnetic resonance signals. Application of this technique to nanoscale silicon particles has been limited because of the low signal enhancements achieved; it is hypothesized that this is due to the low number of endogenous electronic defects inherent to the particles. We introduce a method of incorporating exogenous radicals into silicon nanoparticle suspensions in order to improve the hyperpolarization of 29Si nuclear spins to levels sufficient for in vivo MR imaging. Calibration of radical concentrations and polarization times are reported for a variety of silicon particle sizes (30−200 nm …


Photovoltaic Effect In Single-Junction Organic Solar Cell Fabricated Using Vanadyl Phthalocyanine Soluble Derivative, Shahino Mah Abdullah Jun 2014

Photovoltaic Effect In Single-Junction Organic Solar Cell Fabricated Using Vanadyl Phthalocyanine Soluble Derivative, Shahino Mah Abdullah

Shahino Mah Abdullah

Purpose: The purpose of this paper is to study the optical and electrical characteristics of a single‐junction solar cell based on a green-color dye Vanadyl 2,9,16, 23-tetraphenoxy-29H, 31H-phthalocyanine (VOPcPhO). The use of soluble vanadyl phthalocyanine derivative makes it very attractive for photovoltaic applications due to its tunable properties and high solubility. Design/methodology/approach: A photoactive layer of VOPcPhO has been sandwiched between indium tin oxide (ITO) and aluminum (Al) electrodes to produce ITO/PEDOT:PSS/VOPcPhO/Al photovoltaic device. The VOPcPhO thin film is deposited by a simple spin coating technique. In order to obtain the optimal thickness for the solar cell device, different thicknesses …


Investigation Of Charge Transport In Organic Polymer Donor/Acceptor Photovolatic Materials, Zubair Ahmad, Shahino Mah Abdullah, Khaulah Sulaiman May 2014

Investigation Of Charge Transport In Organic Polymer Donor/Acceptor Photovolatic Materials, Zubair Ahmad, Shahino Mah Abdullah, Khaulah Sulaiman

Shahino Mah Abdullah

Pi-conjugated organic semiconductors have long been used as either holes or electrons transport materials. Recently ambipolar charge carrier transport in these materials have been reported in many investigations. In this paper, we report on the basis of experimental results that the organic semiconductor (donor/acceptor) materials can be as good electrons transporters as these materials are holes transporters. In our study, the solution-processed unipolar diodes based on organic materials P3HT, VOPCPhO and their blends with PCBM have been fabricated. The I-V characteristics of these diodes have been analyzed in the space charge limited current regime. The values of the electron and …


Investigation Of Charge Transport In Organic Polymer Donor/Acceptor Photovolatic Materials, Zubair Ahmad, Shahino Mah Abdullah, Khaulah Sulaiman Apr 2014

Investigation Of Charge Transport In Organic Polymer Donor/Acceptor Photovolatic Materials, Zubair Ahmad, Shahino Mah Abdullah, Khaulah Sulaiman

Zubair Ahmad

Pi-conjugated organic semiconductors have long been used as either holes or electrons transport materials. Recently ambipolar charge carrier transport in these materials have been reported in many investigations. In this paper, we report on the basis of experimental results that the organic semiconductor (donor/acceptor) materials can be as good electrons transporters as these materials are holes transporters. In our study, the solution-processed unipolar diodes based on organic materials P3HT, VOPCPhO and their blends with PCBM have been fabricated. The I-V characteristics of these diodes have been analyzed in the space charge limited current regime. The values of the electron and …


Investigation Of Vopcpho As An Acceptor Material For Bulk Heterojunction Solar Cells, Shahino Mah Abdullah Aug 2012

Investigation Of Vopcpho As An Acceptor Material For Bulk Heterojunction Solar Cells, Shahino Mah Abdullah

Shahino Mah Abdullah

In this study, we have successfully demonstrated a new system of donor–acceptor blend for bulk heterojunction solar cells of poly(3-hexylthiophene) (P3HT) by using vanadyl 2,9,16,23-tetraphenoxy-29H,31H-phthalocyanine (VOPcPhO) as acceptor material. A broad absorption over the whole visible range (450–750 nm) is achieved. Utilizing this blend system in solar cell fabrication, ITO/PEDOT:PSS/P3HT:VOPcPhO/Al solar cells have been fabricated and characterized in open air. A maximum power conversation efficiency up to 1.09% has been recorded. To confirm the charge transport, the electron and hole mobility of VoPcPhO has been measured. The results show that the VoPcPhO has bipolar transport and can act as an …


Temperature-Sensitive Chemical Cell Based On Nickel (Ii) Phthalocyanine-Tetrasulfonic Acid Tetrasodium Salt, Shahino Mah Abdullah Mar 2012

Temperature-Sensitive Chemical Cell Based On Nickel (Ii) Phthalocyanine-Tetrasulfonic Acid Tetrasodium Salt, Shahino Mah Abdullah

Shahino Mah Abdullah

An organic compound Nickel (II) phthalocyanine-tetrasulfonic acid tetrasodium salt (NiTSPc) has been studied as a potential material for a solution based temperature sensor. Using NiTSPc, an ITO/NiTSPc solution/ITO chemical cell has been made and characterized in the temperature range of 20–85 ◦C. This sensor works on the principle of change in the resistance and capacitance of the chemical cell caused by the temperature variation. Good response/recovery and small hysteresis have been attained. The proposed sensor is aimed to evolve towards highly sensitive organic temperature sensor in a specific temperature range.


Dielectric Relaxation Behaviour Of Glycine In Acqueous Solution Medium In The Microwave Frequency Region, Ajaya Kumar Kavala Apr 2008

Dielectric Relaxation Behaviour Of Glycine In Acqueous Solution Medium In The Microwave Frequency Region, Ajaya Kumar Kavala

Mr Ajaya Kumar Kavala

No abstract provided.