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Full-Text Articles in Oceanography and Atmospheric Sciences and Meteorology

Biochar Applications To The Remediation Of Lead And Polychlorinated Biphenyl Contaminated Water, Victory Itua Igberase Aug 2021

Biochar Applications To The Remediation Of Lead And Polychlorinated Biphenyl Contaminated Water, Victory Itua Igberase

Theses and Dissertations

This study investigated the performance of biochar materials as adsorbents to remove Pb and polychlorinated biphenyl (PCB) in aqueous solutions. Batch adsorption and column experiment packed with biochar and geomaterials (pumice) in 1:1 volume ratio was evaluated to address the efficacy of biochar in removing Pb while only batch adsorption was employed for PCB removal with biochar materials. Overall, PT biochars performed the best (42–53 mg g−1) followed by BE biochars (10–32 mg g−1) and AB biochars (17–27 mg g−1) while high temperature biochars were favored in terms of maximum Pb adsorption capacity. Column Pb breakthrough showed similar results, with …


Adsorption Driven Regolith-Atmospheric Water Vapor Transfer On Mars: An Analysis Of Phoenix Tecp Data, Holly Nicole Farris Aug 2019

Adsorption Driven Regolith-Atmospheric Water Vapor Transfer On Mars: An Analysis Of Phoenix Tecp Data, Holly Nicole Farris

Graduate Theses and Dissertations

NASA’s Phoenix mission allowed for investigations of Martian diurnal water vapor cycles through the collection of temperature, relative humidity, and electric conductivity data by the Thermal and Electric Conductivity Probe (TECP) instrument. Using this data and previous experimental data, we propose a regolith-driven adsorption-desorption regime at the Phoenix landing site, where parameters intrinsic to the regolith are controlling localized relative humidity at the surface. To constrain these parameters, we model adsorption as a function of temperature and relative humidity across various Mars-relevant materials, defined by two layer-based adsorption theories: Langmuir (monolayer) and Brunauer-Emmett-Teller or BET (multilayer). Langmuir serves as an …


Bioremoval Of Phenol From Aqueous Solutions Using Native Caribbean Seaweed, Abel E. Navarro, Anibal Hernandez-Vega, Md Emran Masud, Loretta M. Roberson, Liz M. Diaz-Vázquez Dec 2016

Bioremoval Of Phenol From Aqueous Solutions Using Native Caribbean Seaweed, Abel E. Navarro, Anibal Hernandez-Vega, Md Emran Masud, Loretta M. Roberson, Liz M. Diaz-Vázquez

Publications and Research

Among several Puerto Rican algae, Sargassum sp. (SG) and Chaetomorpha (CM) showed the highest phenol adsorption capacity from aqueous solutions and were used in optimized adsorption batch experiments at room temperature. The effects of pH, adsorbent dose, phenol concentration, salinity and presence of interfering substances were evaluated. Initial solution pH exhibited a strong effect, mainly on the phenol aqueous chemistry; showing the maximum adsorption at pH 10. Sorption isotherm results were modelled according to the Langmuir, Tempkin and Freundlich equations. Isotherm modelling indicated a maximum adsorption capacity (qmax) of 82.10 and 17.7 mg of phenol per gram of SG and …


Minimizing The Potential For Groundwater Contamination From Agricultural Point Sources, Joseph H. Massey, Terry L. Lavy, John D. Mattice Jun 1989

Minimizing The Potential For Groundwater Contamination From Agricultural Point Sources, Joseph H. Massey, Terry L. Lavy, John D. Mattice

Technical Reports

An activated charcoal filtration unit was designed to remove pesticides from leftover pesticide solutions and rinsates generated under farm-like conditions. The system, fabricated for less than $1400 using readily available components, effectively removed the pesticides atrazine, benomyl, carbaryl, fluometuron, metolachlor, and trifluralin from wastewater generated on the University of Arkansas Agronomy Farm located in Fayetteville, AR. A total of 2253 L of wastewater were treated using the system. Of these 1768 L were generated from washing out the spray tank (rinsates) while 485 L stemmed from leftover pesticide solutions that were mixed, but not applied. Typical initial pesticide concentrations in …


Movement And Transformation Of Selected Organic Pollutants In Subsurface Environmet In Arkansas, Ali U. Shaikh Jun 1987

Movement And Transformation Of Selected Organic Pollutants In Subsurface Environmet In Arkansas, Ali U. Shaikh

Technical Reports

Several subsurface soil and groundwater samples from eastern, southern and central Arkansas were analyzed for chlorinated organic compounds commonly used as pesticides and industrial chemicals. No significant amount of these compounds were found in these samples. The adsorption/partition characteristics of some of these compounds, such as dichlorophenols, aldrin and endrin, were determined in siltloam, sandyloam and clay soils collected from the above geographical locations. Results indicate that there is considerable difference in retention capability of different types of soils with respect to different pollutants. The partition coefficient of a particular compound in a certain type of soil can be related …