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Full-Text Articles in Physics
Bandwidth Tuning Triggers Interplay Of Charge Order And Superconductivity In Two-Dimensional Organic Materials, S. Kaiser, M. Dressel, Y. Sun, A. Greco, J. A. Schlueter, Gary L. Gard, N. Drichko
Bandwidth Tuning Triggers Interplay Of Charge Order And Superconductivity In Two-Dimensional Organic Materials, S. Kaiser, M. Dressel, Y. Sun, A. Greco, J. A. Schlueter, Gary L. Gard, N. Drichko
Chemistry Faculty Publications and Presentations
We observe charge-order fluctuations in the quasi-two-dimensional organic superconductor β″-(BEDT-TTF)₂SF₅CH₂CF₂SO₃, both by means of vibrational spectroscopy, locally probing the fluctuating charge order, and by investigating the in-plane dynamical response by infrared reflectance spectroscopy. The decrease of the effective electronic interaction in an isostructural metal suppresses both charge-order fluctuations and superconductivity, pointing to their interplay. We compare the results of our experiments with calculations on the extended Hubbard model.
Fermiology And Superconductivity At High Magnetic Fields In A Completely Organic Cation Radical Salt, J. S. Brooks, V. Williams, E. Choi, D. Graf, M. Tokumoto, S. Uji, F. Zuo, J. Wosnitza, J. A. Schlueter, H. David, Rolf Walter Winter, Gary L. Gard, K. Storr
Fermiology And Superconductivity At High Magnetic Fields In A Completely Organic Cation Radical Salt, J. S. Brooks, V. Williams, E. Choi, D. Graf, M. Tokumoto, S. Uji, F. Zuo, J. Wosnitza, J. A. Schlueter, H. David, Rolf Walter Winter, Gary L. Gard, K. Storr
Chemistry Faculty Publications and Presentations
We report specialized interplane magnetoresistance (MR) measurements on the organic superconducting compound β″–(BEDT-TTF)₂SF₅CH₂CF₂SO₃ (where BEDT-TTF is bis(ethylenedithio)tetrathiafulvalene) in both the superconducting (Tc ∼ 5K) and normal states versus magnetic field direction. In the normal state, detailed angular-dependent magnetoresistance oscillation (AMRO) studies reveal peculiar features of the Fermi surface topology of this compound, and very high magnetic field studies further support the unusual nature of the electronic structure. In the superconducting state we investigate, through detailedAMRO measurements, the anomalous MR peak that appears within the superconducting field-temperature phase diagram. Our results reveal a direct connection between the superconducting state determined from …
Pressure-Induced Insulating State In An Organic Superconductor, Gary L. Gard, Javid Mohtasham, J. A. Schlueter, C. Pfleiderer, J. Wosnitza, J. Hagel
Pressure-Induced Insulating State In An Organic Superconductor, Gary L. Gard, Javid Mohtasham, J. A. Schlueter, C. Pfleiderer, J. Wosnitza, J. Hagel
Chemistry Faculty Publications and Presentations
The electronic-transport properties of the quasi-two-dimensional organic superconductor β″–(BEDT-TTF)₂SF₅CH₂CF₂SO₃, where BEDT-TTF stands for bisethylenedithio-tetrathiafulvalene, have been investigated in magnetic fields up to 15 T and under hydrostatic pressure up to about 14 kbars. Shubnikov–de Haas data reveal a nonmonotonic pressure dependence of the holelike Fermi surface, a roughly linear increase of the electron g factor, and an approximately linear decrease of the cyclotron effective mass. By assuming that the latter reflects the pressure-induced reduction of the superconducting coupling parameter λ the rapid reduction of the superconducting transition temperature Tc(p) can be reasonably well described by the modified McMillan equation. Above …
Enhanced Magnetic Quantum Oscillations In The Mixed State Of A Two-Dimensional Organic Superconductor, J. Wosnitza, J. Hagel, P. J. Meeson, D. Bintley, J. A. Schlueter, Javid Mohtasham, Rolf Walter Winter, Gary L. Gard
Enhanced Magnetic Quantum Oscillations In The Mixed State Of A Two-Dimensional Organic Superconductor, J. Wosnitza, J. Hagel, P. J. Meeson, D. Bintley, J. A. Schlueter, Javid Mohtasham, Rolf Walter Winter, Gary L. Gard
Chemistry Faculty Publications and Presentations
We report on de Haas–van Alphen (dHvA) oscillations observed in the mixed state of the organic superconductor β″–(BEDT-TTF)₂SF₅CH₂CF₂SO₃ (BEDT-TTF stands for bisethylenedithio-tetrathiafulvalene) utilizing the field-modulation technique and torque magnetometry. At low temperatures (30 mK), the dHvA signal persists down to 1.4 T well below the upper critical field Bc2≈3.6T. Contrary to most theoretical predictions and previous experimental findings, no additional damping of the dHvA-oscillation amplitude, but a reduced damping of the dHvA signal is found. This highly unusual effect might indicate a reduced quasiparticle scattering rate or an additional oscillatory contribution in the superconducting state.
Coherent Vs Incoherent Interlayer Transport In Layered Metals, Gary L. Gard, J. Wosnitza, J. Hagel, J. S. Qualls, J. S. Brooks, E. Balthes, D. Schweitzer, J. A. Schlueter, U. Geiser, Javid Mohtasham, Rolf Walter Winter
Coherent Vs Incoherent Interlayer Transport In Layered Metals, Gary L. Gard, J. Wosnitza, J. Hagel, J. S. Qualls, J. S. Brooks, E. Balthes, D. Schweitzer, J. A. Schlueter, U. Geiser, Javid Mohtasham, Rolf Walter Winter
Chemistry Faculty Publications and Presentations
The magnetic-field, temperature, and angular dependence of the interlayer magnetoresistance of two different quasi-two-dimensional (2D) organic superconductors is reported. For k -BEDT-TTF)₂I₃, where BEDTTTF is bisethylenedithio-tetrathiafulvalene, we find a well-resolved peak in the angle-dependent magnetoresistance at Q590°(field parallel to the layers). This clear-cut proof for the coherent nature of the interlayer transport is absent for β″–(BEDT-TTF)₂SF₅CH₂CF₂SO₃. This and the nonmetallic behavior of the magnetoresistance suggest an incoherent quasiparticle motion for the latter 2D metal.
Shubnikov–De Haas Effect In The Superconducting State Of An Organic Superconductor, J. Wosnitza, S. Wanka, J. Hagel, R. Häussler, H. V. Löhneysen, J. A. Schlueter, U. Geiser, P. G. Nixon, Rolf Walter Winter, Gary L. Gard
Shubnikov–De Haas Effect In The Superconducting State Of An Organic Superconductor, J. Wosnitza, S. Wanka, J. Hagel, R. Häussler, H. V. Löhneysen, J. A. Schlueter, U. Geiser, P. G. Nixon, Rolf Walter Winter, Gary L. Gard
Chemistry Faculty Publications and Presentations
We report the observation of Shubnikov–de Haas (SdH) oscillations in the mixed state of the organic superconductor β″-(BEDT-TTF)₂SF₅CH₂CF₂SO₃ (Tc≈4.4K). At low temperatures the SdH oscillations persist clearly below the upper critical field Bc₂(0)≈3.6 T almost down to the field where the resistivity vanishes. Rather unusually, no additional damping of the SdH-signal amplitude — as well as of the de Haas–van Alphen amplitude — is observed in the superconducting state. This indicates that the damping in the vortex state of this quasi-two-dimensional superconductor is different in character to that observed for most three-dimensional materials.
Comparative Thermal-Expansion Study Of Β″-(Et)2sf5ch2cf2so3 And Κ-(Et)2cu(Ncs)2: Uniaxial Pressure Coefficients Of Tc And Upper Critical Fields, J. Müller, M. Lang, F. Steglich, J. A. Schlueter, A. M. Kini, U. Geiser, Javid Mohtasham, Rolf Walter Winter, Gary L. Gard, T. Sasaki, N. Toyota
Comparative Thermal-Expansion Study Of Β″-(Et)2sf5ch2cf2so3 And Κ-(Et)2cu(Ncs)2: Uniaxial Pressure Coefficients Of Tc And Upper Critical Fields, J. Müller, M. Lang, F. Steglich, J. A. Schlueter, A. M. Kini, U. Geiser, Javid Mohtasham, Rolf Walter Winter, Gary L. Gard, T. Sasaki, N. Toyota
Chemistry Faculty Publications and Presentations
We report high-resolution measurements of the coefficient of thermal expansion, α=l⁻¹ x (δl/δΤ), on single crystals of the organic superconductors β″-(ET)₂SF₅CH₂CF₂SO₃ and κ-(ET)₂Cu(NCS)₂. For both salts we find large and highly anisotropic phase-transition anomalies at Tc. Combining these data with literature results on the specific heat via the Ehrenfest relation, the uniaxial pressure coefficients of Tc can be determined. Most remarkably, a strikingly similar in-plane vs out-of-plane anisotropy is found for both compounds: the strong suppression of Tc observed in hydrostatic-pressure experiments is dominated by a huge negative uniaxial stress effect perpendicular to the conducting planes. Therefore we expect that …
Two-Dimensional Fermi Liquid With Fixed Chemical Potential, J. Wosnitza, S. Wanka, J. Hagel, E. Balthes, N. Harrison, J. A. Schlueter, A. M. Kini, U. Geiser, Javid Mohtasham, Rolf Walter Winter, Gary L. Gard
Two-Dimensional Fermi Liquid With Fixed Chemical Potential, J. Wosnitza, S. Wanka, J. Hagel, E. Balthes, N. Harrison, J. A. Schlueter, A. M. Kini, U. Geiser, Javid Mohtasham, Rolf Walter Winter, Gary L. Gard
Chemistry Faculty Publications and Presentations
de Haas-van Alphen measurements made on the organic metal β″-(ET)₂SF₅CH₂CF₂SO₃ reveal the existence of an ideal two-dimensional (2D) Fermi surface, but rather than having the conventional sawtooth wave form that is normally observed in all other 2D electron gases, instead, an ‘‘inverse sawtooth’’ wave form is observed, which is to be expected when the chemical potential is pinned at a constant value. While this proves the existence of the theoretically predicted quasi-one-dimensional band, it further implies that this band has an exceptionally large density of states.
Anomalous Low-Temperature And High-Field Magnetoresistance In The Organic Superconductor Β″-(Bedt-Ttf)2sf5ch2cf2so3, F. Zuo, X. Su, P. Zhang, J. S. Brooks, J. Wosnitza, J. A. Schlueter, Jack M. Williams, P. G. Nixon, Rolf Walter Winter, Gary L. Gard
Anomalous Low-Temperature And High-Field Magnetoresistance In The Organic Superconductor Β″-(Bedt-Ttf)2sf5ch2cf2so3, F. Zuo, X. Su, P. Zhang, J. S. Brooks, J. Wosnitza, J. A. Schlueter, Jack M. Williams, P. G. Nixon, Rolf Walter Winter, Gary L. Gard
Chemistry Faculty Publications and Presentations
We report direct observations of anomalous magnetic-field and temperature dependences of the Shubnikov–de Haas oscillations in the organic superconductor β″-(BEDT-TTF)₂SF₅CH₂CF₂SO₃. Unlike other BEDT-TTF based organic superconductors, a nonmetallic temperature dependence of the background magnetoresistance is clearly observed. It is speculated that the nonmetallic behavior may arise from a partial nesting of the open orbits, similar to the field-induced density wave in the quasi-one-dimensional systems or a charge localization. The analysis of the magnetoresistance oscillations are found to deviate from the conventional Lifshitz-Kosevich description at high field and low temperatures. [S0163-1829(99)05433-8]
Optical Properties Of Β″-(Et)2sf5ch2cf2so3: A Layered Molecular Superconductor With Large Discrete Counterions, J. Dong, J. L. Musfeldt, J. A. Schlueter, Jack M. Williams, P. G. Nixon, Rolf Walter Winter, Gary L. Gard
Optical Properties Of Β″-(Et)2sf5ch2cf2so3: A Layered Molecular Superconductor With Large Discrete Counterions, J. Dong, J. L. Musfeldt, J. A. Schlueter, Jack M. Williams, P. G. Nixon, Rolf Walter Winter, Gary L. Gard
Chemistry Faculty Publications and Presentations
We report the polarized infrared and optical reflectance of β″-(ET)₂SF₅CH₂CF₂SO₃ as a function of temperature. This fully organic superconductor displays weakly metallic behavior over the entire temperature range of our investigation. The electronic properties present several unusual features including the lack of a conventional free carrier (Drude) response at low temperature, infrared localization phenomena, and an unexpected temperature dependence of the oscillator strength. Similar behavior is observed in other β and β″ superconductors above Tc, suggesting that this class of compounds is very close to a metal→insulator transition where electronic correlations are important and the Drude response carries very little …
Anisotropic Magnetoresistance In The Organic Superconductor Β″–(Bedt-Ttf)2sf5ch2cf2so3, X. Su, F. Zuo, J. A. Schlueter, Jack M. Williams, P. G. Nixon, Rolf Walter Winter, Gary L. Gard
Anisotropic Magnetoresistance In The Organic Superconductor Β″–(Bedt-Ttf)2sf5ch2cf2so3, X. Su, F. Zuo, J. A. Schlueter, Jack M. Williams, P. G. Nixon, Rolf Walter Winter, Gary L. Gard
Chemistry Faculty Publications and Presentations
In this paper, we report transport measurements of interlayer magnetoresistance with field parallel and perpendicular to the current direction in an all organic superconductor β″–(BEDT-TTF)₂SF₅CH₂CF₂SO₃. For H∥I, the isothermal magnetoresistance R(H) at low temperatures (T
Specific Heat And Critical Fields Of The Organic Superconductor Β″–(Bedt-Ttf)2sf5ch2cf2so3, S. Wanka, J. Hagel, D. Beckmanm, J. Wosnitza, J. A. Schlueter, Jack M. Williams, P. G. Nixon, Rolf Walter Winter, Gary L. Gard
Specific Heat And Critical Fields Of The Organic Superconductor Β″–(Bedt-Ttf)2sf5ch2cf2so3, S. Wanka, J. Hagel, D. Beckmanm, J. Wosnitza, J. A. Schlueter, Jack M. Williams, P. G. Nixon, Rolf Walter Winter, Gary L. Gard
Chemistry Faculty Publications and Presentations
We report on specific-heat, magnetization, and ac-susceptibility measurements of β″–(BEDT-TTF)₂SF₅CH₂CF₂SO₃, an organic superconductor with Tc=4.5 K, where BEDT-TTF stands for bis(ethylenedithio)-tetrathiafulvalene. The jump of the specific heat C at Tc and the exact form of the specific heat difference between C in the superconducting (B=0 T) and in the normal (B=3.5 T) state can be well described by BCS theory with strong coupling. We estimate an electron-phonon coupling parameter λ≈1.1. From measurements of C in magnetic fields we extract the upper critical field Bc₂(T). Low-field dc-magnetization measurements were used to determine the temperature dependence of the lower critical field Bc₁. …
Coherence Peak And Superconducting Energy Gap In Rb_{3}C_{60} Observed By Muon Spin Relaxation, R. F. Kiefl, W. A. Macfarlane, K. H. Chow, S. Dunsiger, T. L. Duty, T. M. S. Johnston, J. W. Schneider, J. Sonier, Laurent Brard, Robert M. Strongin, J. E. Fischer, Amos B. Smith Iii
Coherence Peak And Superconducting Energy Gap In Rb_{3}C_{60} Observed By Muon Spin Relaxation, R. F. Kiefl, W. A. Macfarlane, K. H. Chow, S. Dunsiger, T. L. Duty, T. M. S. Johnston, J. W. Schneider, J. Sonier, Laurent Brard, Robert M. Strongin, J. E. Fischer, Amos B. Smith Iii
Chemistry Faculty Publications and Presentations
Muon spin relaxation resulting from spin exchange scattering of endohedral muonium (μ+e-) with thermal electronic excitations has been observed in the fullerene superconductor Rb3C60. The temperature dependence of T1-1 shows a coherence peak just below Tc and can be fit to the conventional Hebel-Slichter theory for spin relaxation in a superconductor with a broadened BCS density of states. The average energy gap for electronic excitations, Δ/kB=53(4) K or 2Δ/ kBTc=3.6(3), is consistent with the BCS weak coupling limit.
Unusual Thermal Stability Of A Site-Ordered Mc60 Rocksalt Structure (M=K, Rb, Or Cs), Q. Zhu, O. Zhou, J. E. Fischer, Andrew R. Mcghie, W. R. Romanow, Robert M. Strongin, M. A. Cichy, Amos B. Smith Iii
Unusual Thermal Stability Of A Site-Ordered Mc60 Rocksalt Structure (M=K, Rb, Or Cs), Q. Zhu, O. Zhou, J. E. Fischer, Andrew R. Mcghie, W. R. Romanow, Robert M. Strongin, M. A. Cichy, Amos B. Smith Iii
Chemistry Faculty Publications and Presentations
X-ray diffraction and differential scanning calorimetry of MxC60, with x∼1 and M=K, Rb, or Cs, reveal an unusual T-dependent phase sequence. A low-symmetry ground state is found, while the high-T limit is an ordered rocksalt structure in which only the octahedral sites are occupied. The unusual high-T stability of this ordered phase is attributed to the entropy of molecular orientational disorder and/or thermal disorder of the alkali-metal ions within the octahedral sites. Unique to KxC60 with x≥1.4, we find at intermediate temperatures an fcc site-disordered lattice gas …