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Full-Text Articles in Physics

Segregation Of Bismuth To Triple Junctions In Copper, K.-M. Yin, Alexander H. King, T.E. Hsieh, F.-R. Chen, J.J. Kai, L. Chang Sep 1997

Segregation Of Bismuth To Triple Junctions In Copper, K.-M. Yin, Alexander H. King, T.E. Hsieh, F.-R. Chen, J.J. Kai, L. Chang

Alexander H. King

Bismuth segregation in copper has been studied using energy-dispersive X-ray spectrometry (EDX) in a JEOL 2010F transmission electron microscope. In addition to the expected solute enrichment at grain boundaries, we have observed extremely high concentrations of bismuth at certain triple junctions, with significantly greater enrichment factors than in the adjacent grain boundaries. It is shown here that the triple junction segregation is a function of the parameters of the grain boundaries at the triple line, and existence of this type of segregation implies that the affected triple junctions embody excess free energy. At least one of the observed triple junctions …


Vibrational Spectra In Ordered And Disordered Ni3al, Jeffrey D. Althoff, Dane Morgan, Didier De Fontaine, Mark Asta, S. M. Foiles, Duane D. Johnson Sep 1997

Vibrational Spectra In Ordered And Disordered Ni3al, Jeffrey D. Althoff, Dane Morgan, Didier De Fontaine, Mark Asta, S. M. Foiles, Duane D. Johnson

Duane D. Johnson

We calculate the vibrational density of states (DOS) and corresponding thermodynamic properties of L12 ordered and disordered Ni3Al in the quasiharmonic approximation using the embedded-atom method. Vibrational and thermodynamic properties, including vibrational entropy differences between ordered and disordered states, are found to be in good agreement with experiment. The DOS of the configurationally disordered alloy resembles a broadened version of the DOS of the L12 phase, not a one-atom per cell fcc DOS, and is shifted downward in frequency because the disordered state has a larger volume than the ordered phase. Calculations of the projected DOS indicate that high-frequency modes …


Experimental And Theoretical Investigations Of Order-Disorder In Cu2almn, Duane D. Johnson, M. Asta, J. J. Hoyt, B. C. Chakoumakos, S. T. Misture, J. D. Althoff, R. Mccormack May 1997

Experimental And Theoretical Investigations Of Order-Disorder In Cu2almn, Duane D. Johnson, M. Asta, J. J. Hoyt, B. C. Chakoumakos, S. T. Misture, J. D. Althoff, R. Mccormack

Duane D. Johnson

A combination of X-ray and neutron powder diffraction has been used to measure the two long range order parameters vs. temperature below the disorder-B2 transition in the ternary alloy Cu2 AlMn. The results indicate that at temperatures just below the critical point the Al + Mn sublattice is enriched in Al. First-principles calculations based on only the atomic numbers of Cu, Mn and Al support the experimentally-observed preference of Al for the Al + Mn sublattice, and reveal the interplay between the constituent binary systems that gives rise to this behavior.


Photoluminescence Properties Of Silicon Quantum-Well Layers, Peter N. Saeta, A. C. Gallagher Feb 1997

Photoluminescence Properties Of Silicon Quantum-Well Layers, Peter N. Saeta, A. C. Gallagher

All HMC Faculty Publications and Research

Nanometer-scale crystal silicon films surrounded by SiO2 were prepared by oxidizing silicon-on-insulator substrates prepared from SIMOX (separation by implantation of oxygen) and crystallized hydrogenated amorphous silicon films. Average silicon layer thickness was determined from reflection spectra. When sufficiently thin (<2 >nm), all layers emitted red photoluminescence under blue and UV cw excitation, with a spectrum that did not depend on the mean layer thickness. The spectrum was roughly Gaussian with a peak energy of 1.65 eV, which is lower than for most porous silicon spectra. The time scale for the luminescence decay was ~35 μs at room temperature and …


Low Pressure Synthesis Of Bulk, Polycrystalline Gallium Nitride, Alberto Argoitia, Cliff C. Hayman, John C. Angus, Long Wang, Jeffrey S. Dyck, Kathleen Kash Jan 1997

Low Pressure Synthesis Of Bulk, Polycrystalline Gallium Nitride, Alberto Argoitia, Cliff C. Hayman, John C. Angus, Long Wang, Jeffrey S. Dyck, Kathleen Kash

Jeffrey Dyck

Thick films of polycrystalline GaN were grown at low pressures by direct reaction of atomic nitrogen with liquid Ga without the presence of a substrate. The crystals were confirmed to be wurtzitic GaN by x-ray diffraction, transmission electron microscopy, Raman spectroscopy, and elemental analysis. Photoluminescence spectra showed near band edge peaks and broad yellow band emission at both 298 and 10 K. The results show that atomic nitrogen is an attractive alternative to high pressure N2 for the saturation of liquid gallium with nitrogen for the synthesis of bulk GaN.


Nmr And Vortex Lattice Melting In Yba2cu3o7, Charles Recchia, J Martindale, C Pennington, W Hults, J Smith Jan 1997

Nmr And Vortex Lattice Melting In Yba2cu3o7, Charles Recchia, J Martindale, C Pennington, W Hults, J Smith

Charles H Recchia

No abstract provided.


Local Nonequilibrium Transport Models, Sergey Sobolev Jan 1997

Local Nonequilibrium Transport Models, Sergey Sobolev

Sergey Sobolev

No abstract provided.


Local Non-Equilibrium Diffusion Effects On The Kinetic Phase Boundaries In Solidification, Sergey Sobolev Jan 1997

Local Non-Equilibrium Diffusion Effects On The Kinetic Phase Boundaries In Solidification, Sergey Sobolev

Sergey Sobolev

No abstract provided.


Microstructural Characterization Of An Ultra-High-Performance Polyimide, April Heather Baugher Jan 1997

Microstructural Characterization Of An Ultra-High-Performance Polyimide, April Heather Baugher

Dissertations, Theses, and Masters Projects

The motivation for this study was to further characterize a relatively new high-temperature polymer for application as a matrix resin for carbon fiber composites. The two primary questions addressed in this study dealt with the structural and chemical changes occurring in these polymers on exposure to high temperature.;To investigate the structural changes in the heat-treated samples, a positron annihilation lifetime spectrometer was designed, built and optimized. Because the lifetime of a positron in a material reflects the electronic structure of the material in which it annihilates, measurements by positron annihilation lifetime spectroscopy can be used to investigate changes in a …


Radiation-Induced Luminescence In Terbium-Doped Silicate Glasses, Michael Stuart West Jan 1997

Radiation-Induced Luminescence In Terbium-Doped Silicate Glasses, Michael Stuart West

Dissertations, Theses, and Masters Projects

The purpose of this study is to characterize radiation-induced luminescence of terbium-doped silicate glasses. Experiments performed investigated the optical properties, isothermal time-evolution, and temperature dependence of the radiation-induced luminescence of two commercially available terbium-doped glasses. A problem common to this type of glass is the persistent luminescence, or afterglow, that occurs following the end of excitation from an external source of radiation. While the processes that govern characteristic luminescence of rare earth ions, including terbium, are well understood, the processes that give rise to afterglow in doped glasses are not. Identifying the source of long-term luminescence is essential for controlling …


Propagation Of Rayleigh Waves In Thin Films, Agus A. Ananda Jan 1997

Propagation Of Rayleigh Waves In Thin Films, Agus A. Ananda

Dissertations, Theses, and Masters Projects

With the advent of thin film technology and more recently its applications in microelectronics and control of surface properties, the interest in mechanical properties of thin films has grown tremendously. Mechanical defects such as creep, fracture and adhesion loss, play a very important role in physical instabilities of thin film materials. An acoustic microscope has been built to study mechanical properties of thin-films. The microscope operates at a nominal frequency of 50 MHz. Rayleigh surface waves velocities on the surface of film-substrate systems were measured from V(z) curves generated by the acoustic microscope. V(z) curves are produced from interference between …


Voltage Responses To Optical Pulses Of Unbiased Normal And Superconducting Samples, D. Van Vechten, K. S. Wood, G. G. Fritz, J. S. Horitz, G. M. Daly, J. B. Thrasher, D. M. Photiadis, J. Ding, J. F. Pinto, M. G. Blamire, G. Burnell, A. L. Gyulamiryan, V. H. Vartanyan, R. B. Akopyan, Armen Gulian Jan 1997

Voltage Responses To Optical Pulses Of Unbiased Normal And Superconducting Samples, D. Van Vechten, K. S. Wood, G. G. Fritz, J. S. Horitz, G. M. Daly, J. B. Thrasher, D. M. Photiadis, J. Ding, J. F. Pinto, M. G. Blamire, G. Burnell, A. L. Gyulamiryan, V. H. Vartanyan, R. B. Akopyan, Armen Gulian

Mathematics, Physics, and Computer Science Faculty Articles and Research

The direct transformation of the energy of an incident high-energy photon into a measurable potential difference within an absorbing metal is investigated. Experimental evidence is presented that the effect arises from the inherent energy dependence of the electronic density of states, rather than from a simple temperature excursion. The similarities between the results on Al and YBa2Cu3O7 samples indicate that the effect is universal in nature. We assert it may be used as the basis of a fast, energy resolving, individual photon detector for the ultraviolet radiation and x-rays.


Effective Hamiltonian In The Problem Of A "Central Spin" Coupled To A Spin Environment, I Tupitsyn, Nikolai Prokof'ev, P Stamp Jan 1997

Effective Hamiltonian In The Problem Of A "Central Spin" Coupled To A Spin Environment, I Tupitsyn, Nikolai Prokof'ev, P Stamp

Physics Department Faculty Publication Series

We consider here the problem of a "giant spin", with spin quantum number S≫1, interacting with a set of microscopic spins. Interactions between the microscopic spins are ignored. This model describes the low-energy properties of magnetic grains or magnetic macromolecules (ferromagnetically or antiferromagnetically ordered) interacting with a surrounding spin environment, such as nuclear spins. Our aim is to give a general method for truncating the model to another one, valid at low energies, in which a two-level system interacts with the environmental spins, and higher energy terms are absorbed into a new set of couplings. This is done using an …


Reflection High-Energy Electron-Diffraction Study Of Melting And Solidification Of Pb On Graphite, Z. H. Zhang, P. Kulatunga, H. E. Elsayed-Ali Jan 1997

Reflection High-Energy Electron-Diffraction Study Of Melting And Solidification Of Pb On Graphite, Z. H. Zhang, P. Kulatunga, H. E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

The melting and solidification of Pb thin films on pyrolytic graphite are investigated in situ by reflection high-energy electron diffraction. Thin films with thicknesses of 4-150 monolayers are investigated. The surface morphology of the thin films were studied by scanning electron microscopy. Superheating of the Pb thin films by 4±2 to 12±2 K is observed from diffraction intensity measurements. Upon cooling the substrate, the Pb on graphite is seen to supercool by ∼69±4 K.


Femtosecond Photoemission Study Of Ultrafast Electron Dynamics On Cu(100), J. Cao, Y. Gao, R. J. D. Miller, Hani E. Elsayed-Ali, D. A. Mantell Jan 1997

Femtosecond Photoemission Study Of Ultrafast Electron Dynamics On Cu(100), J. Cao, Y. Gao, R. J. D. Miller, Hani E. Elsayed-Ali, D. A. Mantell

Electrical & Computer Engineering Faculty Publications

The energy dependence of the relaxation of photoexcited electrons in copper was measured using femtosecond time-resolved photoemission spectroscopy to within 0.3 eV above the Fermi level. By performing lifetime measurements under different surface conditions, several surface dynamical processes were investigated. In particular, an anomalous long lifetime feature, which cannot be explained with Fermi-liquid theory, was observed in the lifetime-energy curve. This feature was found originating from the photoexcitation of the strongly localized Cu 3d electrons. ©1997 American Physical Society


Internal Forces In Nondegenerate 2d Electron Systems, Christopher Fang-Yen, M Dykman, M Lea Dec 1996

Internal Forces In Nondegenerate 2d Electron Systems, Christopher Fang-Yen, M Dykman, M Lea

Christopher Fang-Yen

No abstract provided.