Physics Commons^™

Photodetachment Of A Model Molecular System By An Elliptically Polarized Field, M. V. Frolov, N. L. Manakov, S. S. Marmo, Anthony F. Starace

Anthony F. Starace Publications

The differential cross section for one-photon molecular detachment by an elliptically polarized field is analyzed for a one-electron molecular model comprised of an electron in the field of two (generally nonequivalent) attractive zero-range potentials (ZRPs) separated by the distance R. A phenomenological parametrization of the photodetachment cross section for a fixed-in-space molecular system in terms of two scalar dynamical parameters is presented and circular dichroism effects are discussed. Analytic results for the dynamical molecular parameters within the ZRP molecular model are used to analyze interference phenomena (including two-center interference) and dichroic effects in the detached electron angular distributions and …

Theoretical Modeling Of Near-Threshold Shape Resonance Behaviour In Photodetachment Experiments, Laurentiu Dan Dumitriu

Masters Theses

This thesis attempts to better understand the results obtained from photodetachment experiments of Fe-, made by the Western Michigan University experimental atomic physics group at the Advanced Light Source (ALS), Lawrence Berkeley National laboratory.

After a relevant description of the quantum mechanics and theoretical atomic physics concepts and formulas involved in this subject, a physically realistic model, based on the square well potential, is developed. Based on this model, the theoretical photodetachment cross section is computed in order to reproduce the qualitative behavior of the experimental photodetachment cross section measured at ALS.

This development, involving programming in Fortran and numerical …

Mirroring And Mimicking Of Partial Cross Sections In The Vicinity Of A Resonance, Chien-Nan Liu, Anthony F. Starace

Anthony F. Starace Publications

We review recent analytical work on mirroring and mimicking behavior of resonance profiles in different partial cross sections. This work is related to the work of Fano and Cooper on resonance profiles in total cross sections and that of Starace on resonance profiles in partial cross sections. Applications of the new theories (describing mirroring and mimicking behavior) to recent experimental measurements and theoretical predictions for photoionization, photodetachment, and Auger spectroscopy in the vicinity of resonance structures are discussed.

Neutral Dissociation Of Hydrogen Following Photoexcitation Of Hcl At The Chlorine K Edge, D. L. Hansen, J. Cotter, G. R. Fisher, K. T. Leung, R. Martin, Paul Neill, Rupert C. Perera, I. A. Sellin, Marc Simon, Y. Uehara, B. Vanderford, S. B. Whitfield

Chemistry and Biochemistry Faculty Research

Time-of-flight mass spectroscopy was used to study the relaxation dynamics of HCl following photoexcitation in the vicinity of the Cl K edge (~2.8 keV) using monochromatic synchrotron radiation. At the lowest resonant excitation to the 6ơ* antibonding orbital, almost half of the excited molecules decay by emission of a neutral H atom, mostly in coincidence with a highly charged Cln1 ion. The present work demonstrates that neutral-atom emission can be a significant decay channel for excited states with very short lifetimes (1 fs). [S1050-2947(98)03604-X]