Environmental Monitoring Commons^™

Evaluating The Hazardous Materials (Hazmat) Pharmacy Among Air Force Majcoms Using Waste Reductions And Activity Indicators, W. Edward Iseman Jr.

Theses and Dissertations

The Hazardous Materials (HazMat) Pharmacy has been designed as an environmentally friendly vehicle to handle, store, dispense, track, recycle, and dispose of hazardous materials in the Air Force. This thesis effort proposed a method in which valuable feedback for the pharmacy can be obtained. Because it is still in the early stages of implementation, there has been little feedback on the pharmacy. An activity index that uses a variable most closely associated with the generation of hazardous waste in a MAJCOM is proposed. Using an aircraft maintenance related variable, like maximum take-off weight, the fluctuations in mission over time can …

Surfactant Enhanced Microbial Degradation Of Jp-8 Contaminated Soil, John D. Thomas

Theses and Dissertations

This research effort used an automated respirometer to evaluate the enhancement of JP-8 fuel biodegradation, from surfactant addition. Two nonionic surfactants, Novell 1412-7 and Alfonic 810-4.5 were chosen for addition to contaminated JP-8, microcosms at three levels of treatment. The three levels of treatment included sub-CMC, CMC, and supra-CMC concentrations for each surfactant. The Novell II, nonionic surfactant, exhibited inhibitory characteristics, and was eliminated from the study. The focus of the study was to determine if JP-8 was actually degraded, and if enhancement of JP-8 biodegradation would be achieved from surfactant addition. The respirometer was found to be repeatable within …

Laser-Induced Breakdown Spectroscopy On Solution Samples Using Surface Excitation, Leonard M. Berman

Theses and Dissertations

Laser-induced breakdown spectroscopy (LIBS) is a spectroscopic technique where output from a pulsed laser is focused onto a target in order to create an intense plasma. The optical emission is characteristic of the elements in the focal volume and can be used for elemental analysis. Research on the detection of nickel in solution in addition to solvent detection of CCl₄, CHCl₃, C2Cl₄, and C2HCl₃ has been performed. Breakdown was formed at the sample surface via a Q-switched Nd:YAG laser. Initially, operation of the laser was at 1064 nm/repetition rate of 5 Hz. Experiments …

Local Effects Of Solid Rocket Motor Exhaust On Stratospheric Ozone Concentrations, Brian K. George

Theses and Dissertations

Solid Rocket Motors (SRMs) power the initial flight of the Space Shuttle and Titan IV rocket. During those first two minutes after liftoff, the exhaust plumes from these motors emit large quantities of chlorine compounds and alumina particles into the atmosphere. For years scientists have argued that such a large chlorine input, injected directly into the stratosphere, would photochemically react with the surrounding air to cause significant ozone depletion. To answer the question of whether SRM exhaust causes a significant ozone depletion, Version 7 data from the Total Ozone Mapping Spectrometer (TOMS) instrument was analyzed for the 30 days prior …

Mass Transport Of Volatile Organic Compounds Between The Saturated And Vadose Zones, Monte S. Harner

Theses and Dissertations

Volatile organic compounds (VOCs) dissolved in the saturated zone are transported into the vadose zone primarily by gaseous phase diffusion. If the saturated zone is remediated, VOCs present in the vadose zone may become a secondary source of contamination for the groundwater. The amount of VOCs that remain in the vadose zone is dependent on site hydrology, soil properties, and the chemical properties of the contaminants. The purpose of this study was to determine what conditions caused VOC concentrations in the vadose zone to significantly recontaminate the saturated zone. A one-dimensional numerical model was developed to investigate the transport of …

The Biodegradation Characteristics Of Proposed Fuel Systems Icing Inhibitors (Fsii), Charles E. Meshako

Theses and Dissertations

The biodegradation characteristics of three fuel system icing ihhibitors (FSII) were evaluated. FSII are jet fuel additives that partition into water readily and are present in the water drained from storage tank bottoms in concentrations approaching 40%. These concentrations raise concerns as to the disposal and handling of these wastes. The current FSII, DiEGME was evaluated along with two new candidates, dipropylene glycol and glycerol formal. DiEGME appeared to be moderately but not completely biodegradable. It is likely that much of it would be removed in a wastewater treatment plant. Dipropylene glycol only showed signs of degradation after more than …

An Exploration Of Environmental Technology Transition From The Laboratory To The Field, Michael A. Greiner

Theses and Dissertations

Environmental policy, social factors, individual behavior, and environmental technologies are key factors in improving the current condition of the environment. The Department of Defense (DoD) is not immune to these aspects, as its actions have and will continue to impact the environment in which they conduct operations. The objective of this research is to analyze the environmental technology aspect of improving environmental conditions. Of particular interest, what barriers and bridges are encountered when an Air Force laboratory transitions environmental technologies to an end-user: operational field organization or major weapon system. The research employs a case study methodology to analyze five …

The Cumulative Impacts Of Management Decisions On Nitrogen Loading To The Rhode Island Salt Ponds, Laura M. Ernst

Theses and Major Papers

Calculations and measurements of nitrogen in groundwater, stream flow and atmospheric deposition were used to see if the cumulative impacts of management decisions over a fifteen year period of time resulted in measurable changes in nitrogen loading to six of the salt ponds on the south shore of Rhode Island. The changes in the source and transmission of nitrogen were tested by comparing calculated and measured nitrogen data from 1980 and 1995. The calculated method included a nitrogen budget based on land-use and literature values for nitrogen loss to groundwater. The second method compared concentrations of nitrogen in groundwater taken …

Introduced Cyprinid (Carp) Fishes In Western Australia And Their Management Implications, K. R. Breheny

Theses : Honours

Australia has no native cyprinid species and five introduced species have established self-sustaining populations. This study examines the cyprinid species present in Western Australia and estimates their distribution. The potential for introduced cyprinids to cause environmental impacts is explained and ameliorative action recommended. The presence and distribution of cyprinid species is assessed by examination of museum records, published literature, reported collections, anecdotal evidence and sampling of wetland habitats. Two species, Carassius nuratus (Goldfish) and Cyprinus carpio (Koi carp) are believed to have established populations and a map of estimated distribution is compiled. The capacity for introduced carp to undergo sudden …

Captive Environmental Influences On Behavior In Zoo Drills And Mandrills (Mandrillus), A Threatened Genus Of Primate, Erik Terdal

Dissertations and Theses

Drills (Mandrillus leucophaeus) are an endangered species of African monkey (Cercopithecidae), and their sole congener the mandrill (Mandrillus sphinx) is vulnerable to extinction. Both species are threatened in the wild by deforestation and hunting.

Drills have a poor record of captive reproduction. Many individuals appear to have behavioral deficiencies which interfere with reproduction. Thus, the zoo population of drills does not serve as a “hedge” against the species’ total extinction: drills are endangered in captivity as well as in the wild. Mandrills, by contrast, reproduce well in captivity. Information on the behavior of mandrills in captivity may help zoo managers …

A Functional Group Approach To Detecting Shifts In Macroalgal Communities Along A Disturbance Gradient, J. C. Phillips

Theses : Honours

A recently proposed hypothesis argued that morphologically and functionally similar macroalgae could be grouped to study the structure of macroalgal communities. It was argued that these functional groups can be used to predict changes to community composition that result from disturbance. This study examined whether the functional group model held in detecting changes in macroalgal community structure within one bioregion, by applying it to a habitat exposed to different levels of physical disturbance associated with wave exposure. Results obtained using a functional group approach were compared to those obtained using a species level approach. Three parallel reef lines in Marmion …

Fuel Characteristics Of Rehabilitated Bauxite Mines In Western Australia, Sarah J. Collins

Theses : Honours

This investigation assessed the fuel characteristics of Alcoa of Australia's rehabilitated bauxite mines in the south-west of Western Australia. The study determined the fuel loads, their composition and structure. The characteristics of fuel were determined, their relationship with time ascertained, and the similarity of these characteristics to the jarrah forest ecosystems that they have replaced was discussed. Pits aged from four to twenty years since rehabilitation were assessed. Predictive models were developed to allow the rapid assessment of fuel. The fuel characteristics in two controlled bum areas were also assessed to how much fuel would burn in a fire and …

An Investigation Into The Use Of The Freshwater Crayfish Marron (Cherax Tenuimanus) As A Flagship For The Restoration Of The Blackwood River, Rachael Nickoll

Theses : Honours

The Marron (Cherax tenuimanus) is arguably the most easily identified and ecologically important aquatic animal species in south-western Australian rivers. In fact it is quintessientially south-western Australian, endemic to the south-west corner of the continent and supporting a recreational fishery and commercial aquaculture industry within the state. Marron have keystone qualities as hosts of various epiphytic flora and fauna, and are central to the food web within south-west rivers. Their sensitivity to depleted oxygen conditions have also made them a potential "indicator" for water quality degradation. The study investigated these qualities in reference to the marron's potential as …