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Diffusion

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Full-Text Articles in Physics

Surface Relief Profile Of Photopolymerisable Systems In A Single Illuminated Spot, Tsvetanka Babeva, Dana Mackey, Izabela Naydenova, Suzanne Martin, Vincent Toal Jan 2009

Surface Relief Profile Of Photopolymerisable Systems In A Single Illuminated Spot, Tsvetanka Babeva, Dana Mackey, Izabela Naydenova, Suzanne Martin, Vincent Toal

Conference Papers

The formation of surface relief profile in photopolymerisable systems when illuminated with a focused beam of light is simulated numerically using a two-way diffusion model that accounts both for monomer and short polymer chains diffusion. The concentration and spatial distribution dynamics of monomer, short and long polymer chains are calculated. It is assumed that the surface profile is a linear combination of monomer and polymer concentration with appropriate coefficients accounting for polymer shrinkage. A good agreement between the calculated and the experimentally measured profiles is observed thus demonstrating the successful application of the two way diffusion in modeling this system.


Two Way Diffusion Model For The Recording Mechanism In A Self-Developing Dry Acrylamide Photopolymer, Suzanne Martin, Izabela Naydenova, Raghavendra Jallapuram, Robert Howard, Vincent Toal Jan 2006

Two Way Diffusion Model For The Recording Mechanism In A Self-Developing Dry Acrylamide Photopolymer, Suzanne Martin, Izabela Naydenova, Raghavendra Jallapuram, Robert Howard, Vincent Toal

Conference Papers

In our most recent study [1] diffusion constants were measured in the simplified monoacrylamide version of a dry acrylamide based photopolymer holographic recording material developed in the Centre for Industrial and Engineering Optics. In this paper we report diffusion constants for the commonly used photopolymer formulation, which also contains the crosslinker bisacrylamide. A physical model for the recording mechanism is proposed which explains the two way diffusion observed in both systems, and is in agreement with much of the previously observed behaviour of the material, particularly in regard to dependence of diffraction efficiency growth on spatial frequency and persistence of …