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Full-Text Articles in Atmospheric Sciences
Evaluation Of 1,3,5 Trimethylbenzene Degradation In The Detailed Tropospheric Chemistry Mechanism, Mcmv3.1, Using Environmental Chamber Data, A. Metzger, J. Dommen, J. Duplissy, A. S.H. Prevot, J. Kleffmann, Yasin F. Elshorbany, A. Wisthaler, U. Baltensperger
Evaluation Of 1,3,5 Trimethylbenzene Degradation In The Detailed Tropospheric Chemistry Mechanism, Mcmv3.1, Using Environmental Chamber Data, A. Metzger, J. Dommen, J. Duplissy, A. S.H. Prevot, J. Kleffmann, Yasin F. Elshorbany, A. Wisthaler, U. Baltensperger
USF St. Petersburg campus Faculty Publications
The degradation mechanism of 1,3,5-trimethyl-benzene (TMB) as implemented in the Master Chemical Mechanism version 3.1 (MCM) was evaluated using data from the environmental chamber at the Paul Scherrer Institute. The results show that the MCM provides a consistent description of the photo-oxidation of TMB/NO(x) mixtures for a range of conditions. In all cases the agreement between the measurement and the simulation decreases with decreasing VOC-NO(x) ratio and in addition with increasing precursor concentration. A significant underestimation of the decay rate of TMB and thus underestimation of reactivity in the system, consistent with results from previous appraisals of the MCM, was …