Physics Commons^™

Analog Cosmology And Superfluidity In Atomic Gases And Electronic Materials, Anshuman Bhardwaj

LSU Doctoral Dissertations

We present a study of analog cosmological models in Bose-Einstein condensates (BEC) and in graphene, and superfluidity in a box-shaped traps. We start by examining the dynamics of a Bose-Einstein condensate (BEC) trapped inside an expanding toroid that can realize an analog inflationary universe. The expanding condensate forces phonons to undergo redshift and damping due to quantum pressure, owing to the thinness of the ring. We predict that such expanding BECs can exhibit spontaneous phonon creation from the vacuum state and show how it would manifest in the atom density and density correlations and discuss connections with the inflationary theory. …

Controlling Electro-Magnetic Functionality Of Ruthenates By Heterostructure Design, Zeeshan Ali

LSU Doctoral Dissertations

Perovskite oxides (ABO₃) show wide range of functionalities originating from interplay of structural, spin, charge, and orbital degrees of freedoms. The bulk perovskite structure could be controlled via conventional chemical substitution, though exploiting heterostructure engineering novel ground states could be observed which otherwise are absent in bulk. In this thesis, the interest is to explore the electro-magnetic phenomena as complex oxides are confined in heterostructures.

I first investigate electromagnetic properties of ultrathin epitaxial ruthenate: SrRuO₃ (SRO); spatially confined between SrTiO₃ (STO) i.e., STO⁵-SROⁿ-STO⁵ with n = 1- and 2-unit cells. It …

Experimental Investigation Of The Physical Properties Of Irmsnn (M = 1, 3 And N = 2, 4, 7), Smita Speer

LSU Doctoral Dissertations

Exploration of transition metal stannides, formed from a combination of transition metals (T) and Sn, has resulted in the discovery a variety of materials with interesting physical properties, which is in part due to the complexity of interactions that can occur between the T-d orbitals and Sn-p orbitals. There have been observations of (extremely) large magnetoresistance [1-4], topological flat and nearly flat bands [5-7], superconducting behavior in 2D and 3D systems [5, 8-11], ultrahigh carrier mobility [12-13], and more attributed to d-p orbital mixing in such systems. This dissertation will address the effects of T-Sn interactions …

Tuning Properties Of Topological Insulators: An Ab-Initio Approach, Karunya Shailesh Shirali

LSU Doctoral Dissertations

This thesis develops a first-principles based approach to explore the tuning of topological properties of the tetradymite topological insulators. We begin by setting up a framework to systematically obtain the bulk and surface properties of topological insulators, treating the structural and electronic properties on an equal footing. We determine a consistent method for including the van der Waals interactions, which are responsible for the weak coupling between sets of atomic layers in this family of layered materials, which is important in obtaining accurate structural properties. We obtain close agreement with experimental values for both the bulk and surface states.

To …

Interface-Induced Lattice Structure And Magnetism In Ultrathin Transition Metal Oxide Trilayers, David Howe

LSU Doctoral Dissertations

The study of magnetism has been a rich playground in condensed matter physics due to the multiple mechanisms capable of producing the effect and its relationship to multiple characteristics of a material. Transition metal oxides (TMOs) have been of particular interest for ongoing research into magnetic phenomenon due to the abundance of interesting physical phenomena found in member systems such as colossal magnetoresistance, skyrmion formation, and interface-driven 2D electron gases. Thin films introduce an additional thickness-dependent element, where reduction below a critical thickness eliminates the magnetic coherence of a system and FM order is lost. The atomic structure of these …

Effects Of Structure, Crystallographic Orientation, And Dimensionality On Emergent Properties Of Transition Metal Oxide Thin Films, Prahald Siwakoti

LSU Doctoral Dissertations

SrRuO₃ is the only example of ferromagnetic perovskite oxide of a 4d transition metal, wherein the electron -electron correlation is still relevant while the heavier 4d ion (Ru) gives it a larger spin-orbit coupling strength which makes it an interesting material to study. In this thesis, we present our investigation of the structure and properties of SrRuO₃ thin films of varying thickness grown on [001] and [111] crystallographic orientation of the SrTiO3 substrate. For SrRuO₃(001), we present microscopically the presence of 90◦ in-plane rotated structural domains that are identified by the difference in octahedral rotations and …

Majorana Quasiparticles In Topological Material Interfaces, David Alspaugh

LSU Doctoral Dissertations

In this dissertation we analyze how Majorana quasiparticles found on material interfaces of both topological insulators (TIs) and topological superconductors (TSCs) are affected by imperfections within their local environment. While these quasiparticles are predicted to be critical for the construction of quantum computers, they are typically modeled only under pristine conditions. Thus, although quantum computers may require the spatial manipulation of Majorana quasiparticles, these topological material interfaces are commonly studied in static contexts and their response to manipulation remains an open question. We first demonstrate that interface potentials on the topological insulator Bi₂Se₃ can enable the emergence …

Adsorption And Reconfiguration Of Amphiphiles At Silica-Water Interfaces: Role Of Electrostatic Interactions, Van Der Waals Forces And Hydrogen Bonds, Yao Wu

LSU Doctoral Dissertations

The ability to explore and predict metastable structures of hybrid self-assemblies is of central importance for the next generation of advanced materials with novel properties. As compared to their thermodynamically stable forms, the kinetically stabilized materials show improved functionality potentially over their stable counterparts. The self-assembly processes usually originate from weak intermolecular interactions, involving a dynamic competition between attractive and repulsive interactions. These weak forces, including van der Waals (vdW), electrostatic interaction and the hydrogen bonding (H-bonding), can be tuned by external stimuli, e.g., confinement, temperature and ionization, and consequently driving hybrid materials into different configurations. It is challenging to …

Quantum Criticality In Strongly Correlated Electron Systems, Samuel Obadiah Kellar

LSU Doctoral Dissertations

The study of the Hubbard model in three dimensions contains a variety of phases dependent upon the chosen parameters. This thesis shows that there is the indication of a zero temperature phase transition at a finite doping. The Hubbard model has been used to identify a similar quantum critical point in two dimensions. The presented results continue these investigations. The system demonstrates a strange metal phase at finite temperature which cannot be described in term of the conventional Fermi liquid. While there have been extensive studies over the past three decades for such materials in two dimensions, there are few …

Identifying Structure Transitions Using Machine Learning Methods, Nicholas Walker

LSU Doctoral Dissertations

Methodologies from data science and machine learning, both new and old, provide an exciting opportunity to investigate physical systems using extremely expressive statistical modeling techniques. Physical transitions are of particular interest, as they are accompanied by pattern changes in the configurations of the systems. Detecting and characterizing pattern changes in data happens to be a particular strength of statistical modeling in data science, especially with the highly expressive and flexible neural network models that have become increasingly computationally accessible in recent years through performance improvements in both hardware and algorithmic implementations. Conceptually, the machine learning approach can be regarded as …

Investigation Of Complex Magnetic Phenomena In Spinel Femn2o4, Mnfe2o4, And Nife2o4, Roshan Kumar Nepal

LSU Doctoral Dissertations

Frustrated magnetic systems, where all spin interactions cannot be simultaneously satisfied, have continued to attract interest due to a plethora of novel magnetic states that emerge in them due to frustration and their potential technological applications. Spinel oxides AB₂O₄, where A and B are metal ions) are an excellent testing ground for the exploration of frustrated magnetism. This dissertation presents the experimental investigation of complex magnetic phenomena in the spinel oxides FeMn₂O₄, MnFe₂O₄, and NiFe₂O₄.

FeMn₂O₄ and MnFe₂O_{4 …}

Examining Interaction Effects In 2d Fermi Gases Using Renormalization Group Theory, Sri Laalitya Uppalapati

LSU Doctoral Dissertations

We use the Renormalization Group (RG) method within the perturbation theory framework to study properties of a balanced, two-dimensional Fermi gas with short-range, attractive interactions in non-superfluid (normal) phase. We find that the RG method allows for the evaluation of logarithmic corrections to Equations of State in various regimes of density and temperature. We present two calculations using RG with perturbation theory. The first being a simplified RG scheme with an interpolation of crossover between RG flow in different regimes. The second calculation features a rigorous derivation whereby the Green's function within a standard perturbation theory is renormalized to derive …

Vibrational And Electronic Structure Of Environmentally Persistent Free Radicals Formed On Metal Oxide Nanoclusters And Single-Crystal Surfaces, Nadra Ibrahim Sakr

LSU Doctoral Dissertations

We have studied the morphology and electronic structure of transition metal oxides (TMOs) nanoparticles and single-crystal surfaces which are known to be active for the formation of environmentally persistent free radicals (EPFRs) from organic precursors. We have also investigated the effect of simulated solar irradiation on the formed EPFRs.

First, we examined the change in the vibrational and structural properties of TiO₂, ZnO, CuO, and Fe₂O₃ nanoparticles due to phenol adsorption at high temperature and thus EPFR formation on the surface of these TMOs. The paramagnetic signal observed by electron paramagnetic resonance (EPR) indicates the …

Nonlinear Optical Studies Of Bulk And Thin Film Complex Materials, Joel E. Taylor

LSU Doctoral Dissertations

Nonlinear optical studies of bulk and thin film materials provide a vast playground for physical and dynamical characterization. In this thesis, we have implemented experimental methods to probe novel phase transitions in single crystals using rotational anisotropic second harmonic generation (RASHG) and carrier dynamics in thin films with time-resolved pump-probe reflectivity. Furthermore, a novel low temperature ultra-high vacuum system coupled to nonlinear optics has been developed to extend lab capabilities. Doping (Bi_1-xSb_x)₂Se₃ with antimony, the surface electronic reconstruction near x=80% was identified with RASHG by deviations in the six-fold and three-fold polarization anisotropic …

The Effects Of Pressure And Magnetic Field On Phase Transitions And Related Physical Properties In Solid State Caloric Materials, Ahmad Ikhwan Us Saleheen

LSU Doctoral Dissertations

Solid-state caloric effects, such as the magnetocaloric (MCE) and barocaloric (BCE) effects, may be utilized in future cooling technologies that are more efficient and environment-friendly. Large caloric effects often occur near phase transitions, especially near coupled first-order magnetostructural transitions (MST), and are initiated by external parameters, such as magnetic field or hydrostatic pressure. In this dissertation, the effects of pressure, temperature, and magnetic field on the phase transitions in three material systems are studied in order to elucidate how the respective caloric effects are affected.

In the first study, the realization of a coupled MST in a MnNiSi-based system through …

Non-Centrosymmetric Superconductivity And Magnetism In The Presence Of Broken Symmetries, Mojammel Alam Khan

LSU Doctoral Dissertations

Non-centrosymmetric (NC) superconducting and magnetic compounds have been synthesized and investigated using magnetic, specific heat, and transport measurements, as well as by neutron scattering and quantum oscillations. The crystal structures of NC compounds are defined by the lack of an inversion center. In NC superconductors, a finite antisymmetric spin orbit coupling originating from broken inversion symmetry results in unconventional Cooper pairing. Instead of a single spin channel, the order parameter is a mixture of spin-singlet and spin-triplet states. For NC magnetic compounds, the antisymmetric and isotropic spin interactions compete, leading to a helical ground state.

We have studied the NC …