Physics Commons^™

Carbon Nanotube Electronic Structures As Anti-Corrosion Coatings, Sreeya Sreevatsa

Dissertations

A new concept of corrosion prevention is considered in this study. Diode-like and transistor-like structures have been fabricated and analyzed in the study of ionic flow through the resulting potential barriers. The structures were made of functionalized carbon nanotubes. Carbon nanotubes are known for many remarkable properties among which is being chemically inert. Taking advantage of this property, a study of corrosion of steel was undertaken.

In the first case study, successive layers of functionalized carbon nanotubes were deposited to form p-n junctions on steel substrates. It was demonstrated that the corrosion was indeed impeded by the potential barrier formed …

Strain Energy And Lateral Friction Force Distributions Of Carbon Nanotubes Manipulated Into Shapes By Atomic Force Microscopy, Mark C. Strus, Roya R. Lahiji, Pablo Ares, Vincente Lopez, Arvind Raman, Ron R. Reifenberger

Other Nanotechnology Publications

The interplay between local mechanical strain energy and lateral frictional forces determines the shape of carbon nanotubes on substrates. In turn, because of its nanometer-size diameter, the shape of a carbon nanotube strongly influences its local electronic, chemical, and mechanical properties. Few, if any, methods exist for resolving the strain energy and static frictional forces along the length of a deformed nanotube supported on a substrate. We present a method using nonlinear elastic rod theory in which we compute the flexural strain energy and static frictional forces along the length of single walled carbon nanotubes (SWCNTs) manipulated into various shapes …

Massively Parallel Indirect Dielectrophoresis Controlled Placement Of Carbon Nanotubes, Hiram Jacob Conley

Theses and Dissertations

Placement of single walled carbon nanotubes is demonstrated through massively parallel indirect dielectrophoresis (MPID). MPID is shown to be able to control the placement of carbon tubes as well as the number of tubes placed. Lumped element analysis for AC circuits is used to model MPID. This model allows for predictions of the number of tubes that will be captured in a trap. This model has been consistent with experimental data of numbers of nanotube placed in a junction. Carbon nanotubes placed with MPID are shown to be electrically active.

Spectroscopic Investigations On Polypropylene-Carbon Nanofiber Composites: I. Raman And Electron Spin Resonance Spectroscopy, Mircea Chipara, John R. Villarreal, Magdalena Dorina Chipara, Karen Lozano, Alin Cristian Chipara, David J. Sellmyer

David Sellmyer Publications

Isotactic polypropylene-vapor grown carbon nanofiber composites containing various fractions of carbon nanofibers, ranging from 0 to 20 wt %, have been prepared. Raman spectroscopy was used to analyze the effect of the dispersion of carbon nanofibers within polypropylene and the interactions between carbon nanofibers and macromolecular chains. The as-recorded Raman spectra have been successfully fitted by a linear convolution of Lorentzian lines. Changes of the Raman lines parameters (position, intensity, width, and area) of polypropylene and carbon nanofibers were analyzed in detail. The Raman spectra of the polymeric matrix—at low concentrations of nanofibers—show important modifications that indicate strong interactions between …

Electrochemically Mediated Charge Transfer Effects On Single-Walled Carbon Nanotubes., Buddika Ka. Abeyweera 1980-

Electronic Theses and Dissertations

This thesis is based on experimental work on electrochemically mediated charge transfer effects on Single-walled carbon nanotube bundles. The study of these effects are very important towards understanding the sensitivity of gases on nanostructures like single-walled carbon nanotubes. Chapter one covers the introduction and overview of carbon nanostructures including single-walled carbon nanotubes. Chapter two covers the experimental techniques involving sample preparation, experimental setup and data acquisition. Chapter three consists of Results and the Discussions explaining the mechanisms based on charge transfer mechanism. In the final chapter, implications and the importance of the study are explained. Single-walled carbon nanotubes are used …

Toxicity Assessment Of Single-Walled Carbon Nanotubes, Eva Herzog

Doctoral

The objective of this study was to investigate the potential adverse health effects of occupational exposure to SWCNT dust using various in vitro approaches. Lung epithelium (represented by A549 and NHBE cells) was chosen as target cell model and exposed to minimally processed particle samples under submerse conditions and effects were compared to that of carbon black and crocidolite asbestos exposure. Cytotoxicity studies indicated low acute cytotoxicity of SWCNT. Morphological changes included decreases in microvilli and increased numbers of surfactant storing lamellar bodies and changes in cytoskeleton. Due to interactions of SWCNT and toxicity indicator dyes, the clonogenic assay was …