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Full-Text Articles in Physics
Development Of Photopolymer Material With Improved Dynamic Range And Sensitivity, Brian Rogers, Izabela Naydenova, Suzanne Martin
Development Of Photopolymer Material With Improved Dynamic Range And Sensitivity, Brian Rogers, Izabela Naydenova, Suzanne Martin
Conference Papers
In this study the effect of the concentration of acrylamide and the influence of different initiators in a photopolymer composition for holographic recording of diffraction gratings is investigated. Light manipulating Holographic Optical Elements (HOEs) have a number of characteristics which can be optimised for different roles. However, at the core of these devices is the refractive index modulation that has been created in the material during recording. Typically higher refractive index modulation will enable greater diffraction efficiency. Solar concentrating HOEs can particularly benefit from material that experiences higher refractive index modulation. For a solar concentrator to have a high acceptance …
Serialised Holography For Brand Protection And Authentication, Dinesh Vather, Izabela Naydenova, Dervil Cody, Monika Zawadzka, Suzanne Martin, Emilia Mihaylova, Stephen Curran, Paul Duffy, Josune Portillo, Daniel Connell, Stephen Mcdonnell, Vincent Toal
Serialised Holography For Brand Protection And Authentication, Dinesh Vather, Izabela Naydenova, Dervil Cody, Monika Zawadzka, Suzanne Martin, Emilia Mihaylova, Stephen Curran, Paul Duffy, Josune Portillo, Daniel Connell, Stephen Mcdonnell, Vincent Toal
Articles
The problems presented by counterfeit products and documentation are discussed. Limitations of existing holograms for anti-counterfeit applications are described. We describe the advantages of full holographic serialisation and the requirements in terms of materials and techniques for mass production of true serialised holograms. These requirements having been met, we report for the first time the mass production of fully serialised holograms. The novelty of approach consists of the direct use of product manufacturer’s information as the object in a holographic recording system along with a self-processing photopolymer and modular optical system to facilitate mass production of truly serialised volume holograms. …
Determination Of The Polymerisation Rate Of A Low-Toxicity Diacetone Acrylamide-Based Holographic Photopolymer Using Raman Spectroscopy, Dervil Cody, Emilia Mihaylova, Luke O'Neill, Izabela Naydenova
Determination Of The Polymerisation Rate Of A Low-Toxicity Diacetone Acrylamide-Based Holographic Photopolymer Using Raman Spectroscopy, Dervil Cody, Emilia Mihaylova, Luke O'Neill, Izabela Naydenova
Articles
The polymerisation rate of a low-toxicity Diacetone Acrylamide (DA)-based photopolymer has been measured for the first time using Raman spectroscopy. A value for the polymerisation rate of 0.020 s−1 has been obtained for the DA photopolymer by modelling the polymerisation reaction dynamics as a stretched exponential or Kohlrausch decay function. This is significantly lower than the polymerisation rate of 0.100 s−1 measured for the well known Acrylamide (AA)-based photopolymer composition. The effect of the additive glycerol on the polymerisation rate of the DA-based photopolymer has also been investigated. The inclusion of glycerol is observed to increase the rate …
Low-Toxicity Diacetone Acrylamide-Based Photopolymer For Applications In Holography, Dervil Cody
Low-Toxicity Diacetone Acrylamide-Based Photopolymer For Applications In Holography, Dervil Cody
Doctoral
Photopolymers are fast becoming one of the most popular holographic recording media due to their suitability for a wide range of holographic applications, such as sensors, diffractive optics and data storage. The majority of the investigated water-soluble holographic photopolymers are Acrylamide (AA) based. However, the toxic and carcinogenic nature of AA is a growing concern. In order for photopolymer recording media to be a viable option for holographic applications, efforts must be made to remove any occupational and environmental hazards involved in large-scale material development and device fabrication. The main objective of the work presented here is the development and …
Holographic Sensors: Three-Dimensional Analyte-Sensitive Nanostructures And Their Applications, Ali K. Yetisen, Izabela Naydenova, Fernando Da Cruz Vasconcellos, Jeffrey Blyth, Christopher R. R. Lowe
Holographic Sensors: Three-Dimensional Analyte-Sensitive Nanostructures And Their Applications, Ali K. Yetisen, Izabela Naydenova, Fernando Da Cruz Vasconcellos, Jeffrey Blyth, Christopher R. R. Lowe
Articles
Holographic sensors are analytical devices that systematically diffract narrow-band light in the ultraviolet to near-infrared range for application in the detection and quantification of analytes and/or physical parameters. They can be functionalized with analyte-responsive materials to construct highly sensitive optical sensors for use in testing, where a visual readout, fast turnaround time, and reversibility are needed. Holography allows fabrication of disposable sensors that are lightweight for miniaturization and multiplexing purposes.3 Holographic sensors offer three capabilities on a single analytical device: (i) label-free analyte-responsive polymer, (ii) real-time, reversible quantification of the external stimuli, and (iii) three-dimensional visual image display.
Humidity And Temperature Effect On Properties Of Transmission Gratings Recorded In Pva/Aa-Based Photopolymer Layers, Tatsiana Mikulchyk, Suzanne Martin, Izabela Naydenova
Humidity And Temperature Effect On Properties Of Transmission Gratings Recorded In Pva/Aa-Based Photopolymer Layers, Tatsiana Mikulchyk, Suzanne Martin, Izabela Naydenova
Articles
This paper explores the effects of humidity on gratings recorded in a polyvinylalcohol–acrylamide photopolymer medium. Investigation of the behaviour of transmission gratings exposed to high humidity is of significant interest for two reasons, firstly because the grating's sensitivity to humidity can be exploited for the development of irreversible humidity indicators, secondly because too much sensitivity to humidity can limit the use of these materials in applications where an environmentally stable hologram is needed. In this paper we focus on the effect of high humidity on the properties of volume phase transmission gratings recorded in PVA/AA photopolymer layers in the temperature …
Research On Holographic Sensors And Novel Photopolymers At The Centre For Industrial And Egnineering Optics, Emilia Mihaylova, Dervil Cody, Izabela Naydenova, Suzanne Martin, Vincent Toal
Research On Holographic Sensors And Novel Photopolymers At The Centre For Industrial And Egnineering Optics, Emilia Mihaylova, Dervil Cody, Izabela Naydenova, Suzanne Martin, Vincent Toal
Books/Book Chapters
The recent resurgence of interest in photopolymers for commercial holograms is a strong incentive for development of photopolymers that are as environmentally friendly as possible. Photopolymer materials consist of a light-sensitive film which is exposed during production to form the hologram, thereby offering versatility well beyond that of current security holograms, which are mass produced from a master using a foil stamping processes.
Holographic Recording In Corona Charged Acrylamide-Based Mfi-Zeolite Photopolymer, Temenujka Yovcheva, Izabela Naydenova, Simeon Sainov, Vincent Toal, Svetlana Mintova
Holographic Recording In Corona Charged Acrylamide-Based Mfi-Zeolite Photopolymer, Temenujka Yovcheva, Izabela Naydenova, Simeon Sainov, Vincent Toal, Svetlana Mintova
Articles
The influence of corona charging on holographic recording in acrylamide-based photopolymer nanocomposite containing MFI zeolite nanoparticles has been studied. The holographic recording was carried out in two different geometries —transmission grating recording and total internal reflection grating recording. During the recording process, the layers were charged in a corona field. It was observed that independently of the corona polarity, in the case of transmission geometry of recording, the corona charging led to a decrease in the diffraction efficiency (DE) of the grating. In the case of the total internal reflection grating, the DE increased in the corona field presence.
In-Plane Sensitive Electronic Speckle Pattern Interferometer Using A Diffractive Holographic Optical Element, Raghavendra Jallapuram, Con Healy, Emilia Mihaylova, Vincent Toal
In-Plane Sensitive Electronic Speckle Pattern Interferometer Using A Diffractive Holographic Optical Element, Raghavendra Jallapuram, Con Healy, Emilia Mihaylova, Vincent Toal
Articles
We describe a student project in electronic speckle pattern interferometry. The project includes holographic recording of diffraction gratings in thick, self-processing photopolymer layers made from off-the-shelf chemicals. The gratings are employed in a simple electronic speckle pattern interferometer to measure in-plane rotation.
Photopolymerizable Nanocomposites For Holographic Recording And Sensor Application, Elsa Leite, Izabela Naydenova, Svetlana Mintova, Louis Leclercq, Vincent Toal
Photopolymerizable Nanocomposites For Holographic Recording And Sensor Application, Elsa Leite, Izabela Naydenova, Svetlana Mintova, Louis Leclercq, Vincent Toal
Articles
Novel nanocomposites consisting of a water soluble acrylamide–based photopolymer and colloidal zeolite nanoparticles of zeolite Beta and zeolite A were prepared. The interactions between the photopolymer components and zeolite nanoparticles in the photopolymerizable nanocomposites were characterized for the first time by 13C NMR and Visible spectroscopy. It was found that the zeolite Beta nanoparticles (up to 5% wt.) behave as a non-inert additive, resulting in an effective increase in layer thickness that causes doubling of the diffraction efficiency of the nanocomposite in comparison to that of the undoped photopolymer. On the other hand, the nanocomposite containing zeolite A nanoparticles showed …
Study Of The Photoinduced Surface Relief Modulation In Photopolymers Caused By Illumination With A Gaussian Beam Of Light, Tzvetanka Babeva, Dana Mackey, Suzanne Martin, Izabela Naydenova, Vincent Toal
Study Of The Photoinduced Surface Relief Modulation In Photopolymers Caused By Illumination With A Gaussian Beam Of Light, Tzvetanka Babeva, Dana Mackey, Suzanne Martin, Izabela Naydenova, Vincent Toal
Articles
The formation of surface relief profile in photopolymerisable systems when illuminated with a focused beam of light is simulated numerically using a two-way diffusion model that takes account both for monomer and short polymer chains diffusion. The concentration and spatial distribution dynamics of monomer and short and long polymer chains are calculated. The surface profile is obtained from calculated components concentrations considering different densities of monomer and polymer. The influence of the illumination time, intensity and spot diameter on the surface profiles dynamics is discussed. A good agreement between the calculated and the experimentally measured profiles is observed thus demonstrating …
Two-Way Diffusion Model For Short Exposure Holographic Grating Formation In Acrylamide-Based Photopolymer, Tzvetanka Babeva, Izabela Naydenova, Dana Mackey, Suzanne Martin, Vincent Toal
Two-Way Diffusion Model For Short Exposure Holographic Grating Formation In Acrylamide-Based Photopolymer, Tzvetanka Babeva, Izabela Naydenova, Dana Mackey, Suzanne Martin, Vincent Toal
Articles
A theoretical model for formation of a short exposure holographic grating is presented. The model accounts for both monomer and polymer diffusion and distinguishes between short polymer chains capable of diffusing and long polymer chains that are immobile. It is shown that the experimentally observed decrease of diffraction efficiency at higher spatial frequency can be predicted by assuming diffusion of short-chain polymers away from the bright fringes. The time evolution of the refractive index modulation after short exposure is calculated and compared with experimental results. The effects of diffusion coefficients, polymerization rates, intensity and spatial frequency of recording on the …
Optimisation Of An Acrylamide-Based Photopolymer System For Holographic Inscription Of Surface Patterns With Sub-Micron Resolution, Kevin Trainer, Kevin Wearen, Dimana Nazarova, Izabela Naydenova, Vincent Toal
Optimisation Of An Acrylamide-Based Photopolymer System For Holographic Inscription Of Surface Patterns With Sub-Micron Resolution, Kevin Trainer, Kevin Wearen, Dimana Nazarova, Izabela Naydenova, Vincent Toal
Articles
We describe the optimisation of the holographic patterning of sub-micrometer surface relief structures in an acrylamide-based photopolymer. A substantial improvement in the photoinduced surface relief resolution was achieved by altering the photopolymer chemical composition and by introducing a single step post recording thermal treatment of the layers. It was observed that, by optimisation of the chemical composition of the photopolymer layers, the maximum achievable spatial frequency increases from 200 l/mm to 550 l/mm. The improvement of the surface relief amplitude by alteration of the chemical composition is limited due to the fact that both decrease of the plasticiser and increase …
A Diffusion Model For Spatially Dependent Photopolymerization, Dana Mackey, Tzvetanka Babeva, Izabela Naydenova, Vincent Toal
A Diffusion Model For Spatially Dependent Photopolymerization, Dana Mackey, Tzvetanka Babeva, Izabela Naydenova, Vincent Toal
Articles
Photopolymers represent an attractive class of optical recording materials due to properties such as high refractive index modulation, dry film processing, long shelf life, etc. Applications include holographically based devices for optical storage disks, optical interconnections, optical memories and filters. This paper will address the dynamics of short-exposure holographic grating formation; a new mathematical model is proposed with the aim of understanding the experimental observations of low diffraction efficiency in high spatial frequency gratings.
Photopolymers: Beyond The Standard Approach To Photosensitisation, Izabela Naydenova, Suzanne Martin, Vincent Toal
Photopolymers: Beyond The Standard Approach To Photosensitisation, Izabela Naydenova, Suzanne Martin, Vincent Toal
Articles
A photopolymerizable material for use in the visible normally consists of a dye sensitizer, a free radical generator, monomer/monomers and, optionally, a binder, and is prepared usually as a dry or liquid film. Upon illumination with light of appropriate wavelength, a photopolymerisation reaction is triggered, leading to a change in the film’s refractive index. Because the presence of the dye is essential, the film is usually made sensitive to light during its preparation. Here we separate the film preparation and the sensitisation processes. In this way the photopolymerisation process can be used to detect dye labelled analytes, providing an alternative …
Characterisation Of The Humidity And Temperature Responses Of A Reflection Hologram Recorded In Acrylamide-Based Photopolymer, Izabela Naydenova, Raghavendra Jallapuram, Vincent Toal, Suzanne Martin
Characterisation Of The Humidity And Temperature Responses Of A Reflection Hologram Recorded In Acrylamide-Based Photopolymer, Izabela Naydenova, Raghavendra Jallapuram, Vincent Toal, Suzanne Martin
Articles
The humidity and temperature responses of a reflection hologram recorded in a self-processing photopolymer layer have been characterised by measurement of the position of the maximum intensity in the spectral response of the hologram. It has been demonstrated that such a hologram can be used for indication of the relative humidity (RH) in a specific temperature range. The operational range and reversibility of the holograms have been characterised in a controlled humidity and temperature environment. The humidity studies were carried out in the range from 10 to 80% RH and the temperature range under study was 15 – 50 ºC.
Optical And Holographic Characteristics Of Photopolymer Layers, Temenujka Yovcheva, Izabela Naydenova, Ivanka Vlaeva, Suzanne Martin, Vincent Toal, Simeon Sainov
Optical And Holographic Characteristics Of Photopolymer Layers, Temenujka Yovcheva, Izabela Naydenova, Ivanka Vlaeva, Suzanne Martin, Vincent Toal, Simeon Sainov
Articles
In the present work the optical and holographic characteristics of acrylamide-based photopolymer layers are studied. For the first time the refractive index change of a liquid acrylamide photopolymer due to exposure at 532 nm is obtained using a critical angle laser micro-refractometer. The 30 mm thick solid photopolymer films are prepared by casting on glass substrates. Bragg holographic gratings with spatial frequencies of 710 mm-1, 1050 mm-1 and 1600 mm-1 are recorded using a diode laser operating at 532 nm wavelength. The diffraction efficiency dependence on the exposure energy is investigated. The obtained results are compared with the Stetson holographic …
Optical Properties Of Photopolymerisable Nanocomposites Containing Zeolite Nanoparticles, Izabela Naydenova, Tzvetanka Babeva, Elsa Leite, Nitesh Pandey, Temenujka Yovcheva, Svetlana Mintova, Vincent Toal
Optical Properties Of Photopolymerisable Nanocomposites Containing Zeolite Nanoparticles, Izabela Naydenova, Tzvetanka Babeva, Elsa Leite, Nitesh Pandey, Temenujka Yovcheva, Svetlana Mintova, Vincent Toal
Conference Papers
Acrylamide-based photopolymerisable nanocomposites containing three different types of nanozeolites – Si-MFI, AlPO and BEA, were studied. The influence of the porous nanoparticles on the average refractive index, optical scattering, holographic recording properties and shrinkage were characterised.
Holographic Recording In Charged Photopolymerisable Nanocomposites, Temenujka Yovcheva, Ivanka Vlaeva, Simeon Sainov, Izabela Naydenova, Vincent Toal, Svetlana Mintova
Holographic Recording In Charged Photopolymerisable Nanocomposites, Temenujka Yovcheva, Ivanka Vlaeva, Simeon Sainov, Izabela Naydenova, Vincent Toal, Svetlana Mintova
Conference Papers
Self – processing photopolymers have a large number of different applications due to their versatile properties as holographic recording materials. A significant effort has been directed towards the development of photopolymers for holographic data storage [1, 2], holographic sensors [3], holographic optical elements [4] and display holograms [5]. The Centre for Industrial and Engineering Optics has been developing acrylamide based photopolymers for the last decade [6-8]. The main parameters requiring improvement in these types of photopolymers are their dynamic range and their mechanical stability during the holographic recording. Recently we have successfully used zeolite nanoparticles as dopants in order to …
Optical Patterning Of Photopolymerisable Materials, Kevin Trainer, Kevin Wearen, Dimana Nazarova, Izabela Naydenova, Vincent Toal
Optical Patterning Of Photopolymerisable Materials, Kevin Trainer, Kevin Wearen, Dimana Nazarova, Izabela Naydenova, Vincent Toal
Conference Papers
Holographic recording is an effective approach for photopolymer surface patterning. It has been previously utilised in acrylamide-based photopolymers and a spatial frequency limit of 200 l/mm has been observed. We report the successful inscription of submicrometer resolution patterns. The spatial frequency response has been extended to 1550 l/mm by introduction of thermal post recording treatment. Initial results from the optical patterning utilising a spatial light modulation (SLM) reveal that the amplitude of the photoinduced surface relief structures is larger in comparison to the amplitude obtained by holographic recording.
Recent And Emerging Applications Of Holographic Photopolymers And Nanocomposites, Izabela Naydenova, Pavani Kotakonda, Raghavendra Jallapuram, Tsvetanka Babeva, Denis Bade, Suzanne Martin, Vincent Toal, Svetlana Mintova
Recent And Emerging Applications Of Holographic Photopolymers And Nanocomposites, Izabela Naydenova, Pavani Kotakonda, Raghavendra Jallapuram, Tsvetanka Babeva, Denis Bade, Suzanne Martin, Vincent Toal, Svetlana Mintova
Conference Papers
Sensing applications of holograms may be based on effects such as change in the spacing of the recorded fringes in a holographic diffraction grating in the presence of an analyte so that the direction of the diffracted laser light changes, or, in the case of a white light reflection grating, the wavelength of the diffracted light changes. An example is a reflection grating which swells in the presence of atmospheric moisture to indicate relative humidity by a change is the colour of the diffracted light. These devices make use of the photopolymer’s ability to absorb moisture. In a more versatile …
A Visual Indication Of Environmental Humidity Using A Colour Changing Hologram Recorded In A Self-Developing Photopolymer, Izabela Naydenova, Raghavendra Jallapuram, Vincent Toal, Suzanne Martin
A Visual Indication Of Environmental Humidity Using A Colour Changing Hologram Recorded In A Self-Developing Photopolymer, Izabela Naydenova, Raghavendra Jallapuram, Vincent Toal, Suzanne Martin
Articles
A reflection hologram for visual indication of environmental humidity has been studied. The hologram is recorded in a self-developing photopolymer and changes colour when exposed to a change in humidity and is fully reversible. The range of colour change, reversibility and the response time of the hologram have been studied in a controlled humidity environment. Fully reversible holograms with response times from few seconds to tens of minutes have been designed. Extremely sensitive bright visual humidity indicators, capable of dramatic colour change within a few seconds of breathing on them are demonstrated.
A Visual Indication Of Environmental Humidity Using A Color Changing Hologram Recorded In A Self-Developing Photopolymer, Izabela Naydenova, Raghavendra Jallapuram, Vincent Toal, Suzanne Martin
A Visual Indication Of Environmental Humidity Using A Color Changing Hologram Recorded In A Self-Developing Photopolymer, Izabela Naydenova, Raghavendra Jallapuram, Vincent Toal, Suzanne Martin
Articles
A reflection hologram for visual indication of environmental humidity has been studied. The hologram is recorded in a self-developing photopolymer and changes color when exposed to a change in humidity and is fully reversible. The range of color change, reversibility, and the response time of the hologram have been studied in a controlled humidity environment. Fully reversible holograms with response times from few seconds to tens of minutes have been designed. Extremely sensitive bright visual humidity indicators, capable of dramatic color change within a few seconds of breathing on them are demonstrated
Holographic Recording In Nanoparticle-Doped Photopolymer, Izabela Naydenova, Hosam Sherif, Svetlana Mintova, Suzanne Martin, Vincent Toal
Holographic Recording In Nanoparticle-Doped Photopolymer, Izabela Naydenova, Hosam Sherif, Svetlana Mintova, Suzanne Martin, Vincent Toal
Conference Papers
A nanoparticle-doped acrylic photopolymer is characterised as a material for holographic recording. The influence of nanoparticles on the photopolymer dynamic range, dynamics of recording, temporal stability and mechanical stability in terms of shrinkage has been studied. The dynamics of recording and the temporal stability are investigated by real time monitoring of the build up of diffraction gratings of spatial frequencies of 200 to 2000 l/mm. The shrinkage has been characterised by recording slanted transmission gratings and observation of the change in the Bragg angle.
Holographic Recording Of Patterns In Thin Film Acrylamide-Based Photopolymer, Izabela Naydenova, Kotakonda Pavani, Emilia Mihaylova, Katia Loudmer, Suzanne Martin, Vincent Toal
Holographic Recording Of Patterns In Thin Film Acrylamide-Based Photopolymer, Izabela Naydenova, Kotakonda Pavani, Emilia Mihaylova, Katia Loudmer, Suzanne Martin, Vincent Toal
Conference Papers
A study of the light induced surface relief modulation in thin photopolymer layers is reported. Due to the nature of the photopolymer used no additional post-processing is required after holographic recording. An investigation of the dependence of the amplitude of the photoinduced relief modulation on different parameters of recording such as spatial frequency, intensity of the beams and times of exposure has been carried out. The surface relief modulation is characterized by white light interferometry. Photopolymer layer thickness ranges from 1-5m. A model of the mechanism of surface relief formation is proposed on the basis of the measured dependencies. A …
Investigation Of The Diffusion Processes In Self-Processing Acrylamide-Based Photopolymer System, Izabela Naydenova, Raghavendra Jallapuram, Robert Howard, Suzanne Martin, Vincent Toal
Investigation Of The Diffusion Processes In Self-Processing Acrylamide-Based Photopolymer System, Izabela Naydenova, Raghavendra Jallapuram, Robert Howard, Suzanne Martin, Vincent Toal
Articles
Results from the investigation of the diffusion processes in a dry acrylamide-based photopolymer system are presented. The investigation is carried out in the context of experimental work on optimization of the high spatial frequency response of the photopolymer. Tracing the transmission holographic grating dynamics at short times of exposure is utilized to measure diffusion coefficients. The results reveal that two different diffusion processes contribute with opposite sign to the refractive index modulation responsible for the diffraction grating build up. Monomer diffusion from dark to bright fringe areas increases the refractive index modulation. It is characterized with diffusion constant D0=1.6E-7 cm2/s. …