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Sea-Ice Melt Co2-Carbonate Chemistry In The Western Arctic Ocean: Meltwater Contributions To Air-Sea Co2 Gas Exchange, Mixed-Layer Properties And Rates Of Net Community Production Under Sea Ice, N. R. Bates, R. Garley, K. E. Frey, K. L. Shake, J. T. Mathis
Sea-Ice Melt Co2-Carbonate Chemistry In The Western Arctic Ocean: Meltwater Contributions To Air-Sea Co2 Gas Exchange, Mixed-Layer Properties And Rates Of Net Community Production Under Sea Ice, N. R. Bates, R. Garley, K. E. Frey, K. L. Shake, J. T. Mathis
Geography
The carbon dioxide (CO2)-carbonate chemistry of sea-ice melt and co-located, contemporaneous seawater has rarely been studied in sea-ice-covered oceans. Here, we describe the CO2-carbonate chemistry of sea-ice melt (both above sea-ice as "melt ponds" and below sea-ice as "interface waters") and mixed-layer properties in the western Arctic Ocean in the early summer of 2010 and 2011. At 19 stations, the salinity (∼0.5 to <6.5), dissolved inorganic carbon (DIC; ∼20 to <550 μmol kg-1) and total alkalinity (TA; ∼30 to <500 μmol kg-1) of above-ice melt pond water was low compared to the co-located underlying mixed layer. The partial pressure of CO2 (pCO2) in these melt ponds was highly variable (∼<10 to >1500 μatm) with the majority of melt ponds acting as potentially strong sources of CO2 to the atmosphere. The pH of melt pond waters was also highly variable ranging from mildly acidic (6.1 to 7) to slightly …
Annual Sea-Air Co2 Fluxes In The Bering Sea: Insights From New Autumn And Winter Observations Of A Seasonally Ice-Covered Continental Shelf, Jessica N. Cross, Jeremy T. Mathis, Karen E. Frey, Catherine E. Cosca, Seth L. Danielson, Nicholas R. Bates, Richard A. Feely, Taro Takahashi, Wiley Evans
Annual Sea-Air Co2 Fluxes In The Bering Sea: Insights From New Autumn And Winter Observations Of A Seasonally Ice-Covered Continental Shelf, Jessica N. Cross, Jeremy T. Mathis, Karen E. Frey, Catherine E. Cosca, Seth L. Danielson, Nicholas R. Bates, Richard A. Feely, Taro Takahashi, Wiley Evans
Geography
High-resolution data collected from several programs have greatly increased the spatiotemporal resolution of pCO2(sw) data in the Bering Sea, and provided the first autumn and winter observations. Using data from 2008 to 2012, monthly climatologies of sea-air CO2 fluxes for the Bering Sea shelf area from April to December were calculated, and contributions of physical and biological processes to observed monthly sea-air pCO2 gradients (ΔpCO2) were investigated. Net efflux of CO2 was observed during November, December, and April, despite the impact of sea surface cooling on ΔpCO2. Although the Bering Sea was believed to be a moderate to strong atmospheric …