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Peter Dowben Publications

Photoemission

2006

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Cobaltocene Adsorption And Dissociation On Cu(1 1 1), Jaewu Choi, Peter A. Dowben Aug 2006

Cobaltocene Adsorption And Dissociation On Cu(1 1 1), Jaewu Choi, Peter A. Dowben

Peter Dowben Publications

Photoemission results indicate that the initial adsorption of cobaltocene on Cu(1 1 1) at 150 K leads to molecular fragmentation, but with subsequent cobaltocene exposures, molecular absorption occurs. The molecularly adsorbed species is either adsorbed with only a fraction of molecules adopting a preferential orientation along the surface normal or adsorbed with the molecular axis away from the surface normal. This adsorption behavior is compared to nickelocene and ferrocene adsorption.