Physics Commons^™

Novel As-S-Se Compositions Of Solution-Processed Chalcogenide Thin Films For Infrared Optics, Annabella Orsini

Physics and Astronomy Honors Papers

Chalcogenide glasses (ChGs) have a wide range of interdisciplinary applications. In industry, ChGs are used to vastly improve infrared sight abilities. There are, however, improvements that can be made to the films’ stability, cost, and flexibility. Our project seeks to produce thin films that have these improvements, with capabilities comparable or better than what is widely used in the field. Thin films created through solution-based processes have proven to be much more flexible in comparison to bulk glass versions. Other elements in Group 16, such as Sulfur and Selenium have shown across literature to be a cost-effective alternative to Tellurium …

Emission Spectroscopy Of Ingaas Quantum Dots Via High-Resolution Fabry-Perot Interferometer, Raju Bhai Kc

Graduate Theses, Dissertations, and Problem Reports

Single photons emitted from self-assembled quantum dots have been widely studied to use as a promising qubit for quantum information processing. Therefore, it is critical to fully understand the emission spectra from the quantum dot's excitation if we want to use a single photon as a quantum bit. It is almost impossible to produce rotationally symmetric quantum dots due to various growth conditions and restrictions. So the real quantum dots do not have a perfectly symmetric structure. A broken rotational symmetry causes an asymmetric exchange interaction between electron and hole, leading to a fine structure splitting between two excited states. …

Surface Reconstruction In Iron Garnets, Sushree Dash

Dissertations, Master's Theses and Master's Reports

This dissertation presents the results of a study investigating the physical mechanisms underlying an unexpectedly large increase in magneto-optic efficiency observed in iron garnet. Such materials are technologically important for telecommunications due to their nonreciprocal optical action. In the past, our group had found evidence of an enhanced Faraday rotation in bismuth-substituted iron garnet films less than 50 nm thick. Subsequent investigation revealed that this enhancement could be traced to surface effects. This is significant because understanding these phenomena could be used to formulate engineering solutions for device miniaturization. In this dissertation, we present the result of a research project …

Control Of Nonlinear Properties Of Van Der Waals Materials, Rezlind Bushati

Dissertations, Theses, and Capstone Projects

Van der Waals materials are a broad class of materials that exhibit unique optoelectronic properties. They provide a rich playground for which they can be integrated into current on-chip devices due to their nanometer-scale size, and be utilized for studying fundamental physics. Strong coupling of emitters to microcavities provides many opportunities for new exotic physics through the formation of hybrid quasi-particles exciton-polaritons. This thesis
focuses on exploring and enhancing nonlinearity of van der Waals materials through strongly coupling to microcavities. By taking advantage of the stacking order of TMDs, we show intense second-harmonic generation from bulk, centrosymmetric TMD systems. In …

Monitoring Bacteria Cultures Using Near Infrared (Nir) Binary Spectronephelometry (Bsn), Raman Spectra And Principal Component Analysis (Pca), Steven Ortiz

Dissertations - ALL

Current noninvasive methods cannot continuously and simultaneously monitor the concentrations of cells and media components that define the state of native bacterial cultures, because of changing turbidity. A new technique, binary spectronephelometry (BSN) has the same or better sensitivity and precision for population monitoring as optical density at 600nm (OD600), while simultaneously measuring metabolic processes. The BSN algorithm uses laser induced emission to probe mildly turbid media i.e., propagation of light occurs in the single scattering regime. A BSN "training set" associates a grid of elastic emission measurements, comprising Rayleigh and Mie scattering, and inelastic emission measurements, comprising fluorescence and …

Experimental Investigation Of All-Optical Production Of Metastable Krypton, Joshua Carl Frechem

Physics Theses & Dissertations

Metastable production of noble gases requires significant energy due to their filled valence shells. These transitions from the ground state are in the vacuum ultraviolet and extreme ultraviolet, which are relatively inaccessible to lasers. This necessitates the use of either electron/ion bombardment via inefficient glow discharges or the use of high-power lasers and nonlinear processes. The all-optical production efficiency using these high-power lasers promises to be orders of magnitude higher than glow discharges, but far more costly. This work looks to improve all-optical production of metastable krypton (Kr*) through the use of a commercially available vacuum ultraviolet lamp with a …

Characterization And Coherent Spin Selective Manipulation Of Quantum Dot Energy Levels, Tristan Anthony Wilkinson

Graduate Theses, Dissertations, and Problem Reports

Semiconductor quantum dots (QDs) are promising candidates to fulfill a wide range of applications in real-world quantum computing, communication, and networks. Their excellent optical properties such as high brightness, single-photon purity, and narrow linewidths show potential utility in many areas. In order to realize long term goals of integration into complex and scalable quantum information systems, many current challenges must be overcome. One of these challenges is accomplishment of all necessary computing operations within a QD, which might be enabled by coherent manipulation of single QD energy level structures. In the realm of scalability for quantum devices, a way to …

Charge Dynamics Of Inas Quantum Dots Under Resonant And Above-Band Excitation, Gary R. Lander Jr

Graduate Theses, Dissertations, and Problem Reports

Research involving light-matter interactions in semiconductor nanostructures has been an interesting topic of investigation for decades. Many systems have been studied for not only probing fundamental physics of the solid state, but also for direct development of technological advancements. Research regarding self-assembled, epitaxially grown quantum dots (QDs) has proven to be prominent in both regards. The development of a reliable, robust source for the production of quantum bits to be utilized in quantum information protocols is a leading venture in the world of condensed matter and solid-state physics. Fluorescence from resonantly driven QDs is a promising candidate for the production …

Ultrafast Spectroscopy Of Air Lasing In Filaments, Brian Robert Kamer

Optical Science and Engineering ETDs

Filamentation in air is a phenomenon that has been extensively investigated for the last two decades. At sufficiently high intensity, even air is a nonlinear medium. These intensities are reached with ultrashort pulses (50 to 100 fs) of more than 1 J energy, which self-focus in air, reach ionizing intensities of oxygen and nitrogen, creating a plasma that defocuses the beam. The air filament is a self-induced waveguide resulting from a balance of focusing and defocusing. In this work new techniques were developed to visualize and analyze this phenomenon through its emission, in particu- lar the UV emission of the …

Linear And Non Linear Properties Of Two-Dimensional Exciton-Polaritons, Mandeep Khatoniar

Dissertations, Theses, and Capstone Projects

Technology has been accelerating at breakneck speed since the first quantum revolution, an era that ushered transistors and lasers in the late 1940s and early 1960s. Both of these technologies relied on a matured understanding of quantum theories and since their inception has propelled innovation and development in various sectors like communications, metrology, and sensing. Optical technologies were thought to be the game changers in terms of logic and computing operations, with the elevator pitch being "computing at speed of light", a fundamental speed limit imposed by this universe’s legal system (a.k.a physics). However, it was soon realized that that …

The Primary Volatile Composition Of Comet C/2015 Er61 (Panstarrs), Aaron Butler

Theses

In the outer edges of the solar system exist two regions: the Kuiper belt and Oort cloud. These two regions have a high amount of icy bodies (comets) orbiting the Sun. Comets located within the Oort cloud and Kuiper belt contain an ancient codex to the solar systems contents, before the formation of our solar system. Presented are near-infrared, high-resolution (λ/Δλ ~40000) data obtained from the immersion-grating echelle spectrograph iSHELL at the 3m NASA Infrared Telescope Facility (IRTF) in Maunakea, Hawaii of the Oort cloud comet C/2015 ER61 (PANSTARRS). Observations took place on April 15 and 17 in 2017 while …

Mult-Spectral Imaging Of Vegetation With A Diffractive Plenoptic Camera, Tristan R. Naranjo

Theses and Dissertations

Snapshot multi-spectral sensors allow for object detection based on its spectrum for remote sensing applications in air or space. By making these types of sensors more compact and lightweight, it allows drones to dwell longer on targets or the reduction of transport costs for satellites. To address this need, I designed and built a diffractive plenoptic camera (DPC) which utilized a Fresnel zone plate and a light field camera in order to detect vegetation via a normalized difference vegetation index (NDVI). This thesis derives design equations by relating DPC system parameters to its expected performance and evaluates its multi-spectral performance. …

Comparative Experimental And Theoretical Study Of Dopamine And Serotonin Interaction, Jose A. Guerrero

Open Access Theses & Dissertations

To accurately identify and measure the concentrations of dopamine (DA) and serotonin (5-HT) in mixtures of these neurotransmitters without labeling, a comprehensive, comparative computational and Raman experimental analysis is provided. While the distinction between these two analytes may be accomplished for concentrations in the millimolar range of these mixtures, their accurate quantification remains unattainable. As shown for the first time in this study, potential creation of a new composite resulting from their interactions with each other could be a reason for this lack of quantification.

Although this new hydrogen-bonded complex greatly complicates future analyte differentiation and quantification at concentrations typical …

Development Of A Ground-Based Aerial-Tracking Instrument For Open-Path Spectroscopy To Monitor Atmospheric Constituents, Haden Hodges

Civil Engineering Undergraduate Honors Theses

A ground-based aerial-tracking instrument, known as the Ground Tracker, designed to provide spectral data to quantify greenhouse gases is under development. The Ground Tracker includes an Optical System including a high power rifle scope, video camera, and spectrometer used to locate an active light source from the Emitter, and collect spectral data by utilizing an actuating mirror. The implementation of this instrument could be made low cost by utilizing existing weather balloon infrastructure to allow the Emitter to be placed into the lower stratosphere. The recovery of the emitter will be possible by tracking the GPS coordinates. Weather balloon instrument …

The Population Densities Of Argon Metastable Levels, Nada Khogeer, Chelsy Gonzalez, Milka Nikolic

Physics and Astronomy

In this experiment, we used the optical emission spectroscopy (OES) method to obtain the main properties of low temperature Argon plasma. The experiment was sustained in powers and pressures that ranges from 30-100 W and 15-100 mTorr. We used numerical methods for the Argon kinetic model to calculate metastable levels and resonant states for the first excited states in low temperature Argon plasma. By finding the ratio of two spectral lines and finding another ratio from a different upper energy level that goes down to the same two lower energy levels, we can construct a system of two nonlinear equations. …

Spectroscopy Of Neon For The Advanced Undergraduate Laboratory, H. C. Busch, M. B. Cooper, C. I. Sukenik

Physics Faculty Publications

We describe a spectroscopy experiment, suitable for upper-division laboratory courses, that investigates saturated absorption spectroscopy and polarization spectroscopy in a neon discharge. Both experiments use nearly identical components, allowing students to explore both techniques in a single apparatus. Furthermore, because the wavelength of the laser is in the visible part of the spectrum (640 nm), the experiment is well-suited for students with limited experience in optical alignment. The labs nicely complement a course in atomic or plasma physics, provide students with the opportunity to gain important technical skills in the area of optics and lasers, and can provide an introduction …

Estimating And Correcting Interference Fringes In Infrared Spectra In Infrared Hyperspectral Imaging, Ghazal Azarfar, Ebrahim Aboualizadeh, Nicholas Walter,, Simona Ratti, Camilla Olivieri, Alessandra Alessandra, Michael Nasse, Achim Kohler, Mario Giordano, Carol Hirschmugl

Physics Faculty Articles

Short-term acclimation response of individual cells of Thalassiosira weissflogii was monitored by Synchrotron FTIR imaging over the span of 75 minutes. The cells, collected from batch cultures, were maintained in a constant flow of medium, at an irradiance of 120 μmol m−2 s−1 and at 20 °C. Multiple internal reflections due to the micro fluidic channel were modeled, and showed that fringes are additive sinusoids to the pure absorption of the other components of the system. Preprocessing of the hyperspectral cube (x, y, Abs(λ)) included removing spectral fringe using an EMSC approach. Principal component analysis of the time series of …

Analysis Of The Red And Green Optical Absorption Spectrum Of Gas Phase Ammonia, Nikolai F. Zobov, Phillip A. Coles, Roman I. Ovsyannikov, Aleksandra A. Kyuberis, Robert J. Hargreaves, Peter F. Bernath, Jonathan Tennyson, Sergei N. Yurchenko, Oleg L. Polyansky

Chemistry & Biochemistry Faculty Publications

Room temperature NH₃ absorption spectra recorded at the Kitt Peak National Solar Observatory in 1980 are analyzed. The spectra cover two regions in the visible: 15,200 - 15,700 cm^-1 and 17,950 - 18,250 cm^-1. These high overtone rotation-vibration spectra are analyzed using both combination differences and variational line lists. Two variational line lists were computed using the TROVE nuclear motion program: one is based on an ab initio potential energy surface (PES) while the other used a semi-empirical PES. Ab initio dipole moment surfaces are used in both cases. 95 energy levels with J = 1 …

Multispectral Identification Array, Zachary D. Eagan

Computer Engineering

The Multispectral Identification Array is a device for taking full image spectroscopy data via the illumination of a subject with sixty-four unique spectra. The array combines images under the illumination spectra to produce an approximate reflectance graph for every pixel in a scene. Acquisition of an entire spectrum allows the array to differentiate objects based on surface material. Spectral graphs produced are highly approximate and should not be used to determine material properties, however the output is sufficiently consistent to allow differentiation and identification of previously sampled subjects. While not sufficiently advanced for use as a replacement to spectroscopy the …

Micro-Spectroscopy Of Bio-Assemblies At The Single Cell Level, Jeslin Kera

Honors Undergraduate Theses

In this thesis, we investigate biological molecules on a micron scale in the ultraviolet spectral region through the non-destructive confocal absorption microscopy. The setup involves a combination of confocal microscope with a UV light excitation beam to measure the optical absorption spectra with spatial resolution of 1.4 μm in the lateral and 3.6 μm in the axial direction. Confocal absorption microscopy has the benefits of requiring no labels and only low light intensity for excitation while providing a strong signal from the contrast generated by the attenuation of propagating light due to absorption. This enables spatially resolved measurements of single …

Identification Of Photocurrents In Topological Insulators, Derek A. Bas, Rodrigo A. Muniz, Sercan Babakiray, David Lederman, J. E. Sipe, Alan D. Bristow

Faculty & Staff Scholarship

Optical injection and detection of charge currents is an alternative to conventional transport and photoemission measurements, avoiding the necessity of invasive contact that may disturb the system being examined. This is a particular concern for analyzing the surface states of topological insulators. In this work one- and two-color sources of photocurrents are isolated and examined in epitaxial thin films of Bi2Se3. We demonstrate that optical excitation and terahertz detection simultaneously captures one- and two-color photocurrent contributions, which has not been required for other material systems. A method is devised to extract the two components, and in doing so each can …

Measuring The Hyperfine Splittings Of Lowest Energy Atomic Transitions In Rubidium, Benjamin D. Graber

Undergraduate Honors Thesis Projects

The goal of this experiment was to measure the hyperfine energy splittings of the ground to first excited state transitions in rubidium using saturated absorption spectroscopy. Using this technique, we measured these transition energy spectra by taking the difference of two photodiode outputs due to multiple beams of a single laser scanned over a range of frequencies and shone through a cell of Rb vapor. When the laser frequency was resonant with an atomic transition, photons of those frequencies were absorbed, leaving a dip in intensity of the beam measured at the photodiode. One of the two laser beams had …

Optical Spectroscopy Of Xenon-Related Defects In Diamond, Yury Dziashko

Dissertations, Theses, and Capstone Projects

The work presents the results of optical studies of Xe-related defect in diamond. This defect is one of a few having narrow zero-phonon line in the near-infrared part of the photo-luminescence spectra. It appears in diamond after Xe+ ion implantation followed by thermal annealing. Given unique physical properties of diamond (hardness, optical transparency in wide spectral range, chemical inertness, high thermal conductivity, low thermal expansion coefficient) and stability of Xe-related center it can be viewed as an potential candidate for the source of single-photons, or as optically manipulated qubit, not unlike nitrogen-vacancy center. However, compared to the latter Xe-related center …

Basic Astronomy Labs, Terry L. Smith, Michael D. Reynolds, Jay S. Huebner

Jay S Huebner

Providing the tools and know-how to apply the principles of astronomy first-hand, these 43 laboratory exercises each contain an introduction that clearly shows budding astronomers why the particular topic of that lab is of interest and relevant to astronomy. About one-third of the exercises are devoted solely to observation, and no mathematics is required beyond simple high school algebra and trigonometry.Organizes exercises into six major topics—sky, optics and spectroscopy, celestial mechanics, solar system, stellar properties, and exploration and other topics—providing clear outlines of what is involved in the exercise, its purpose, and what procedures and apparatus are to be used. …

Steady-State Switching And Dispersion/Absorption Spectroscopy Of Multistate Atoms Inside An Optical Ring Cavity, Jiteng Sheng

Graduate Theses and Dissertations

This thesis mainly focuses on the experimental investigations of electromagnetically induced transparency (EIT) related phenomena in various systems involving multilevel atoms inside an optical ring cavity. Semiclassical methods, e.g. density-matrix equations, are used through out this thesis to simulate the experimental results. First, the cavity transmission spectrum can be significantly modified when multilevel atoms are placed inside an optical ring cavity. Such coupled atom-cavity systems are well explained by the intracavity dispersion/absorption properties. Specifically, three-level lambda-type, four-level N-type and double-lambda-type atoms inside an optical ring cavity are investigated by examining their cavity transmission spectra. Second, optical multistability (OM) has been …

Uv-Visible Microscope Spectrophotometric Polarization And Dichroism With Increased Discrimination Power In Forensic Analysis, Dale Kevin Purcell

All Open Access Legacy Dissertations and Capstone Projects

Microanalysis of transfer (Trace) evidence is the application of a microscope and microscopical techniques for the collection, observation, documentation, examination, identification, and discrimination of micrometer sized particles or domains. Microscope spectrophotometry is the union of microscopy and spectroscopy for microanalysis. Analytical microspectroscopy is the science of studying the emission, reflection, transmission, and absorption of electromagnetic radiation to determine the structure or chemical composition of microscopic-size materials. Microscope spectrophotometry instrument designs have evolved from monochromatic illumination which transmitted through the microscope and sample and then is detected by a photometer detector (photomultiplier tube) to systems in which broad-band (white light) illumination …

Optical Detection And Classification Of Phytoplankton Taxa Through Spectral Analysis, Daniel Tyler Sensi

USF Tampa Graduate Theses and Dissertations

Phytoplankton serve as the bottom of the marine food web and therefore play an essential role in marine ecosystems. On the other hand, coastal phytoplankton communities can adversely affect the marine ecosystem and humans. A variety of techniques have been developed to measure and study phytoplankton, including in situ methods (e.g., flow cytometry) and laboratory methods (e.g., microscopic taxonomy). These provide accurate measurements of phytoplankton taxa and concentrations, yet they are limited in space and time, and synoptic information is difficult to obtain with these techniques.

Optical remote sensing may provide complementary information for its synoptic nature, as demonstrated by …

Random Transformations Of Optical Fields And Applications, Thomas Kohlgraf-Owens

Electronic Theses and Dissertations

The interaction of optical waves with material systems often results in complex, seemingly random fields. Because the fluctuations of such fields are typically difficult to analyze, they are regarded as noise to be suppressed. Nevertheless, in many cases the fluctuations of the field result from a linear and deterministic, albeit complicated, interaction between the optical field and the scattering system. As a result, linear systems theory (LST) can be used to frame the scattering problem and highlight situations in which useful information can be extracted from the fluctuations of the scattered field. Three fundamental problems can be posed in LST …

Laser-Induced Breakdown Spectroscopy, Connor Drake

Physics

The goal of this work is to use a Neodymium-Doped Yttrium Aluminum Garnet (Nd:YAG) Laser, spectrometer, and computer to create a Laser Induced Breakdown Spectroscopy (LIBS) system. LIBS utilizes a focused, high-powered, pulsed laser whose peak electric field ionizes materials at the beam focal point, creating localized plasma. The plasma state includes broken molecular bonds, atom/electron-ionization, and excited electrons, which on the macroscopic level is a loud “snap” and a bright spark. In this project, a fiber optic cable is used to capture light emitted from the spark, and direct it into a spectrometer which tallies the number of photons …

Spectroscopic Analysis Of Tungsten Oxide Thin Films For Sensor Applications, Jose Luis Enriquez Carrejo

Open Access Theses & Dissertations

The objective of this study is targeted toward improving the quality of pure tungsten oxide (WO3) for application to the detection of poisoning gases, especially of H2S. While pure WO3 is a recognized candidate for gas sensing, its characteristics are strongly dependent on the conditions and methods used in its deposition.

Samples of WO3 thin films analyzed in this work were grown on silicon and sapphire substrates using RF magnetron sputtering at a number of different substrate temperatures and Ar:O2 pressure ratios. The properties of the samples were investigated spectroscopically with the goal of determining how variations in the above …