Physics Commons^™

Magnetic Resonance Studies Of Free Radicals Generation And Their Impact In Different Polymers, Sunita Humagain

Dissertations, Theses, and Capstone Projects

Studies of free radicals in the physics, chemistry, biology, and materials science have contributed to advancements in those fields. The presence of radicals can damage the material and system in some instances and, in some cases, they may enhance the property of the material as well. Knowledge of free radical transformations helps in resilience of certain polymers and inhibition of the oxidation of food and medicine. In this thesis, using the magnetic resonance techniques, EPR and NMR, the generation of free radicals and their effect on the structure of the material is being studied.

Kapton Polyimide (PI, Kapton®) used in …

Magnetic And Catalytic Properties Of Transition Metal Doped Mos2 Nanocrystals, Luis Martinez

Open Access Theses & Dissertations

Magnetism and catalytic activity of nanoscale layered two-dimensional (2D) transition metal dichalcogenides (TMDs) have gained an increasing research interest in the recent past. To broaden the current knowledge and understanding on this subject, in this work, together with my collaborators, I study the magnetic and electrocatalytic properties of hydrothermally grown pristine and transition metal doped (10% of Co, Ni, Fe and Mn) 2H-MoS2 nanosheets/nanocrystals (NCs), with the particle size of 25-30 nm. A broad range of experimental measurements such as x-ray diffraction, transmission electron microscopy, x-ray photo absorption spectroscopy, Raman spectroscopy, magnetic, catalytic and electron spin resonance have been employed …

Investigating The Influence Of Interface And Vacancy Defects On The Growth Of Silicon Quantum Dots In Sio2, John Phelan

Electronic Thesis and Dissertation Repository

The effects of interface and vacancy defects on silicon quantum dot (Si-QD) growth are investigated using measurements of Time Resolved Photoluminescence (TRPL), Photoluminescence (PL) Spectroscopy and Electron Paramagnetic Resonance (EPR). Thermally grown SiO₂ thin films (280nm) were irradiated with high energy (400keV – 1MeV) silicon ions in order to introduce defects into the Si-QD growth layer of SiO₂. A noticeable increase in PL emission intensity is seen with the highest energy pre-implanted sample over a single implant sample. TRPL results show increased radiative lifetimes for the lower energy (400keV) pre-implant while little or no difference is seen …

Characterization Of Neutron-Induced Defects In Isotopically Enriched Lithium Tetraborate, Brant E. Kananen

Theses and Dissertations

Lithium Tetraborate (LTB) is assessed for use as a material for neutron detection. LTB isotopically enriched in either Li-6 or B-10 provides a medium that efficiently captures and transmutes neutrons into more readily detected forms of material or energy. Neutron detection is desirable to detect elicit movement of special nuclear material or nuclear weapons. Single crystals of LTB, Li-6 or B-10 enriched, were neutron irradiated, and electron paramagnetic resonance was used to detect point defects induced by the neutrons. Multiple defects were noted in the irradiated crystals. Two particular defects, perturbed lithium vacancies and lithium clusters are proposed as induced …

Coupling Into Waveguide Evanescent Modes With Applications In Electron Paramagnetic Resonance, Jason Walter Sidabras

Master's Theses (2009 -)

The use of analytical and numerical techniques in solving the coupling of evanescent modes in a microwave waveguide through slots can be optimized to create a uniform magnetic field excitation on axis within a waveguide. This work has direct applications in Electron Paramagnetic Resonance (EPR) where a 100~kHz time-varying magnetic field is incident on a sample contained in a microwave cavity. Typical cavity designs do not take into consideration the uniformity of the 100~kHz field modulation and assume it to be uniform enough over the sample region from quasi-static principles. This work shows otherwise and uses Ansoft (Pittsburgh, PA) High …

Electron Paramagnetic Resonance Of Gd3+ Ions In The Superconductor Gdba2Cu3OX, F. Mehran, S. E. Barnes, C. C. Tsuei, T. R. Mcguire

Physics Articles and Papers

EPR from Gd³⁺ ions in the high-T_c≃90 K superconductor GdBa₂Cu₃O_x is reported. The temperature dependence of the linewidth and intensity of the Gd³⁺ ions in the vicinity of T_c are related to the corresponding characteristics of the Cu²⁺ ions.