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Full-Text Articles in Water Resource Management
Advanced Chemical Oxidation And Toxicity Reduction Of 2,4,6-Trichlorophenol By Using Fenton's Reagent: Part Ii, Dechlorination Kinetics, Somnath Basu, Venkat Sreenivasan, Irvine W. Wei
Advanced Chemical Oxidation And Toxicity Reduction Of 2,4,6-Trichlorophenol By Using Fenton's Reagent: Part Ii, Dechlorination Kinetics, Somnath Basu, Venkat Sreenivasan, Irvine W. Wei
Irvine W. Wei
Laboratory investigation has shown that Fenton's Reagent is a very effective oxidant for 2,4,6-Trichlorophenol (TCP). The authors reported the first phase of this research, consisting of five different reactions of Fenton's Reagent on TCP, at the 1995 AIChE Summer National Meeting in Boston as Part I of this paper. The results demonstrated total removal of TCP, with almost complete release of aromatic ring bound chlorine atoms into chloride ions, significant reduction of TOC, and very importantly, significant toxicity reduction compared to the original substrate. These results suggested that Fenton's Reaction can be considered as a candidate process for treatment of …
Advanced Chemical Oxidation And Toxicity Reduction Of 2,4,6-Trichlorophenol By Using Fenton's Reagent: Part Iv, Reaction Mechanism And Kinetics, Somnath Basu, Irvine W. Wei
Advanced Chemical Oxidation And Toxicity Reduction Of 2,4,6-Trichlorophenol By Using Fenton's Reagent: Part Iv, Reaction Mechanism And Kinetics, Somnath Basu, Irvine W. Wei
Irvine W. Wei
No abstract provided.
A Conceptual Continuous Process For The Treatment And Toxicity Reduction Of Wastewater Contaminated With 2,4,6-Trichlorophenol: Extended Abstract, Somnath Basu, Irvine W. Wei
A Conceptual Continuous Process For The Treatment And Toxicity Reduction Of Wastewater Contaminated With 2,4,6-Trichlorophenol: Extended Abstract, Somnath Basu, Irvine W. Wei
Irvine W. Wei
Fenton's Reagent is an aqueous solution of ferrous ions and hydrogen peroxide. Through laboratory experiments Fenton's Reagent has been shown to be an excellent treatment agent for the removal of organic contaminants dissolved in water. It carries out oxidative degradation of various organic substrates using the principle of advanced chemical oxidation. This is an excellent alternate route for the removal of hazardous and toxic chemicals, which are recalcitrant to biological treatment. The authors of this paper conducted an extensive laboratory investigation to study the degradation of 2,4,6- Trichlorophenol (TCP) using Fenton's Reagent, reported elsewhere. The results indicated an optimum H₂O₂:TCP …
Advanced Chemical Oxidation And Toxicity Reduction Of 2,4,6-Trichlorophenol By Using Fenton's Reagent: Part I, Kuang-Wei (Stone) Chen, Somnath Basu, Irvine W. Wei
Advanced Chemical Oxidation And Toxicity Reduction Of 2,4,6-Trichlorophenol By Using Fenton's Reagent: Part I, Kuang-Wei (Stone) Chen, Somnath Basu, Irvine W. Wei
Irvine W. Wei
The objective of this study is to exmnine the removal of a priority chlorinated aromatic pollutant, 2,4,6-Trichlorophenol (TCP), in aqueous solution by using Fenton's Reagent (a mixture of hydrogen peroxide and ferrous iron catalyst). Chlorinated phenols are priority pollutants, regulated by stringent discharge litnits. The presence of chlorine increases the toxicity of these phenolic compounds and decreases their biodegradability. Therefore, the processes of oxidation and dechlorination of chlorinated phenols by using Fenton's Reagent were employed in this study. Experiments were conducted in one-liter stirred batch reactors at 20°C. Three parallel reactors were used for reactions between 0.25 mM 2,4,6-TCP and …
Advanced Chemical Oxidation Of 2,4,6-Trichlorophenol By Using Fenton's Reagent - Dechlorination And Toxicity Reduction, Kuang-Wei (Stone) Chen, Irvine W. Wei
Advanced Chemical Oxidation Of 2,4,6-Trichlorophenol By Using Fenton's Reagent - Dechlorination And Toxicity Reduction, Kuang-Wei (Stone) Chen, Irvine W. Wei
Irvine W. Wei
Chlorinated phenols are priority pollutants, regulated by stringent discharge limits. The presence of chlorine increases the toxicity of these phenolic compounds and decreases their biodegradability. This study is to examine the removal of a priority chlorinated aromatic pollutant, 2,4,6-trichlorophenol (TCP), in aqueous solution by using Fenton's Reagent (a mixture of hydrogen peroxide and fenous iron catalyst), in terms of dechlorination and toxicity reduction. Test results indicate that the higher the molar ratio of H₂O₂ to TCP, the faster the release of chloride from TCP. However, the chloride released in all runs eventually approach the same level of theoretical chloride concentration, …