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Full-Text Articles in Physics

Terahertz Studies Of The Dielectric Response And Second-Order Phonons In A Gase Crystal, B. L. Yu, F. Zeng, V. Kartazayev, R. R. Alfano, K. C. Mandal Apr 2015

Terahertz Studies Of The Dielectric Response And Second-Order Phonons In A Gase Crystal, B. L. Yu, F. Zeng, V. Kartazayev, R. R. Alfano, K. C. Mandal

Krishna C. Mandal

No abstract provided.


Terahertz Studies Of The Dielectric Response And Second-Order Phonons In A Gase Crystal, B. L. Yu, F. Zeng, V. Kartazayev, R. R. Alfano, K. C. Mandal Apr 2015

Terahertz Studies Of The Dielectric Response And Second-Order Phonons In A Gase Crystal, B. L. Yu, F. Zeng, V. Kartazayev, R. R. Alfano, K. C. Mandal

Krishna C. Mandal

No abstract provided.


Jahn-Teller Coupling And Fragmentation After Core-Shell Excitation Ini Cf4 Investigated By Partial-Ion-Yield Spectroscopy, Renaud Guillemin, Wayne C. Stolte, Maria Novella Piancastelli, Dennis W. Lindle Oct 2010

Jahn-Teller Coupling And Fragmentation After Core-Shell Excitation Ini Cf4 Investigated By Partial-Ion-Yield Spectroscopy, Renaud Guillemin, Wayne C. Stolte, Maria Novella Piancastelli, Dennis W. Lindle

Chemistry and Biochemistry Faculty Research

We investigate fragmentation processes induced by core-level photoexcitation in CF4 at both the carbon and fluorine K edges by means of partial-ion-yield spectroscopy. The molecule CF4 is a textbook example of systems in which Jahn-Teller coupling strongly manifests itself in the photoabsorption spectrum. Spectral features related to Jahn-Teller and quasi-Jahn-Teller splitting are observed, and important differences in the fragmentation pathways are revealed depending on the symmetries of the core-excited states. We interpret these experimental observations on the grounds of symmetry lowering from the Td to the C3v point group as well as preferential orientation with respect …


Nonlinear Absorption And Free Carrier Recombination In Direct Gap Semiconductors, Peter D. Olszak Jan 2010

Nonlinear Absorption And Free Carrier Recombination In Direct Gap Semiconductors, Peter D. Olszak

Electronic Theses and Dissertations

Nonlinear absorption of Indium Antimonide (InSb) has been studied for many years, yet due to the complexity of absorption mechanisms and experimental difficulties in the infrared, this is still a subject of research. Although measurements have been made in the past, a consistent model that worked for both picosecond and nanosecond pulse widths had not been demonstrated. In this project, temperature dependent two-photon (2PA) and free carrier absorption (FCA) spectra of InSb are measured using femtosecond, picosecond, and nanosecond IR sources. The 2PA spectrum is measured at room temperature with femtosecond pulses, and the temperature dependence of 2PA and FCA …


Singlet Delta Oxygen: A Quantitative Analysis Using Off-Axis Integrated-Cavity-Output-Spectroscopy (Icos), Jeffrey E. Gallagher Mar 2006

Singlet Delta Oxygen: A Quantitative Analysis Using Off-Axis Integrated-Cavity-Output-Spectroscopy (Icos), Jeffrey E. Gallagher

Theses and Dissertations

A new spectroscopic technique applicable to the detection of ultra-weak and for- bidden molecular transitions is presented. The method is based on off-axis integrated-cavity-output spectroscopy (ICOS). The primary goal for this research effort is to utilize the ICOS technique and demonstrate its ability to provide quantitative data of singlet delta oxygen. This thesis will focus on three areas of characterization to achieve this goal. First, the absolute line positions will be determined and compared to values derived from the most recent theory. Second, the integrated absorption cross-sections will be verified using Boltzmann analysis. Finally, pressure broadening coefficients will be determined …


Terahertz Studies Of The Dielectric Response And Second-Order Phonons In A Gase Crystal, B. L. Yu, F. Zeng, V. Kartazayev, R. R. Alfano, K. C. Mandal Oct 2005

Terahertz Studies Of The Dielectric Response And Second-Order Phonons In A Gase Crystal, B. L. Yu, F. Zeng, V. Kartazayev, R. R. Alfano, K. C. Mandal

Faculty Publications

No abstract provided.


Collisional Effects In The Absorption Spectra Of The Oxygen A Band And Nitric Oxide Fundamental Band, Robert S. Pope Dec 1998

Collisional Effects In The Absorption Spectra Of The Oxygen A Band And Nitric Oxide Fundamental Band, Robert S. Pope

Theses and Dissertations

Fourier transform spectroscopy was used to measure pressure broadening coefficients in the absorption spectra of both the oxygen A band and the nitric oxide fundamental band. Oxygen spectra were recorded with O2, N2, CO, CO2, SF6 and noble gas collision partners, while nitric oxide spectra were recorded using noble gas collision partners. Pressure broadening coefficients were determined in the P and R branches for every resolved line for each of the fifteen collision pairs studied. In addition, broadening coefficients and qualitative evidence of line coupling were found for the Q branch of NO …