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Resistivity And Thermoelectric-Power Measurements Of PrXY1-XBa2Cu3O7-Δ Up To 1200 K And An Electronic-Structure Analysis, B. Fisher, J. Genossar, L. Patlagan, J. Ashkenazi

Physics Articles and Papers

We report measurements of absolute thermoelectric power and resistivity in Pr_xY_1-xBa₂Cu₃O_7-δ, as function of x and δ, over a wide temperature range. At high temperature, the substitution of Pr for Y does not affect the thermopower and resistivity; Pr behaves then as a trivalent ion: Pr³⁺. For small x and δ the effects of substitution of Y by Pr and of oxygen deficiency on the low-temperature resistivity are additive. A simple electronic-structure model is proposed to account for thermopower as function of temperature, x, and δ.