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Full-Text Articles in Fresh Water Studies
Micro-Spi Sediment Profile Imaging Micro-Inspector, Andrew P. Corvin, Caleb T. Davies, Matt R. Ferrari
Micro-Spi Sediment Profile Imaging Micro-Inspector, Andrew P. Corvin, Caleb T. Davies, Matt R. Ferrari
Mechanical Engineering
This project was proposed by Dr. Brian Paavo through a desire to more easily study the benthic sediment layers of the ocean. To do so, he asked us to build a simple and compact machine for use in sediment profile imagery (SPI). Although devices like this already exist, they are all large scale devices that require a ship with a crane to deploy, which is expensive and time consuming. Instead, he desired a “micro” SPI, which is capable of being deployed from a small vessel that can easily navigate shallow waters. Our interpretation of these requirements was as follows: a …
Understanding N-Nitrosodimethylamine Formation In Water: Chloramine Chemistry, Kinetics, And A Proposed Reaction Pathway, Huong Thu Pham
Understanding N-Nitrosodimethylamine Formation In Water: Chloramine Chemistry, Kinetics, And A Proposed Reaction Pathway, Huong Thu Pham
Graduate Theses and Dissertations
The formation of N-nitrosodimethylamine (NDMA) in drinking water systems is a concern because of its potential carcinogenicity and occurrence at toxicologically relevant levels. The postulated mechanism for NDMA formation involves a substitution between dichloramine and amine-based precursors to form an unsymmetrical dimethylhydrazine (UDMH), which is then oxidized by ground-state molecular oxygen to form NDMA. However, this latter reaction is spin forbidden, thus likely occurs at a slow rate. It is hypothesized that the reaction between monochloramine and hydroxylamine (a nitrification product) may form an intermediate, which is involved in the NDMA formation pathway. This intermediate may also be generated from …