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Atomic, Molecular and Optical Physics Commons™

Open Access. Powered by Scholars. Published by Universities.®

1995

Air Force Institute of Technology

Articles 1 - 8 of 8

Full-Text Articles in Atomic, Molecular and Optical Physics

Study Of The Long-Term Desorption Of Trichloroethylene From Clay Soils Using Infrared Spectroscopy, Mary P. Stager Dec 1995

Study Of The Long-Term Desorption Of Trichloroethylene From Clay Soils Using Infrared Spectroscopy, Mary P. Stager

Theses and Dissertations

Slow desorption of contaminants from soil presents one of the greatest challenges to modeling contaminant fate and transport and implementing effective remediation technologies. The kinetics of long-term desorption of trichloroethylene (TCE) from powdered clay soils were studied to determine the desorption rates and mechanism. Infrared absorption spectroscopy was used to monitor the concentration of TCE desorbed from contaminated flint clay for 71 hours. Observed gas phase TCE concentrations as a function of time were compared to that predicted by a one-site Langmuir desorption mechanism. The Langmuir model, with a single type of bonding site, did not account for the release …

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A Comparison Of Methods For Estimating Rms Error: A `Brute Force" Approach Versus A Mathematically-Elegant Approach, As Applied To The Calculation Of A Specific Retrieval Error For A Limb-Scanning Microwave Radiometer-Spectrometer, Larry L. Johnson Dec 1995

A Comparison Of Methods For Estimating Rms Error: A `Brute Force" Approach Versus A Mathematically-Elegant Approach, As Applied To The Calculation Of A Specific Retrieval Error For A Limb-Scanning Microwave Radiometer-Spectrometer, Larry L. Johnson

Theses and Dissertations

The Millimeter-wave Atmospheric Sounder (MAS) is a high resolution limb- scanning microwave radiometer-spectrometer which has been flown aboard the Space Shuttle. The instrument was designed to sense the microwave emission from several upper atmospheric constituents, including water vapor and ozone. The resonant frequencies of water vapor and ozone are extremely close (183 and 184 GHz, respectively), so that the high-frequency wing of the water vapor spectrum overlaps the low frequency wing of the ozone spectrum. Consequently, the measured ozone spectrum incorporates a slight water vapor contribution; therefore, the retrieved ozone profile is dependent on the true water vapor profile. The …

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A Portable Compton Gamma-Ray Camera Design, Brian L. Evans Dec 1995

A Portable Compton Gamma-Ray Camera Design, Brian L. Evans

Theses and Dissertations

The purpose of this research is to investigate the angular resolution, efficiency, and energy resolution possible from a portable Compton camera gamma ray imaging system for possible use in the field of nuclear nonproliferation. The proposed device uses room temperature semiconductor and position sensitive scintillation detectors. The position and energy resolution (and their energy dependence) of a room temperature lithium drifted silicon (Si(Li)) detector and a position sensitive thallium -doped sodium iodide (NaI(Tl)) scintillation detector are investigated. The position and energy resolution of the position sensitive scintillation detector is also modeled computationally, and the results compared to measured data. An …

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Steady-State Kinetics Of Br(2P1/2) Yields Co2(101) Electronic-To-Vibrational Energy Transfer Laser System, Stephen J. Karis Nov 1995

Steady-State Kinetics Of Br(2P1/2) Yields Co2(101) Electronic-To-Vibrational Energy Transfer Laser System, Stephen J. Karis

Theses and Dissertations

Steady state photolysis experiments were conducted to gain information relevant to the construction of a continuous wave electronic to vibrational pumped infrared laser. An Ar+ laser =488 µm) was used to produce the electronically excited state Br(2P1/2) (Br*) via photolysis of molecular bromine. Energy was then transferred to the near resonant vibrational state CO2(101) (CO2) via the collisional quenching of Br* by CO2. The dependence of the 2.71 µm Br* and 4.3 µm CO2 emissions on CO2 pressure was measured, as well as …

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Optical Characterization Of Indium Arsenide Antimonide Semiconductors Grown By Molecular Beam Epitaxy, Michael A. Marciniak Sep 1995

Optical Characterization Of Indium Arsenide Antimonide Semiconductors Grown By Molecular Beam Epitaxy, Michael A. Marciniak

Theses and Dissertations

The material parameters and crystalline quality of undoped, MBE-grown InAs1-xSbx nearly lattice-matched to (100) GaSb (-0.617% ≤ Δ a-a ≤ +0.708%) similar to material used for mid-infrared semiconductor lasers were determined by optical characterization. Absorption measurements at temperatures between 6-295 K determined the energy gap and wavelength-dependent absorption coefficient for each sample. The compositional dependence of the energy gap was anomalous when compared to previously reported data, suggesting phase separation existed in the material. The samples were also studied by temperature- and excitation-dependent photoluminescence (PL), which, for the majority of cases, showed only a single band-edge peak, …

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Collisional Dynamics Of The Rubidium 52P Levels, Matthew D. Rotondaro Sep 1995

Collisional Dynamics Of The Rubidium 52P Levels, Matthew D. Rotondaro

Theses and Dissertations

The collisional dynamics of the 52P levels in rubidium has been examined using steady-state laser absorption and spectrally-resolved laser induced fluorescence techniques. State-to-state cross-sections for energy transfer between Zeeman split levels ranged from 16-248 °A2 for collisions with nitrogen and rare gases. These energy transfer cross-sections exhibit a significant dependence on (J,mj) state and certain symmetry relationships are demonstrated. A sub-Doppler spectrum of the Zeeman split levels indicating the isotopic shift in the D1 line of 106 ± 35 was obtained using laser saturation spectroscopy.

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Non-Imaging Infrared Spectral Target Detection, Matthew R. Whiteley Sep 1995

Non-Imaging Infrared Spectral Target Detection, Matthew R. Whiteley

Theses and Dissertations

Automatic detection of time-critical mobile targets using spectral-only infrared radiance data is explored. A quantification of the probability of detection, false alarm rate, and total error rate associated with this detection process is provided. A set of classification features is developed for the spectral data, and these features are utilized in a Bayesian classifier singly and in combination to provide target detection. The results of this processing are presented and sensitivity of the class separability to target set, target configuration, diurnal variations, mean contrast, and ambient temperature estimation errors is explored. This work introduces the concept of atmospheric normalization of …

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Ohmic Contact To Ion Implanted Gallium Arsenide Antimonide For Application To Indium Aluminum Arsenide-Gallium Arsenide Antimonide Heterostructure Insulated-Gate Field Effect Transistors, Kenneth G. Merkel Ii Jul 1995

Ohmic Contact To Ion Implanted Gallium Arsenide Antimonide For Application To Indium Aluminum Arsenide-Gallium Arsenide Antimonide Heterostructure Insulated-Gate Field Effect Transistors, Kenneth G. Merkel Ii

Theses and Dissertations

The p-channel In0.52Al0.48As-GaAs1-xSbx heterostructure insulated-gate field effect transistor (p-HIGFET) is a candidate for complementary integrated circuits due to superior cutoff characteristics and low gate leakage current. Advancement of the In0.52Al0.48As-GaAs1-xSbx p-HIGFET requires improved source-drain design. Five main tasks were accomplished to achieve this goal. First, thermal limits of the In0.52Al0.48As-GaAs0.51Sb0.49 HIGFET were investigated. Second, the temperature dependence of band gap and impurity energies were determined for beryllium doped In0.52Al0.48. Third, high acceptor concentrations were obtained …

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