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Separations Campaign (TRP)

Chemistry

Fullerenes

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Full-Text Articles in Oil, Gas, and Energy

Immobilization Of Fission Iodine By Reaction With A Fullerene Containing Carbon Compound And Insoluble Natural Matrix, Spencer M. Steinberg, Gary Cerefice, David W. Emerson Jan 2005

Immobilization Of Fission Iodine By Reaction With A Fullerene Containing Carbon Compound And Insoluble Natural Matrix, Spencer M. Steinberg, Gary Cerefice, David W. Emerson

Separations Campaign (TRP)

The recovery of iodine released during the processing of used nuclear fuel poses a significant challenge to the transmutation of nuclear waste. Iodine-129, a long-lived fission product formed by both commercial nuclear power generation and nuclear weapons production, is released when reprocessing nuclear fuel. Since iodine can be concentrated in the human thyroid, any uncontrolled release of iodine may result in an increased rate of thyroid cancer in the exposed population. For this reason, recovery of iodine is important for implementing any nuclear transmutation strategy.

The stability of the association of iodine with FCC and NOM products are studied. Product …


Development, Fabrication And Study Of Fullerene-Containing Carbon Material (Fcc) For Immobilization Of Iodine: Progress Report 1-3, Michael Savopulo, Boris E. Burakov Jan 2004

Development, Fabrication And Study Of Fullerene-Containing Carbon Material (Fcc) For Immobilization Of Iodine: Progress Report 1-3, Michael Savopulo, Boris E. Burakov

Separations Campaign (TRP)

During previous reporting periods we studied properties of iodine doped FCC in comparison with activated carbon. An additional goal was to investigate the possibility to convert iodine doped FCC and activated carbon into ceramic-like material avoiding iodine loss. In order to obtain ceramic based on CxNy with fullerene structure we decided to carry out gamma irradiation of iodine doped samples in nitrogen atmosphere (0.7 atm. N2). It was found that iodine doping and irradiation caused principal changes in composition of FCC such as substituting of fullerene C60 and graphite (both formed by benzene-like carbon …