Physics Commons^™

First Measurement Of The Polarization Observable E In The P→ (Ɣ→, Π+) In Reaction Up To 2.25 Gev, S. Strauch, W. J. Briscoe, M. Döring, E. Klempt, V. A. Nikonov, E. Pasyuk, D. Rönchen, A.V. Sarantsev, I. Strakovsky, R. Workman, K. P. Adhikari, D. Adikaram, L. El Fassi

Physics Faculty Publications

First results from the longitudinally polarized frozen-spin target (FROST) program are reported. The double-polarization observable E, for the reaction ɣ^→p^→→π+n, has been measured using a circularly polarized tagged-photon beam, with energies from 0.35 to 2.37 GeV. The final-state pions were detected with the CEBAF Large Acceptance Spectrometer in Hall B at the Thomas Jefferson National Accelerator Facility. These polarization data agree fairly well with previous partial-wave analyses at low photon energies. Over much of the covered energy range, however, significant deviations are observed, particularly in the high-energy region where high-L multipoles contribute. The data have been …

Wavelength Dependent Specific Plasmon Resonance Coupling Of Single Silver Nanoparticles With Egfp, Kerry J. Lee, Tao Huang, Prakash D. Nallathamby

Chemistry & Biochemistry Faculty Publications

Noble metal nanoparticles (NPs) possess unique plasmonic properties, enabling them to serve as sub-diffraction light sources and nano-antennae for a wide range of applications. Here we report the specific interaction of single Ag NPs with single EGFP molecules and a high dependence of their interaction upon localized-surface-plasmon-resonance (LSPR) spectra of single Ag NPs and EGFP. The LSPR spectra of single red Ag NPs show a stunning 60 nm blue-shift during their incubation with EGFP, whereas they remain unchanged during their incubation with bovine serum albumin (BSA). Interestingly, the peak wavelengths of the LSPR spectra of green and blue Ag NPs …

In-Package Atmospheric Pressure Cold Plasma Treatment Of Cherry Tomatoes, N. Misra, Kevin Keener, Paula Bourke, J Mosnier, Patrick Cullen

Articles

Cold plasma is increasingly under research for decontamination of foods, especially fresh fruits and vegetables. The effect of cold plasma on food quality, however, remains under researched. This study investigates the effects of cold plasma generated within a sealed package from a dielectric barrier discharge on the physical quality parameters and respiration rates of cherry tomatoes. Respiration rates and weight loss were monitored continuously, while other parameters are reported at the end of storage period. Differences among weight loss, pH and firmness for control and treated cherry tomatoes were insignificant towards the end of storage life. Changes in respiration rates …

Sensitive And Specific Discrimination Of Pathogenic And Nonpathogenic Escherichia Coli Using Raman Spectroscopy - A Comparison Of Two Multivariate Analysis Techniques, Steven Rehse, Khozima Hamasha, Qassem I. Mohaidat, Russell A. Putnam, Ryan C. Woodman, Sunil Palchaudhuri

Physics Publications

The determination of bacterial identity at the strain level is still a complex and time-consuming endeavor. In this study, visible wavelength spontaneous Raman spectroscopy has been used for the discrimination of four closely related Escherichia coli strains: pathogenic enterohemorrhagic E. coli O157:H7 and non-pathogenic E. coli C, E. coli Hfr K-12, and E. coli HF4714. Raman spectra from 600 to 2000 cm-1 were analyzed with two multivariate chemometric techniques, principal component-discriminant function analysis and partial least squares-discriminant analysis, to determine optimal parameters for the discrimination of pathogenic E. coli from the non-pathogenic strains. Spectral preprocessing techniques such as smoothing with …

Spatial And Spectral Performance Of A Chromotomosynthetic Hyperspectral Imaging System, Randall L. Bostick, Glen P. Perram

Faculty Publications

The spatial and spectral resolutions achievable by a prototype rotating prism chromotomosynthetic imaging (CTI) system operating in the visible spectrum are described. The instrument creates hyperspectral imagery by collecting a set of 2D images with each spectrally projected at a different rotation angle of the prism. Mathematical reconstruction techniques that have been well tested in the field of medical physics are used to reconstruct the data to produce the 3D hyperspectral image. The instrument operates with a 100 mm focusing lens in the spectral range of 400–900 nm with a field of view of 71.6 mrad and angular resolution of …

The Role Of Llnl's Fast Calibration Facility In Diagnosing Nif Fusion Plasmas, Joshua G. Thompson, Carey Scott, Greg V. Brown

STAR Program Research Presentations

The Fusion and Astrophysics (FAST) Calibration and Diagnostic Facility uses the original Electron Beam Ion Trap (EBIT-I) to profile x-ray filters that are used in the Dante Soft X-Ray Diagnostic at the National Ignition Facility (NIF). FAST has an advantage over any other facility not only for its high accuracy, but also for its proximity to NIF in the Lawrence Livermore National Laboratory (LLNL). This makes for highly accurate and near-instantaneous filter calibration turnover.

EBIT-I was first constructed to create, trap, and observe static highly charged ions (HCIs) and conduct experimental astrophysics (creating an x-ray spectroscopy catalogue of ions). To …

Laboratory Astrophysics: Using Ebit Measurements To Interpret High Resolution Spectra From Celestial Sources, Carey Scott, Joshua Thompson, N. Hell, Greg V. Brown

STAR Program Research Presentations

Astrophysicists use radiation to investigate the physics controlling a variety of celestial sources, including stellar atmospheres, black holes, and binary systems. By measuring the spectrum of the emitted radiation, astrophysicists can determine a source’s temperature and composition. Accurate atomic data are needed for reliably interpreting these spectra. Here we present an overview of how LLNL’s EBIT facility is used to put the atomic data on sound footing for use by the high energy astrophysics community.

Poincare Recurrence And Spectral Cascades In Three-Dimensional Quantum Turbulence, George Vahala, Jeffrey Yepez, Linda L. Vahala, Min Soe, Bo Zhang, Sean Ziegeler

Electrical & Computer Engineering Faculty Publications

The time evolution of the ground state wave function of a zero-temperature Bose-Einstein condensate (BEC) gas is well described by the Hamiltonian Gross-Pitaevskii (GP) equation. Using a set of appropriately interleaved unitary collision-stream operators, a qubit lattice gas algorithm is devised, which on taking moments, recovers the Gross-Pitaevskii (GP) equation under diffusion ordering (time scales as length²). Unexpectedly, there is a class of initial states whose Poincaré recurrence time is extremely short and which, as the grid resolution is increased, scales with diffusion ordering (and not as length³). The spectral results of J. Yepez et al. …

Core-Level Spectroscopy Of The Pd/W(110) Interface: Evidence Of Long-Range Pd-Island—Winteractions At Submonolayer Coverages, D. Mark Riffe, N. D. Shinn, B. Kim, K. J. Kim, T. H. Kang

All Physics Faculty Publications

We have measured W 4f_7/2 core-level photoemission spectra from W(1 1 0) in the presence of Pd overlayers for coverages up to ∼1 pseudomorphic monolayer (ML). At coverages close to 0.05 ML a striking change in the W core-level spectrum is observed, which we interpret as indicating a long-range lateral effect of 2D Pd islands upon the W electronic structure in both the first and second W layers. As the coverage increases the long-range effect weakens and finally vanishes near 0.85 ML. Above this coverage the W spectra are typical for a W-based bimetallic interface, with the first-layer …

Measurement Of Direct Ƒ0(980) Photoproduction On The Proton, M. Battaglieri, Gerard P. Gilfoyle, Et. Al.

Physics Faculty Publications

We report on the results of the first measurement of exclusive ƒ₀(980) meson photoproduction on protons for E_γ = 3.0–3.8 GeV and -t = 0.4–1.0 GeV^2. Data were collected with the CLAS detector at the Thomas Jefferson National Accelerator Facility. The resonance was detected via its decay in the π⁺ π^- channel by performing a partial wave analysis of the reaction γ p → pπ⁺π^-. Clear evidence of the ƒ₀(980) meson was found in the interference between P and S waves at M_{π⁺π …}

Spectroscopic Study Of The Dimerisation Process Of Iron Protoporphyrin Ix, K. Dziedzic-Kocurek, Hugh Byrne, A. Swiderski, J. Stanek

Articles

The commercial protoporphyrin IX, iron-ferriprotoporphyrin IX-chloride and synthesized iron porphyrin μ-oxo-dimers were examined by UV/vis absorption and fluorescence, Fourier transformed infrared spectroscopy, resonance Raman, X-ray absorption, Mössbauer spectroscopy and SQUID. The evidence of Fe-O-Fe antiferromagnetic coupling concluded from SQUID and Mössbauer in the case of samples containing dimerized forms confirmed the presence of the oxo-bridges. In this paper the results of UV/vis, fluorescence, Fourier transform infrared FTIR and Raman spectroscopies are reported and discussed. The study is based on the comparison of the free-base protoporphyrin IX, Fe-PPIX-Cl and the synthesized dimerized specimen. The vibrational modes in two energy regions i.e. …

Measurement Of Direct Fₒ(980) Photoproduction On The Proton, K. P. Adhikari, H. Bagdasaryan, S. Bültmann, S. L. Careccia, K. V. Dharmawardane, G. E. Dodge, N. Kalantarians, A. Klein, A.V. Klimenko, S. E. Kuhn, J. Lanchiet, M. R. Niroula, J. Zhang

Physics Faculty Publications

We report on the results of the first measurement of exclusive f₀(980) meson photoproduction on protons for E_γ = 3.0–3.8  GeV and −t = 0.4–1.0  GeV² . Data were collected with the CLAS detector at the Thomas Jefferson National Accelerator Facility. The resonance was detected via its decay in the π⁺π⁻ channel by performing a partial wave analysis of the reaction γp→pπ⁺π⁻ . Clear evidence of the f₀(980) meson was found in the interference between P and S waves at M _π+π− ∼1  GeV. The S -wave differential …

Superfluid Turbulence From Quantum Kelvin Wave To Classical Kolmogorov Cascades, Jeffrey Yepez, George Vahala, Linda L. Vahala, Min Soe

Electrical & Computer Engineering Faculty Publications

The main topological feature of a superfluid is a quantum vortex with an identifiable inner and outer radius. A novel unitary quantum lattice gas algorithm is used to simulate quantum turbulence of a Bose-Einstein condensate superfluid described by the Gross-Pitaevskii equation on grids up to 5760³. For the first time, an accurate power-law scaling for the quantum Kelvin wave cascade is determined: k^-3. The incompressible kinetic energy spectrum exhibits very distinct power-law spectra in 3 ranges of k space: a classical Kolmogorov k^-(5/3) spectrum at scales greater than the outer radius of individual quantum vortex …

Core-Level Spectroscopy Of The Ni/W(110) Interface: Correlation Of W Interfacial Core Levelshifts With First-Layer Ni Phases, D. Mark Riffe, R. T. Franckowiak, N. D. Shinn, B. Kim, K. J. Kim, T. H. Kang

All Physics Faculty Publications

We have measured W 4f_7/2 core-level photoemission spectra from W(1 1 0) in the presence of Ni overlayers, from ∼0.2 to ∼3 monolayers. Interfacial core-level shifts associated with first-layer Ni phases have been identified: −230 ± 15 meV for the 1 × 1 pseudomorphic phase and −70 ± 7 meV for the 7 × 1 close-packed commensurate phase. At higher Ni coverages the interfacial core-level shift is −100 ± 10 meV. These shifts are analyzed using the partial-shift model of Nilsson et al. [Phys. Rev. B 38 (1988) 10357]; the analysis indicates that the difference in binding energies between …

A Six-Dimensional H2–H2 Potential Energy Surface For Bound State Spectroscopy, Robert Hinde

Chemistry Publications and Other Works

We present a six-dimensional potential energy surface for the (H₂)₂ dimer based on coupled-cluster electronic structure calculations employing large atom-centered Gaussian basis sets and a small set of midbond functions at the dimer’s center of mass. The surface is intended to describe accurately the bound and quasibound states of the dimers (H₂)₂, (D₂)₂, and H₂–D₂ that correlate with H₂ or D₂ monomers in the rovibrational levels (v, j) =(0,0), (0,2), (1,0), and (1,2). We employ a close-coupled approach to compute the …

Potential Of Vibrational Spectroscopy In The Diagnosis Of Human Tumours., Eoghan O'Faolain

Doctoral

Just fewer than 20,000 people are annually diagnosed with some form of cancer in Ireland and one in three people are likely to contract some form of cancer by age 74. With the number of cases increasing at an annual rate of 2%, the early detection and treatment of cancer is becoming increasingly important. Both IR and Raman spectroscopy offer the potential for real time, quantitative detection of cancer and even precancer. This study investigates the potential of Raman and Fourier transform infrared, both benchtop and synchrotron spectroscopies for the detection of cervical cancer. The tissue was classified and its …

High-Temperature Calcium Vapor Cell For Spectroscopy On The 4s2 1s0-4s4p 3p1 Intercombination Line, Christopher J. Erickson, Brian Neyenhuis, Dallin S. Durfee

Faculty Publications

We have demonstrated a high-temperature vapor cell for absorption spectroscopy on the Ca intercombination line. The cell uses a dual-chamber design to achieve the high temperatures necessary for an optically dense vapor while avoiding the necessity of high-temperature vacuum valves and glass-to-metal seals. We have observed over 50% absorption in a single pass through the cell. Although pressure broadening in the cell prevented us from performing saturated-absorption spectroscopy, the broadening resulted in higher signal-to-noise ratios by allowing us to probe the atoms with intensities much greater than the 0.2µW/cm2 saturation intensity of the unbroadened transition. The techniques presented in this …

Interaction Of Single Walled Carbon Nanotubes With Starch-Based Systems, Alan Casey, Gerald Farrell, Mary Mcnamara, Hugh Byrne, Gordon Chambers

Conference papers

The interaction of carbon nanotubes with soft organic molecules such as cyclodextrins and other saccharides has recently been shown to produce water-soluble composites. Such systems offer considerable advantages over polymer based composites due to their biocompatibility and noncovalent coupling which can potentially preserve the unique properties of the tubes. The mechanism of interaction of such systems has been proposed to be dominated by hydrophobic and hydrophilic interactions along the surface of the tube. In this study a number of composite systems have been formed with HiPco carbon nanotubes using starch and starch based polymers. The first composite formed with starch …

Relativistic And Radiative Corrections To The Mollow Spectrum, Jorg Evers, Ulrich D. Jentschura, Christoph H. Keitel

Physics Faculty Research & Creative Works

The incoherent inelastic part of the resonance fluorescence spectrum of a laser-driven atom is known as the Mollow spectrum [B. R. Mollow, Phys. Rev. 188, 1969 (1969)]. Starting from this level of description, we discuss theoretical foundations of high-precision spectroscopy using the resonance fluorescence light of strongly laser-driven atoms. Specifically, we evaluate the leading relativistic and radiative corrections to the Mollow spectrum, up to the relative orders of ( Z α )² and α ( Z α )² , respectively, and Bloch-Siegert shifts as well as stimulated radiative corrections involving off-resonant virtual states. Complete results are provided for …

Infrared-Active Vibron Bands Associated With Substitutional Impurities In Solid Parahydrogen, Robert Hinde

Chemistry Publications and Other Works

We present a model for the line shapes of infrared-active Q₁(0) vibron bands observed in solid parahydrogen doped with low concentrations of spherical substitutional impurities. The line shapes are highly sensitive to the H₂ vibrational dependence of the dopant–H₂ interaction. When this vibrational dependence is strong, the dopant can trap the infrared-active vibron in its first solvation shell; in this case, the trapped vibron manifests itself in the absorption spectrum as a narrow feature to the red of the pure solid’s vibron band.

Nanoindentation And Strain Characteristics Of Nanostructured Boride/Nitride Films, Niklas Hellgren, R A. Andrievskii, G V. Kalinnikov, P Sandstrom, D V. Shtanskii

Educator Scholarship & Departmental Newsletters

The hardness, elastic modulus, and elastic recovery of nanostructured boride/nitride films 1–2 µm thick have been investigated by the nanoindentation technique under the maximum loads over a wide range (from 5 to 100 mN). It is demonstrated that only the hardness parameters remain constant at small loads (5–30 mN). The data obtained are discussed and compared with the parameters determined by other methods.

Concept Of Local Polaritons And Optical Properties Of Mixed Polar Crystals, Lev I. Deych, Alexey Yamilov, Alexander A. Lisyansky

Physics Faculty Research & Creative Works

The concept of local polaritons is used to describe the optical properties of mixed crystals in the frequency region of their restrahlen band. It is shown that this concept allows for a physically transparent explanation of the presence of weak features in the spectra of so-called one-mode crystals and for one-two mode behavior. The previous models Were able to explain these features only with the use of many fitting parameters. We show that under certain Conditions new impurity-induced polariton modes may arise within the restrahlen of the host crystals, and study their dispersion laws and density of states. Particularly, we …

Inception Of Snapover And Gas Induced Glow Discharges, J. T. Galofaro, B. V. Vayner, D. C. Ferguson, W. A. Degroot, C. D. Thomson, John R. Dennison, R. E. Davies

All Physics Faculty Publications

Ground based experiments of the snapover phenomenon were conducted in the large vertical simulation chamber at the Glenn Research Center (GRC) Plasma Interaction Facility (PIF). Two Penning sources provided both argon and xenon plasmas for the experiments. The sources were used to simulate a variety of ionospheric densities pertaining to a spacecraft in a Low Earth Orbital (LEO) environment. Secondary electron emission is believed responsible for dielectric surface charging, and all subsequent snapover phenomena observed. Voltage sweeps of conductor potentials versus collected current were recorded in order to examine the specific charging history of each sample. The average time constant …

Analysis Of Scanning Tunneling Optical Spectroscopy Applied To Narrow Gap Semiconductors, James D. Patterson, James G. Mantovani

Aerospace, Physics, and Space Science Faculty Publications

Homogeneous II-VI narrow gap semiconducting alloys are of interest because of their use in infrared detectors. These compound semiconductor materials are inherently difficult to grow in bulk due to gravity induced convective flows. A microgravity growth environment has therefore been considered. In order to evaluate the quality of crystals grown in space compared to those grown on the ground, it is necessary to characterize both. One important aspect of this characterization is the study of stoichiometry, x. A characterization scheme using scanning tunneling optical spectroscopy (STOS) involves determining the spectral response of the photoexcited tunneling current for a semiconductor. By …

Spectroscopy Of Atoms Confined To The Single Node Of A Standing Wave In A Parallel-Plate Cavity, V. Sandoghar, C. I. Sukenik, S. Haroche, E. A. Hinds

Physics Faculty Publications

We have performed spectroscopy on sodium atoms that are optically channeled in the single node of a laser standing wave set up across a parallel-plate cavity. Using this technique we have extended our previous measurement of the Lennard-Jones van der Waals energy-level shift [Sandoghdar et al., Phys. Rev. Lett. 68, 3432 (1992)] down to a cavity width of ~500 nm. We discuss the applications of this technique to the precise measurement of atom-surface distances.

Basic Astronomy Labs, Terry L. Smith, Michael D. Reynolds, Jay S. Huebner

Physics Faculty Research and Scholarship

Providing the tools and know-how to apply the principles of astronomy first-hand, these 43 laboratory exercises each contain an introduction that clearly shows budding astronomers why the particular topic of that lab is of interest and relevant to astronomy. About one-third of the exercises are devoted solely to observation, and no mathematics is required beyond simple high school algebra and trigonometry.Organizes exercises into six major topics—sky, optics and spectroscopy, celestial mechanics, solar system, stellar properties, and exploration and other topics—providing clear outlines of what is involved in the exercise, its purpose, and what procedures and apparatus are to be used. …

Visible Luminescence From Single Crystal‐Silicon Quantum Wells, Peter N. Saeta, A. C. Gallagher

All HMC Faculty Publications and Research

Single crystal‐silicon quantum wells with SiO₂ barriers have been grown from SIMOX silicon‐on‐insulator substrates. Photoluminescence in the red and near‐infrared is observed for average well width <8 >nm, with peak signal for 2‐nm average width. The luminescence spectrum is independent of well width for SiO₂ barriers, but shifts 0.3 eV to higher energy upon removal of the upper oxide layer with HF. Both results suggest the importance of radiation from surface states.

Mesostructure Of Photoluminescent Porous Silicon, David D. Allred, F. Ruiz, C. Vázquez-López, Jesus González-Hernández, G. Romero-Paredes, R. Peña-Sierra, G. Torres-Delgado

Faculty Publications

Scanning electron microscopy, atomic force microscopy, and Raman spectroscopy were used to characterize the microstructure of photoluminescent porous silicon (PS) layers formed by the anodic etching (HF:H2O:ethanol), at various current densities, of p-type (100) silicon wafers possessing resitivity in the range 1-2 Ω cm. Existing models for the origin of luminescence in PS are not supported by our observations. Cross-sectional as well as surface atomic force micrographs show the material to be clumpy rather than columnar; rodlike structures are not observed down to a scale of 40 nm. A three-dimensional model of the mesostructure of porous silicon is discussed. Room-temperature …

Self-Consistent Determination Of Electronic Structure And Elementary Excitations Of Finite Modulation-Doped Superlattices, Roger H. Yu

All Faculty Scholarship for the College of the Sciences

A self-consistent framework for the study of the electronic level structure of finite superlattices has been proposed. One of the surface states (Tamm states) found in our calculation crosses the Fermi energy in the energy gap when the depletion effect near the surface increases. We have shown the existence of low-energy Tamm states in our calculation when the surface barrier is lower than that of the interior. The electronic excitations of the superlattice have been studied via the electron-energy-loss function within the random-phase approximation. Two plasmon modes (well above the phonon response frequency) due to the Tamm states have also …

Nature Of Carbon-Carbon Bonding In Evaporated And Ion-Sputtered (Diamondlike) Amorphous Carbon From (E, 2e) Spectroscopy, Chao Gao, Yun Yu Wang, A. L. Ritter, John R. Dennison

All Physics Faculty Publications

The local carbon-carbon bonding in evaporated (e-C) and ion-sputtered (i-C) amorphous carbon has been investigated by transmission electron-energy-loss spectroscopy (EELS) and by (e, 2e) spectroscopy. The EELS data indicate that the e-C is graphiclike and the i-C is diamondlike. The (e, 2e) data demonstrate that the concentration of sp² bonding is ∼100% in both materials (0.85≤c_sp²≤1.0) for e-C and 0.75≤c_sp²≤1.0 for i-C). There is significant rehybridization of the π orbital in i-C.