Oceanography and Atmospheric Sciences and Meteorology Commons^™

Exploring The Potential Impacts Of Climate Change On North America's Laurentian Great Lakes Tourism Sector, Natalie Chin

Open Access Dissertations

Climate change is one of the major challenges facing the global hospitality and tourism sector in the coming century and, given the important role that weather and climate play in all aspects of the tourism experience, tourism businesses owners need to start thinking about and enacting climate change adaptation strategies now. This work has utilized a combination of social science and physical science methods to (1) understand how the Great Lakes tourism sector could be impacted by climate change and (2) provide some insights into how researchers can help business owners prepare for these potential impacts. Overall, the results of …

The Cloud-Radiative Forcing Of The U.S. Landfalling Atmospheric Rivers, Qianwen Luo

Open Access Dissertations

Atmospheric rivers (ARs) are narrow channels in the atmosphere that transport an enormous amount of moisture from the tropics to the higher latitudes. Streaks of highly reflective clouds are observed along with the ARs in satellite imagery. These clouds both influence the moisture transport of ARs, as well as modify the Earth-Atmospheric energy budget through pathways such as cloud-radiative forcing (CRF). This dissertation studies the CRF of the U.S. Landfalling ARs in weather and climate scales. Three crucial questions are addressed. First, how do clouds produced by the ARs modulate the moisture and heat balance of the Earth-Atmospheric system? Even …

Modeling The Impact Of Land Surface Feedbacks On Post Landfall Tropical Cyclones, Subashini Subramanian

Open Access Dissertations

The land surface is an important component of numerical models. The land surface models are modules that control energy partitioning, compute surface exchange coefficients and form the only physical boundary in a regional scale numerical model. Thus, an accurate representation of land surface is critical to compute surface fluxes, represent the boundary layer evolution and affect changes in weather systems. Land surface can affect landfalling tropical cyclones in two ways: (i) when the cyclone is offshore and land can influence cyclones by introducing dry (or moist) air that can weaken (or strengthen) the organized convective structure of cyclones, and (ii) …

Unraveling The Fingerprints Of Nox Using Stable Isotopes: Implications For Nox Source Partitioning And Oxidation Chemistry, Wendell William Walters

Open Access Dissertations

The nitrogen (N) and oxygen (O) stable isotope composition (δ15N & δ18O) of nitrogen oxides (NOx )may be a useful tool for constraining NOx emission sources as well as for understanding the atmospheric oxidation pathways responsible for its removal if various NOx sources and sink processes exhibit characteristic isotopic compositions (“fingerprints”). However, this requires (1) an accurate and complete inventory of δ15N(NOx) values from major emission sources, (2) an assessment of the kinetic and equilibrium isotope effects that can impact δ15N and δ18O values of NOx, (3) and test these assumptions by conducting accurate in situ δ15N and δ18O measurements …

An Examination Of Geographic Patterns Of Soil Climate And Its Classification In The U.S. System Of Soil Taxonomy, Hans Edwin Winzeler

Open Access Dissertations

Soil climate, the record of temporal patterns of soil moisture and temperature, is an important component of the structure of U.S. Soil Taxonomy. The U.S. Soil Survey has used the Newhall Simulation Model (NSM) for estimating soil climate from atmospheric climate records at weather stations since the 1970s. The current soil climate map of the U.S. was published in 1994 by using NSM runs from selected weather stations along with knowledge-based hand-drawn mapping procedures. We developed a revised soil climate mapping methodology using the NSM and digital soil mapping techniques.

The new methodology is called Grid Element Newhall Simulation Model …

Studies Of Arctic Tropospheric Ozone Depletion Events Through Buoy-Borne Observations And Laboratory Studies, John W. Halfacre

Open Access Dissertations

The photochemically-induced destruction of ground-level Arctic ozone in the Arctic occurs at the onset of spring, in concert with polar sunrise. Solar radiation is believed to stimulate a series of reactions that cause the production and release of molecular halogens from frozen, salty surfaces, though this mechanism is not yet well understood. The subsequent photolysis of molecular halogens produces reactive halogen atoms that remove ozone from the atmosphere in these so-called “Ozone Depletion Events” (ODEs). Given that much of the Arctic region is sunlit, meteorologically stable, and covered by saline ice and snow, it is expected that ODEs could be …

The Use Of Stable Isotopes And Particulate Matter In The Investigation Of Local And Regional Atmospheric Chemistry, Tanya Lynn Katzman

Open Access Dissertations

The chemical composition of particulate matter (PM), a known contributor to air pollution, is highly variable, and elemental analysis reveals information about local and regional sources, as well as how air masses and climate influence PM compositions. Seasonal changes in climate, such as temperature, amount of daylight, or meteorological patterns influence source emissions (increased residential heating activities, decreased natural soil emissions) and the relative importance of certain chemical pathways in the atmosphere. Since the magnitude of these seasonal changes are highly dependent on location, each sampling site is unique and the chemical composition of PM provides valuable insight into local …

Evolutionary Potential Of A Dispersal-Restricted Species In Response To Climate Change, Lorena Torres Martinez

Open Access Dissertations

Habitat replacement and fragmentation associated with projected climate change pose a critical threat to global biodiversity. Edaphically limited plant species with restricted dispersal abilities will be especially handicapped to track their optimal climate spatially. Instead, the persistence of these species will depend on their capacity to adapt in situ to novel climate regimes. Here I evaluated the evolutionary potential of Lasthenia fremontii, an annual plant species restricted to ephemeral wetlands called vernal pools in California to adapt to the projected patterns of climate change. Across L. fremontii distribution there is a latitudinal gradient in precipitation which, combined with reduced …

Crop Modeling For Assessing And Mitigating The Impacts Of Extreme Climatic Events On The Us Agriculture System, Zhenong Jin

Open Access Dissertations

The US agriculture system is the world’s largest producer of maize and soybean, and typically supplies more than one-third of their global trading. Nearly 90% of the US maize and soybean production is rainfed, thus is susceptible to climate change stressors such as heat waves and droughts. Process-based crop and cropping system models are important tools for climate change impact assessments and risk management. As data- science is becoming a new frontier for agriculture growth, the incoming decade calls for operational platforms that use hyper-local growth monitoring, high-resolution real-time weather and satellite data assimilation and cropping system modeling to help …

Climate Change And Hazardous Convective Weather In The United States: Insights From High-Resolution Dynamical Downscaling, Kimberly A. Hoogewind

Open Access Dissertations

Global climate model (GCM) projections increasingly suggest that large-scale environmental conditions favorable for hazardous convective weather (HCW) may increase in frequency in the future due to anthropogenic climate change. However, this storm environment-based approach is undoubtedly limited by the assumption that convective-scale phenomena will be realized within these environments. The spatial resolution of GCMs remains much too coarse to adequately represent the scales at which severe convective storms occur, including processes that may lead to storm initiation. With the advancement of computing resources, however, it has now become feasible to explicitly represent deep convective storms within a high-resolution regional climate …

A Hydroclimatic Assessment Of The U.S. Corn Belt Across Spatial And Temporal Scales, Olivia B. Kellner

Open Access Dissertations

The term hydroclimate is used to describe the climate of a given location as determined by the incident radiant energy (temperature) and the existence of water in its various forms on Earth. Two types of climate comprise the science of hydroclimatology: the climate as established by general global circulation patterns at specific locations on Earth (large-scale climate) and the climate established at Earth's surface resulting from the daily fluxes of radiant energy and water in its various forms between the atmosphere, Earth's surface, and the subsurface (local-scale climate) (Shelton 2009). This dissertation investigates different spatial and temporal scales of the …

Fully Electronic Method Of Measuring Post-Release Gap And Gradient/Residual Stress Of A Mems Cantilever, Andrew Stephen Kovacs

Open Access Dissertations

Smartphones and other wireless devices have become ubiquitous over the past decade, and the RF front-end inside of them has become more complex and disproportionately consumes more power compared to other components. Micro-electromechanical systems (MEMS) have a huge potential to reduce these problems while simultaneously offering superior performance compared to current leading-edge technology. However, MEMS technology has difficulty transitioning from the lab to large-scale manufacturing due to the unpredictability of device lifetime and manufacturability issues. This can be mitigated by investigating how critical material or physical parameters (gap, stress, Young's modulus, material thickness, etc.) vary from manufacturing uncertainties and how …

Studies Of The Interaction Of Biogenic Volatile Organic Compounds And Nox In Forest Environments, Kevin M. Mcavey

Open Access Dissertations

Ozone is a pollutant that causes crop damage, adverse health effects, and is a contributor to global climate change. Ozone concentrations are predicted to rise over the next half-century along with global temperature. Ozone production is controlled by the chemistry between biogenic volatile organic compounds and NO_x (NO + NO₂), and therefore, a greater understanding of NO_x + BVOC chemistry along with their sources and sinks is needed. One large uncertainty in understanding NO_x + BVOC chemistry is the production of organic nitrates (RONO₂), which act as a radical termination step in the …

Spectroscopic Characterization And Photochemistry Of Nitrogen-Containing Molecules Relevant To Titan's Atmosphere, Deepali N. Mehta-Hurt

Open Access Dissertations

Titan's atmospheric chemistry has been the source of intrigue since the planetary body's discovery. Though there is a growing understanding of the atmospheric chemistry of small molecules on Titan, much less is known about larger molecule formation, and particularly about nitrile chemistry. This dissertation characterizes nitrile/isonitrile intermediates that are postulated to be important in Titan's atmosphere, adding to the necessary foundation for understanding Titan's atmospheric chemistry. The vibronic spectroscopy of para-diisocyanobenzene (pDIB, C≡N-Ph-N≡C) has been characterized as a first step towards photochemical studies that can test the transformation of the isonitrile group to other nitrogen-based functionalities.p …

Laboratory Studies On The Production Of Alpha-Pinene-Derived Organic Nitrates And Their Atmospheric Fate, Joel David Rindelaub

Open Access Dissertations

Currently, the formation yields of organic nitrates from the oxidation of biogenic volatile organic compounds, such as α-pinene, is highly uncertain, negatively impacting our knowledge on tropospheric ozone production and the fate of atmospheric NO_x. To lower this uncertainty, we quantified the organic nitrate yield from the OH radical oxidation of α-pinene under high NO_x conditions. The α-pinene- derived nitrates created in chamber experiments readily partitioned to the aerosol phase and underwent particle phase hydrolysis, indicating that these processes are likely a sink for atmospheric NO_x. The hydrolysis of organic nitrates was found to be …

Aircraft-Based Measurements For The Identification And Quantification Of Sources And Sinks In The Carbon Cycle, Dana R Caulton

Open Access Dissertations

Improved quantification of carbon-cycle sources and sinks is an important requirement for determining mitigation strategies and modeling future climate interactions. Analytically robust measurements require high-precision instrumentation and thoughtful experimental design to produce rigorous and reproducible results despite complex and quickly changing meteorological and environmental conditions. Here, an aircraft platform equipped with a high-precision cavity ring-down spectrometer for CO₂, CH₄ and H₂O quantification was used to acquire data from previously un-sampled sources. The aircraft mass-balance technique was used to quantify CH4 emissions from natural gas well pads in the drilling stage, which were 2-3 orders of …

Towards A Paradigm Shift In The Modeling Of Soil Organic Carbon Decomposition For Earth System Models, Yujie He

Open Access Dissertations

Soils are the largest terrestrial carbon pools and contain approximately 2200 Pg of carbon. Thus, the dynamics of soil carbon plays an important role in the global carbon cycle and climate system. Earth System Models are used to project future interactions between terrestrial ecosystem carbon dynamics and climate. However, these models often predict a wide range of soil carbon responses and their formulations have lagged behind recent soil science advances, omitting key biogeochemical mechanisms. In contrast, recent mechanistically-based biogeochemical models that explicitly account for microbial biomass pools and enzyme kinetics that catalyze soil carbon decomposition produce notably different results and …

Quantifying Crop Yield, Bioenergy Production And Greenhouse Gas Emissions From Cropland And Marginal Land Using A Model-Data Fusion Approach, Zhangcai Qin

Open Access Dissertations

Bioenergy is becoming increasingly attractive to many countries, but has sparked an intensive debate regarding energy, economy, society and environment. Biofuels provide alternative energy to conventional fossil fuels. However, the environmental impact of producing and using biofuel is a major concern to our society. This study is dedicated to quantifying and evaluating biofuel production and potential climate change mitigation due to potential large-scale bioenergy expansion in the conterminous United States, using model-data fusion approaches.

Biofuel made from conventional (e.g., maize (Zea mays L.)) and cellulosic crops (e.g., switchgrass (Panicum virgatum L.) and Miscanthus (Miscanthus × giganteus)) …

Uncertainty In Climatic Change Impacts On Multiscale Watershed Systems, Olga V. Tsvetkova

Open Access Dissertations

Uncertainty in climate change plays a major role in watershed systems. The increase in variability and intensity in temperature and precipitation affects hydrologic cycle in spatial and temporal dimensions. Predicting uncertainty in climate change impacts on watershed systems can help to understand future climate-induced risk on watershed systems and is essential for designing policies for mitigation and adaptation. Modeling the temporal patterns of uncertainties is assessed in the New England region for temperature and precipitation patterns over a long term. The regional uncertainty is modeled using Python scripting and GIS to analyze spatial patterns of climate change uncertainties over space …

Trophic Ecology Of Oxygen Minimum Zone Zooplankton Revealed By Carbon And Nitrogen Stable Isotopes, Rebecca Williams

Open Access Dissertations

Oxygen minimum zones (OMZs) are areas in which midwater oxygen concentration can be significantly lower than in non OMZ areas at comparable depths. OMZs are of great interest because of the limits oxygen availability places on life. The potential for OMZ expansion with warming of the oceans has refocused attention on the importance of these areas and their potential impacts on the global carbon cycle. The large open ocean OMZs of the Eastern Tropical Pacific and Arabian Sea are notable for their size, thickness, and the intensity of oxygen depletion (

Here, I use measurements of natural abundance carbon and …