Physics Commons^™

Near- And Far- Field Optical Response Of Ensembles Of Nanostructures, Lauren Zundel

Physics & Astronomy ETDs

The ability of metallic nanostructures to support collective oscillations of their conduction electrons, known as surface plasmons, makes them attractive candidates for a wide range of applications in areas as diverse as cancer therapy, biosensing, and solar energy harvesting. These applications are especially promising for periodic arrays of nanostructures, which can support collective modes known as lattice resonances, and for nanostructures with extreme aspect ratios that give rise to enhanced light-matter interaction. In this Thesis, we employ a coupled dipole model to theoretically explore the lattice resonances supported by complex arrays of nanoparticles containing multiple nanoparticles per unit cell. We …

Utilizing Inverse Design To Create Plasmonic Waveguide Devices, Michael Efseaff, Kyle Wynne, Mark C. Harrison

Engineering Faculty Articles and Research

In modern communications networks, data is transmitted over long distances using optical fibers. At nodes in the network, the data is converted to an electrical signal to be processed, and then converted back into an optical signal to be sent over fiber optics. This process results in higher power consumption and adds to transmission time. However, by processing the data optically, we can begin to alleviate these issues and surpass systems which rely on electronics. One promising approach for this is plasmonic devices. Plasmonic waveguide devices have smaller footprints than silicon photonics for more compact photonic integrated circuits, although they …

Resonant Plasmonic–Biomolecular Chiral Interactions In The Far-Ultraviolet: Enantiomeric Discrimination Of Sub-10 Nm Amino Acid Films, Tiago Ramos Leite, Lin Zschiedrich, Orhan Kizilkaya, Kevin M. Mcpeak

Faculty Publications

Resonant plasmonic–molecular chiral interactions are a promising route to enhanced biosensing. However, biomolecular optical activity primarily exists in the far-ultraviolet regime, posing significant challenges for spectral overlap with current nano-optical platforms. We demonstrate experimentally and computationally the enhanced chiral sensing of a resonant plasmonic–biomolecular system operating in the far-UV. We develop a full-wave model of biomolecular films on Al gammadion arrays using experimentally derived chirality parameters. Our calculations show that detectable enhancements in the chiroptical signals from small amounts of biomolecules are possible only when tight spectral overlap exists between the plasmonic and biomolecular chiral responses. We support this conclusion …

Surface Plasmon Characterization In Ag Nanotriangles For Evaluation Of Fano Resonance Conditions, Nabila Islam

Student Research Symposium

Surface plasmon polariton (SPP) is a collective oscillation of electrons and light at the metal -dielectric interface excited by the incident radiation on metal surface through the momentum matching conditions. The properties of SPPs and the resonance conditions are highly dependent on the confining materials and geometry of the confining nanostructure. The sensitivity of the surface plasmon resonance to the property of the confining materials made Surface plasmon resonance (SPR) sensors a central tool for biosensing. However, the frequency resolution of SPR sensors is typically limited by the broad resonance of the SPR mode. The resolution can be enhanced through …

Fundamental Aspects Of The Interaction Between Light And Nanostructures, Stephen Keith Sanders

Physics & Astronomy ETDs

Recent breakthroughs in nanophotonics have brought new opportunities to control and manipulate light at the nanoscale. The optical properties of metallic nanostructures have attracted particular interest because of their plasmon resonances, which couple strongly with visible light, and generate large near-field enhancements in their vicinity. In the first part of this thesis, we investigate the fundamental limits of the local density of photonic states near nanostructures by analyzing a sum rule relating its spectral integral to the field induced by a static dipole. Next, we analyze how the design of metallic nanoantennas can benefit from incorporating active materials that display …

On-Chip Nanoscale Plasmonic Optical Modulators, Abdalrahman Mohamed Nader Abdelhamid

Theses and Dissertations

In this thesis work, techniques for downsizing Optical modulators to nanoscale for the purpose of utilization in on chip communication and sensing applications are explored. Nanoscale optical interconnects can solve the electronics speed limiting transmission lines, in addition to decrease the electronic chips heat dissipation. A major obstacle in the path of achieving this goal is to build optical modulators, which transforms data from the electrical form to the optical form, in a size comparable to the size of the electronics components, while also having low insertion loss, high extinction ratio and bandwidth. Also, lap-on-chip applications used for fast diagnostics, …

Photoemission Electron Microscopy For Direct Observation Of Photonic And Plasmonic Phenomena, Theodore Stenmark

Dissertations and Theses

Photoemission electron microscopy (PEEM) is a high-resolution microscopy technique that collects photoemitted electrons from the sample surface to form an image. PEEM offers a non-scanning imaging method with a spatial resolution in the range of 5-100nm by combining the advantages of light excitation and electron imaging. Our work looks at PEEM as an analysis tool for photonic and plasmonic phenomena. Photonic wave guiding structures exhibiting a strong dispersion relation have attracted considerable attention for applications in integrated optics, communications and sensing devices. Line defects in a photonic crystal (PC) slab offer a highly efficient way to create light with group …

Implementing Inverse Design Tools For Plasmonic Digital Logic Devices, Krishna Narayan, Mark C. Harrison

Engineering Faculty Articles and Research

Despite the benefits that optics and photonics have brought to improving communications, there remains a lack of commercialized optical computing devices and systems, which reduces the benefits of using light as an information-carrying medium. We are developing architectures and designs of photonic logic gates for creating larger-scale functional photonic logic circuits. In contrast to other approaches, we are focusing on the development of logic devices which can be cascaded in arbitrary ways to allow for more complex photonic integrated circuit design. Additionally, optical computing often uses on-off keying, which fails to take advantage of denser encoding schemes often used to …

Plasmonic Waveguides To Enhance Quantum Electrodynamic Phenomena At The Nanoscale, Ying Li, Christos Argyropoulos

Department of Electrical and Computer Engineering: Faculty Publications

The emerging field of plasmonics can lead to enhanced light-matter interactions at extremely nanoscale regions. Plasmonic (metallic) devices promise to efficiently control both classical and quantum properties of light. Plasmonic waveguides are usually used to excite confined electromagnetic modes at the nanoscale that can strongly interact with matter. The analysis of these nanowaveguides exhibits similarities with their low frequency microwave counterparts. In this article, we review ways to study plasmonic nanostructures coupled to quantum optical emitters from a classical electromagnetic perspective. These quantum emitters are mainly used to generate single-photon quantum light that can be employed as a quantum bit …

Interactions Of Organic Fluorophores With Plasmonic Surface Lattice Resonances, Robert J. Collison

Dissertations, Theses, and Capstone Projects

It is common knowledge that metals, alloys and pure elements alike, are lustrous and reflective, the more so when a metal surface is flat, polished, and free from oxidation and surface fouling. However, some metals reflect visible light, in the 380 nm to 740 nm range of wavelengths, much more strongly than others. In particular, some metals reflect wavelengths in certain portions of the ultraviolet (UV), visible, and near-infrared (NIR) regime, let us say 200 nm to 2000 nm, while absorbing light strongly in other segments of this range. There are several factors that account for this difference between various …

Combined Experimental And Modeling Analysis For Thedevelopment Of Optical Materials Suitable To Enhance Theimplementation Of Plasmonic-Enhanced Luminescent Down-Shifting Solutions On Existing Silicon-Based Photovoltaic Devices, James Walshe, Mihaela Girtan, Sarah Mccormack, John Doran, George Amarandei

Articles

The development of highly efficient solar collectors requires modulating the light interactions with the semiconducting materials. Incorporating luminescent species and metal nanoparticles within a semitransparent polymeric material (e.g., polymethyl methacrylate (PMMA)) leads to the formation of a plasmon-enhanced luminescent down-shifting (PLDS) layer, which offers a retrofittable approach toward expanding the wavelength range over which the conversion process can effectively occur. Adding antireflection coatings (ARCs) further controls the spectral response. However, with each additional component comes additional loss pathways. In this study, the losses related to light interactions with the PMMA and the ARCs have been investigated theoretically using a transfer …

A Hybrid Achromatic Metalens, Fatih Balli, Mansoor A. Sultan, Sarah K. Lami, J. Todd Hastings

Electrical and Computer Engineering Faculty Publications

Metalenses, ultra-thin optical elements that focus light using subwavelength structures, have been the subject of a number of recent investigations. Compared to their refractive counterparts, metalenses offer reduced size and weight, and new functionality such as polarization control. However, metalenses that correct chromatic aberration also suffer from markedly reduced focusing efficiency. Here we introduce a Hybrid Achromatic Metalens (HAML) that overcomes this trade-off and offers improved focusing efficiency over a broad wavelength range from 1000-1800 nm. HAMLs can be designed by combining recursive ray-tracing and simulated phase libraries rather than computationally intensive global search algorithms. Moreover, HAMLs can be fabricated …

Electrodynamics Modeling Of Plasmonic-Organic Hybrid Waveguides, Marcus Michel

Pomona Senior Theses

Optical fibers have multiple advantages over conventional electrical connections, such as lower energy losses and higher bandwidth. To use optics for chip-to-chip communication, electro-optic (EO) modulators need to be scaled down to be incorporated on integrated circuits. This size reduction has been accomplished using plasmonic-organic hybrid (POH) waveguides, which make use of nonlinear organic EO materials and surface plasmon polaritons to achieve light modulation in devices with lengths on the micron scale. As these devices are just starting to be developed, there are many avenues for their potential optimization. In order to streamline and reduce the cost of the optimization …

Plasmonic Properties Of Nanoparticle And Two Dimensional Material Integrated Structure, Desalegn Tadesse Debu

Graduate Theses and Dissertations

Recently, various groups have demonstrated nano-scale engineering of nanostructures for optical to infrared wavelength plasmonic applications. Most fabrication technique processes, especially those using noble metals, requires an adhesion layer. Previously proposed theoretical work to support experimental measurement often neglect the effect of the adhesion layers. The first finding of this work focuses on the impact of the adhesion layer on nanoparticle plasmonic properties. Gold nanodisks with a titanium adhesion layer are investigated by calculating the scattering, absorption, and extinction cross-section with numerical simulations using a finite difference time domain (FDTD) method. I demonstrate that a gold nanodisk with an adhesive …

Control Of Light-Matter Interactions Via Nanostructured Photonic Materials, Nicholas Proscia

Dissertations, Theses, and Capstone Projects

The thesis here investigates the manipulation of light-matter interactions via nanoscale engineering of material systems. When material systems are structured on the nanoscale, their optical responses can be dramatically altered. In this thesis, this is done in two primary ways: One method is by changing the geometry of nanostructures to induce a resonant behavior with incident electromagnetic field of optical wavelengths. This allows field enhancement in highly localized areas to strengthen exotic light-matter interactions that would otherwise be too weak to measure or for practical use. In this regard, the work presented here studies a voltage produced in a metal …

Grating Coupler For Surface Waves Based On Electrical Displacement Currents, Jonathan R. Brescia

Honors Undergraduate Theses

Bound electromagnetic surface waves can be excited by free-space waves on a corrugated conduction surface. These electromagnetic surface waves, called surface plasmon polaritons (SPPs), are coupled to a plasma of free charges, which travel together with the wave. We investigated the effect of separating metal corrugations from the smooth metal ground plane with a thin dielectric layer and show that SPPs can be excited via displacement currents. However, the SPP excitation resonances broaden and disappear as the dielectric thickness approaches 1% of the wavelength.

Optimizing The Plasmonic Enhancement Of Light In Metallic Nanogap Structures For Surface-Enhanced Raman Spectroscopy, Stephen Joseph Bauman

Graduate Theses and Dissertations

Technology based on the interaction between light and matter has entered something of a renaissance over the past few decades due to improved control over the creation of nanoscale patterns. Tunable nanofabrication has benefitted optical sensing, by which light is used to detect the presence or quantity of various substances. Through methods such as Raman spectroscopy, the optical spectra of solid, liquid, or gaseous samples act as fingerprints which help identify a single type of molecule amongst a background of potentially many other chemicals. This technique therefore offers great benefit to applications such as biomedical sensors, airport security, industrial waste …

Plasmonic Enhancement Of Photoluminescence And Photobrightening In Cdse Quantum Dots, David Alan French

Graduate Theses and Dissertations

Quantum dots are gaining recognition not just in the physics and chemistry community, but in the public eye as well. Quantum dot technologies are now being used in sensors, detectors, and even television displays. By exciting quantum dots with light or electricity, they can be made to emit light, and by altering the quantum dot characteristics the wavelength can be finely tuned. The light emitted can be also be made more intense by an increase in the excitation energy. The excitation light can be increased via plasmonic enhancement, leading to increased luminescence. Aside from the relatively steady-state response, quantum dots …

Electromagnetic Wave-Matter Interactions In Complex Opto-Electronic Materials And Devices, Raj Kumar Vinnakota

Doctoral Dissertations

This dissertation explores the fundamentals of light-matter interaction towards applications in the field of Opto-electronic and plasmonic devices. In its core, this dissertation attempts and succeeds in the the modeling of light-matter interactions, which is of high importance for better understanding the rich physics underlying the dynamics of electromagnetic field interactions with charged particles. Here, we have developed a self-consistent multi-physics model of electromagnetism, semiconductor physics and thermal effects which can be readily applied to the field of plasmotronics and Selective Laser Melting (SLM). Plasmotronics; a sub-field of photonics has experienced a renaissance in recent years by providing a large …

Plasmonic Grating Geometrics And Wavelength-Dependent Focus Depth In Infrared Detectors, Patrick R. Kennedy

Theses and Dissertations

The objective for this research is to determine a relationship between plasmonic grating geometries and the wavelength-dependent focus depth. This research is focused on enhancing the signal collected by infrared detectors by using a metal grating as a planar lens to focus light in the detecting region of the substrate. This can be used to maintain a thinner absorbing region and possibly to create multi-color imaging in a single pixel. Simulations demonstrate that the plasmonic lens is capable of creating a wavelength dependent focus spot.

Nanowire-Based Light-Emitting Diodes: A New Path Towards High-Speed Visible Light Communication, Mohsen Nami

Physics & Astronomy ETDs

Nano-scale optoelectronic devices have gained significant attention in recent years. Among these devices are semiconductor nanowires, whose dimeters range from 100 to 200 nm. Semiconductor nanowires can be utilized in many different applications including light-emitting diodes and laser diodes. Higher surface to volume ratio makes nanowire-based structures potential candidates for the next generation of photodetectors, sensors, and solar cells. Core-shell light-emitting diodes based on selective-area growth of gallium nitride (GaN) nanowires provide a wide range of advantages. Among these advantages are access to non-polar m-plane sidewalls, higher active region area compared to conventional planar structures, and reduction of threading …

Zr-Doped Tio2 As A Thermostabilizer In Plasmon-Enhanced Dye-Sensitized Solar Cells, Anastasia Pasche, Bernd Grohe, Silvia Mittler, Paul A. Charpentier

Physics and Astronomy Publications

Harvesting solar energy is a promising solution toward meeting the world’s evergrowing energy demand. Dye-sensitized solar cells (DSSCs) are hybrid organic–inorganic solar cells with tremendous potential for commercial application, but they are plagued by in efficiency due to their poor sunlight absorption. Plasmonic silver nanoparticles (AgNPs) have been shown to enhance the absorptive properties of DSSCs, but their plasmonic resonance can cause thermal damage resulting in cell deterioration. Hence, the influence of Zr-doped TiO2 on the efficiency of plasmon-enhanced DSSCs was studied, showing that 5 mol.% Zr-doping of the photoactive TiO2 material can improve the photovoltaic performance of DSSCs by …

Plasmonic Enhancement Of Organic Light Emitting Diodes (Oleds) With Periodic And Random Nanostructures, Pavel Markeev

Graduate Masters Theses

This revised thesis has been submitted in 2021 due to findings of academic misconduct in the original thesis. The misconduct included improper citation and plagiarism of Dr. Khadir’s PhD thesis [1], particularly in the introduction, the state of the art and images 1.1-1.6, 2.4, 3.2, 3.4.

The localized surface plasmon resonance (LSPR) is known as a phenomenon that allow to enhance the efficiency of Organic Light Emitting Diodes (OLED). This work researches the dependence of OLED performance with and without metallic nanoparticle incorporated in the organic layers. Diodes with periodic (PMN) and random (RMN) metallic nanoparticles along with both types …

Infrared Energy Conversion In Plasmonic Fields At Two-Dimensional Semiconductors, Gregory Thomas Forcherio

Graduate Theses and Dissertations

Conversion of infrared energy within plasmonic fields at two-dimensional, semiconductive transition metal dichalcogenides (TMD) through plasmonic hot electron transport and nonlinear frequency mixing has important implications in next-generation optoelectronics. Drude-Lorentz theory and approximate discrete dipole (DDA) solutions to Maxwell’s equations guided metal nanoantenna design towards strong infrared localized surface plasmon resonance (LSPR). Excitation and damping dynamics of LSPR in heterostructures of noble metal nanoantennas and molybdenum- or tungsten-disulfide (MoS2; WS2) monolayers were examined by parallel synthesis of (i) DDA electrodynamic simulations and (ii) near-field electron energy loss (EELS) and far-field optical transmission UV-vis spectroscopic measurements. Susceptibility to second-order nonlinear frequency …

Characterization Of Coupled Gold Nanoparticles In A Sparsely Populated Square Lattice, Roy Truett French Iii

Graduate Theses and Dissertations

Metal nanoparticles deposited in regular arrays spaced at optical wavelengths support a resonance due to a coherent coupling between localized surface plasmon mode and lattice diffraction allowing for engineering of tunable devices for use in biological sensors, nanoantennae, and enhanced spectroscopy. Techniques such as electron beam lithography, focused ion beam lithography, nanosphere lithography, and nanoimprint lithography are used for fabrication but are limited by cost, device throughput, and small deposition. Polymer soft lithography and continuous dewetting of particles is a potentially viable alternative showing promise in all of those areas. This thesis developed the fabrication of a refined hydrophilic nanoimprinted …

The Study Of Plasmonics In Nanohole Metallic Metamaterials, Kieffer J. Davieau

Electronic Thesis and Dissertation Repository

Plasmonics is the study of light-matter interaction. The interaction of incident light (photons) with surface plasmons present in metamaterials results in unique optical properties. Nanohole arrays are a metamaterial consisting of an array of sub-wavelength holes perforated in an optically thin metallic film which resides upon a dielectric material. The interaction of light with the surface plasmons present in the nanohole array leads to extraordinary optical transmission which produces resonance peaks with a higher intensity than the incident light. By changing the physical parameters of the nanohole array, such as hole size and periodicity, the resonance peaks can be tuned …

Optical Forces Generated By Plasmonic Nanostructures, Matthew A. Moocarme

Dissertations, Theses, and Capstone Projects

For millennia, scientists have sought to uncover the secrets of what holds the world together. Optical physicists are often at the forefront, unraveling material properties through investigations of light-matter interactions. As the field has progressed, the smallest unit at which matter can be probed and manipulated has subsequently decreased. The resulting sub-field nanophotonics- which reflects the processing of light at the nanoscale- has blossomed into a vast design space for both applied and theoretical researchers. Plasmonics, the phenomena by which the electron-density of a material oscillates in response to incident electromagnetic radiation, is a subject that has excited nanophotonics researchers …

Plasmon-Mediated Energy Conversion In Metal Nanoparticle-Doped Hybrid Nanomaterials, Jeremy Dunklin

Graduate Theses and Dissertations

Climate change and population growth demand long-term solutions for clean water and energy. Plasmon-active nanomaterials offer a promising route towards improved energetics for efficient chemical separation and light harvesting schemes. Two material platforms featuring highly absorptive plasmonic gold nanoparticles (AuNPs) are advanced herein to maximize photon conversion into thermal or electronic energy. Optical extinction, attributable to diffraction-induced internal reflection, was enhanced up to 1.5-fold in three-dimensional polymer films containing AuNPs at interparticle separations approaching the resonant wavelength. Comprehensive methods developed to characterize heat dissipation following plasmonic absorption was extended beyond conventional optical and heat transfer descriptions, where good agreement was …

A Transfer Matrix Approach To Aid In The Design And Optimization Of Hybrid Advanced Passive Structures For Enhancing Photovoltaic Efficiency, James Walshe, Sarah Mccormack, Hind Ahmed, John Doran

Conference Papers

The addition of a luminescent down-shifting (LDS) layer directly onto a photovoltaic (PV) cell introduces additional loss mechanisms within the system. The combination of non-ideal photo-luminescent materials encapsulated within a limited range of viable host materials, with the increased reflection losses arising from the newly created interface represent losses which must be overcome for LDS to offer an enhancement to the underlying cells efficiency. Exploiting the interaction between the highly enhanced electric fields established close to a metal nanoparticles (MNP’s) surface is one route aimed at mitigating the poor optical properties of the luminophore-host combinations available. Alternative approaches, aimed at …

Plasmonic Devices Based On Transparent Conducting Oxides For Near Infrared Applications, Kim Jongbum

Open Access Dissertations

In the past decade, there have been many breakthroughs in the field of plasmonics and nanophotonics that have enabled optical devices with unprecedented functionalities. Even though remarkable demonstration of at photonic devices has been reported, constituent materials are limited to the noble metals such as gold (Au) and silver (Ag) due to their abundance of free electrons which enable the support of plasmon resonances in the visible range. With the strong demand for extension of the optical range of plasmonic applications, it is now a necessity to explore and develop alternative materials which can overcome intrinsic issues of noble metals …