Physics Commons^™

Influence Of Surfactants On The Formation And Growth Of Cadmium Telluride Nanoplatelets, A.S. Akhmetova, A.K. Ospanova, B.N. Yussupbekova, T.T. Alibay

Eurasian Journal of Physics and Functional Materials

The article presents a comprehensive review of the current research on the use of surfactants in CdTe nanoplatelet synthesis, including a discussion of the various types of surfactants that have been used and their effects on nanoplatelet size, shape, and optical properties. Additionally, the article examines the mechanisms by which surfactants influence the growth and morphology of CdTe nanoplatelets, with a focus on the role of surfactant, size, and structure. Overall, this article provides a detailed analysis of the use of surfactants in the synthesis of CdTe nanoplatelets and highlights the potential for this approach to improve the performance of …

An Interactive Simulation And Visualization Tool For Conventional And Aberration-Corrected Transmission Electron Microscopy, Xingzhong Li

Nebraska Center for Materials and Nanoscience: Faculty Publications

Contrast transfer function (CTF) is a vital function in transmission electron microscopy (TEM). It expresses to what extent amplitudes converted from the phase changes of the diffracted waves contribute to the TEM image, including the effects of lens aberrations. Simulation is very helpful to understand the application of the function thoroughly. In this work, we develop the CTFscope as a component in the Landyne software suite, to calculate the CTF with temporal and spatial dumping envelopes for conventional TEM and to extend it to various aberrations (up to fifth order) for aberration-corrected (AC)- TEM. It also includes effects on the …

A Tem Study Of Fe3+X Co3-XTi2 (X = 0, 1, 2, 3) Intermetallic Alloys, Xingzhong Li, Anandakumar Sarella, B. Balasubramanian, Shah R. Valloppilly

David Sellmyer Publications

A TEM study has been carried out on crystal structures in the rare-earth-free intermetallic alloys, Fe_3+xCo_3-xTi₂ (x = 0, 1, 2, 3). These alloys have been demonstrated to have potentially high magnetic anisotropy. In these alloys, the main intermetallic compound was recently reported as a new hexagonal phase with a space group of P-6 m2. The present study reveals that the main compound belongs to Laves C14 variant surrounded by α-Fe type crystal as secondary phase in the Fe_3+xCo_3-xTi₂ (x = 0, 1, 2, 3) alloys, in agreement with the …

A Modulated Structure Derived From The Xa-Type Mn2Rusn Heusler Compound, Xingzhong Li, Wen-Yong Zhang, Ralph Skomski, David J. Sellmyer

Nebraska Center for Materials and Nanoscience: Faculty Publications

A modulated structure derived from the inverse Heusler phase (the XA-type and the disordered variant L2₁B-type) has been observed in rapidly quenched Mn2RuSn ribbons. The powder X-ray diffraction pattern of the quenched ribbons can be indexed as an L2₁B-type structure. Electron diffraction patterns of the new structure mostly resemble those of the XA-type (and the disordered variant L2₁B-type) structure and additional reflections with denser spacing indicate a long periodicity. Orthogonal domains of the modulated structure were revealed by a selected-area electron diffraction pattern and the corresponding dark-field transmission electron microscopy images. The structure was …

Md And Tem Evaluation Of Swift Xe Ion Induced Latent Tracks In Si3n4, R. A. Rymzhanov, A. Zhalmagambetova, A. Ibrayeva, A. Janse Van Vuuren, J. H. O’Connell, V. A. Skuratov

Eurasian Journal of Physics and Functional Materials

As known silicon nitride ceramics is considered as a candidate material for inert matrix fuel hosts used for transmutation of minor actinides. Unfortunately, by now very limited data is devoted to investigate of its stability under high energy heavy ion irradiation simulating fission fragment impact. Aim of our present study is a comparative analysis of parameters of latent tracks induced with swift Xe ion irradiation in polycrystalline Si₃N₄ using molecular dynamic (MD) simulation and high resolution transmission electron microscopy (TEM). Silicon nitride samples were irradiated with 220 MeV xenon ions at room temperature to fluence 5 × …

Correlated Sem, Fib, And Tem Studies Of Material Collected By The Nasa Stardust Spacecraft, Brendan Albert Haas

Arts & Sciences Electronic Theses and Dissertations

The objective of this thesis is to describe the study of cometary materials returned by NASA’s Stardust mission. The majority of the research presented in this thesis focuses on improving our characterization and understanding of the fine (< 1 µm) component of comet Wild 2. Investigations of the Stardust foils are conducted with correlated Scanning Electron Microscopy (SEM), Focused Ion Beam (FIB) sample preparation, and Transmission Electron Microscopy (TEM). Investigations of the Stardust aerogels are conducted with plasma ashing sample preparation followed by detailed characterization of the material with TEM. Additional studies of the Stardust interstellar foils, as well as the use of a Convolutional Neural Network (CNN) to search images of the Stardust foils for impact features, are also presented. As a part of this thesis I have developed a new technique for analyzing the Stardust aerogels through the use of plasma ashing sample preparation. This technique is an improvement upon previous attempts to separate cometary materials from the aerogel through the use of HF vapor etching. Plasma ashing allows for cometary materials trapped within the Stardust aerogels to be deposited directly onto TEM grids allowing for detailed characterization of the cometary material with minimal interference from the aerogel itself. The correlated SEM/FIB/TEM studies of the Stardust foils demonstrated here nearly double the number of Stardust craters that have been elementally and structurally characterized in scientific literature. The crater impactor residues were largely composed of combinations of silicates and iron-nickel sulfides that, following impact, rapidly quenched into amorphous melt layers. Two craters were found to contain signatures of the refractory minerals spinel and taenite, indicating a component of the Wild 2 fines originated in the inner Solar System. However, the lack of crystalline material throughout the crater residues suggests that the fine component may largely be composed of amorphous silicates that likely formed in the outer Solar System. Additionally, the submicron Stardust craters appeared enriched in volatile elements relative to CI chondrites, further suggesting that the fine component of Wild 2 originated from a reservoir that was separate from the more refractory coarse (> 1 µm) component. The Stardust aerogel samples returned carbon-rich and potential oldhamite grains. Carbon-rich materials have not been previously observed in the Stardust foils, likely due to the violent collection methods, and the result suggests the ashing technique may be used to better characterize components of the Wild 2 fines that have been difficult to investigate. The presence of oldhamite in the …

Correlated Nanosims, Tem, And Xanes Studies Of Presolar Grains, Evan Edward Groopman

Arts & Sciences Electronic Theses and Dissertations

The objective of this thesis is to describe the correlated study of individual presolar grains via Nano-scale Secondary Ion Mass Spectrometry (NanoSIMS), Transmission Electron Microscopy (TEM), and Scanning Transmission X-ray Microscopy (STXM) utilizing X-ray Absorption Near Edge Structure (XANES), with a focus on connecting these correlated laboratory studies to astrophysical phenomena. The correlated isotopic, chemical, and microstructural studies of individual presolar grains provide the most detailed description of their formation environments, and help to inform astrophysical models and observations of stellar objects.

As a part of this thesis I have developed and improved upon laboratory techniques for micromanipulating presolar grains …

Orthorhombic Zr2Co11 Phase Revisited, Xingzhong Li, Wenyong Zhang, David J. Sellmyer, X Zhao, M C. Nguyen, C Z. Wang, K M. Ho

David Sellmyer Publications

The structure of the orthorhombic Zr₂Co₁₁ phase was revisited in the present work. Selected-area electron diffraction (SAED) and high-resolution electron microscopy (HREM) techniques were used to investigate the structure. They show the orthorhombic Zr₂Co₁₁ phase has a 1-D incommensurate modulated structure. The structure can be approximately described as a B-centered orthorhombic lattice. The lattice parameters of the orthorhombic Zr₂Co₁₁ phase have been determined by a tilt series of SAED patterns. A hexagonal network with a modulation wave has been observed in the HREM image and the hexagonal motif is considered as …

The Talbot Effect, Malia Kawamura

Honors Theses

The goal of this project is to experimentally investigate the optical Talbot effect and the electron Talbot effect. The Talbot effect is a near-field diffraction effect which occurs when plane waves are incident upon a grating. The Talbot effect creates full grating revivals at integral Talbot lengths and revivals with greater spatial periodicity at fractional Talbot lengths. We use a green helium neon laser and Ronchi rulings to take CCD camera images of the fractional Talbot revivals directly. Additionally, a photodiode records light intensity as a function of time as a second identical grating is moved to verify the presence …

Electron Microscopy Characterization Of Vanadium Dioxide Thin Films And Nanoparticles, Felipe Rivera

Theses and Dissertations

Vanadium dioxide (VO_2) is a material of particular interest due to its exhibited metal to insulator phase transition at 68°C that is accompanied by an abrupt and significant change in its electronic and optical properties. Since this material can exhibit a reversible drop in resistivity of up to five orders of magnitude and a reversible drop in infrared optical transmission of up to 80%, this material holds promise in several technological applications. Solid phase crystallization of VO_2 thin films was obtained by a post-deposition annealing process of a VO_{x,x approx 2} amorphous film sputtered on an amorphous silicon dioxide (SiO_2) …

Experimental And Theoretical Analysis Of Strain Engineered Aluminium Nitride On Silicon For High Quality Aluminium(X)Indium(Y)Gallium(1-X-Y)Nitride Epitaxy, Mihir Hemant Tungare

Legacy Theses & Dissertations (2009 - 2024)

III-Nitrides on Si are of great technological importance due to the availability of large area, epi ready Si substrates and the ability to heterointegrate with mature silicon micro and nanoelectronics. The major roadblock with realizing this is the large difference in thermal expansion coefficients and lattice constants between the two material systems. A novel technique developed in our research lab shows the potential of simultaneous and substantial reduction in dislocation and crack density in GaN on Si (111). Research undertaken in the current doctoral dissertation, validates the superior GaN quality on Si obtained using our technique and determines the factors …

Pore Structure, Barrier Layer Topography And Matrix Alumina Structure Of Porous Anodic Alumina Film, Yucheng Sui, B.Z. Cui, L. Martinez, R. Perez, David J. Sellmyer

David Sellmyer Publications

Different anodic voltages and methods were adopted to produce porous anodic alumina films (PAAF) in an aqueous solution of oxalic acid. Carbon tube growth by chemical vapor deposition (CVD) in the films was used to copy the internal pore structure and was recorded by transmission electron microscopy (TEM) photos. Atomic force microscope (AFM) was employed to obtain the topography of the barrier layer of the corresponding films. When the anodic voltage was 40 V and the two-step method adopted, the barrier layer of the film had domains with highly ordered hexagonal cell distribution, and the corresponding pores were straight. When …