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Full-Text Articles in Other Oceanography and Atmospheric Sciences and Meteorology
Variations In Synechococcus Cell Quotas Of Phosphorus, Sulfur, Manganese, Iron, Nickel, And Zinc Within Mesoscale Eddies In The Sargasso Sea, Benjamin S. Twining, Daliangelis Nunez-Milland, Stefan Vogt, Rodney S. Johnson, Peter N. Sedwick
Variations In Synechococcus Cell Quotas Of Phosphorus, Sulfur, Manganese, Iron, Nickel, And Zinc Within Mesoscale Eddies In The Sargasso Sea, Benjamin S. Twining, Daliangelis Nunez-Milland, Stefan Vogt, Rodney S. Johnson, Peter N. Sedwick
OES Faculty Publications
The quotas of P, S, Mn, Fe, Ni, and Zn in individual Synechococcus cells collected from the surface and deep chlorophyll maximum (DCM) layer of three mesoscale eddies in the Sargasso Sea were measured using synchrotron X-ray fluorescence microscopy. Cells in a mode-water eddy had significantly higher P (57 +/- 10 amol) and Mn (28 +/- 7 zmol) cell quotas than cells collected from a cyclone (22 +/- 2 amol and 10 +/- 1 zmol, respectively) or anticyclone (25 +/- 3 amol and 18 +/- 3 zmol, respectively). Conversely, Ni and Zn quotas were significantly higher in the cells from …
A Chemical Ionization Mass Spectrometer For Continuous Underway Shipboard Analysis Of Dimethylsulfide In Near-Surface Seawater, Eric S. Saltzman, Warren J. De Bruyn, M. J. Lawler, Christa Marandino, C. A. Mccormick
A Chemical Ionization Mass Spectrometer For Continuous Underway Shipboard Analysis Of Dimethylsulfide In Near-Surface Seawater, Eric S. Saltzman, Warren J. De Bruyn, M. J. Lawler, Christa Marandino, C. A. Mccormick
Biology, Chemistry, and Environmental Sciences Faculty Articles and Research
A compact, low-cost atmospheric pressure, chemical ionization mass spectrometer ('mini-CIMS') has been developed for continuous underway shipboard measurements of dimethylsulfide (DMS) in seawater. The instrument was used to analyze DMS in air equilibrated with flowing seawater across a porous Teflon membrane equilibrator. The equilibrated gas stream was diluted with air containing an isotopically-labeled internal standard. DMS is ionized at atmospheric pressure via proton transfer from water vapor, then declustered, mass filtered via quadrupole mass spectrometry, and detected with an electron multiplier. The instrument described here is based on a low-cost residual gas analyzer (Stanford Research Systems), which has been modified …
Dms Air/Sea Flux And Gas Transfer Coefficients From The North Atlantic Summertime Coccolithophore Bloom, Christa Marandino, Warren J. De Bruyn, Scott Miller, Eric S. Saltzman
Dms Air/Sea Flux And Gas Transfer Coefficients From The North Atlantic Summertime Coccolithophore Bloom, Christa Marandino, Warren J. De Bruyn, Scott Miller, Eric S. Saltzman
Biology, Chemistry, and Environmental Sciences Faculty Articles and Research
Dimethylsulfide (DMS) atmospheric and oceanic concentrations and eddy covariance air/sea fluxes were measured over the N. Atlantic Ocean during July 2007 from Iceland to Woods Hole, MA, USA. Seawater DMS levels north of 55 degrees N ranged from 3 to 17 nM, with variability related to the satellite-derived distributions of coccoliths and to a lesser extent, chlorophyll. For the most intense bloom region southwest of Iceland, DMS air/sea fluxes were as high as 300 mu mol m(-2) d(-1), larger than current model estimates. The observations imply that gas exchange coefficients in this region are significantly greater than those estimated using …
The Aqueous Phase Yield Of Alkyl Nitrates From Roo+No: Implications For Photochemical Production In Seawater, Elizabeth E. Dahl, Eric S. Saltzman, Warren J. De Bruyn
The Aqueous Phase Yield Of Alkyl Nitrates From Roo+No: Implications For Photochemical Production In Seawater, Elizabeth E. Dahl, Eric S. Saltzman, Warren J. De Bruyn
Biology, Chemistry, and Environmental Sciences Faculty Articles and Research
Alkyl nitrates have been observed in remote oceanic regions of the troposphere and in the surface ocean. The mechanism for their production in the oceans is not known. A likely source is the reaction of ROO + NO (where R is an alkyl group). Steady-state laboratory experiments show that alkyl nitrates are produced in the aqueous phase via this reaction, with branching ratios of 0.23 +/- 0.04, 0.67 +/- 0.03, and 0.71 +/- 0.04 for methyl, ethyl, and propyl nitrate respectively. The branching ratios in aqueous solution are significantly higher than in the gas phase. Irradiation of surface seawaters yield …
Academic Fleet Renewal- Two Years Later, Larry Atkinson
Academic Fleet Renewal- Two Years Later, Larry Atkinson
CCPO Publications
(First paragraph) In November 2000, I wrote a Soapbox article on fleet renewal for Sea Technology. It is a little unsettling to see how slowly ideas move towards implementation. Nevertheless, we are making progress. In this editorial I will note a bit of that progress and try to guess where we will be in two more years.