Environmental Monitoring Commons^™

Multidimensional Investigation Of Tennessee’S Urban Forest, Jillian L. Gorrell

Doctoral Dissertations

Preserving existing trees in urban areas and properly cultivating urban forest conservation and management opportunities is valuable to the ever-growing urban environment and necessary for creating optimal experiences and educational tools to meet the needs of increasing urban populations. This dissertation contains studies investigating several facets of the urban forest, including environmental effects of deforestation and urbanization, tree equity, and urban forest facility management and accessibility. Community education and outreach at arboreta about the importance of the tree canopy can help promote environmental stewardship. A digital questionnaire was electronically distributed to representatives of arboreta certified through the Tennessee Division of …

Microplastic Accumulation In Terrestrial Gastropods And Soils, Gregory B. Bonilla

Masters Theses

Microplastics (MPs) have become an emerging threat to ecosystems across the world. Transport, impacts, and fates are grossly understudied, especially in terrestrial environments. Current research on MP bioaccumulation has focused mainly on aquatic organisms with little study of terrestrial organisms, including snails where data are nearly nonexistent. To address this, we collected and examined land snails and their surrounding soil for MP content in shell and tissue. From September 11, 2020, to October 25, 2021, cover boards were placed (n=30) along relatively undisturbed sites in hardwood, forested areas, and tall grasses in a Wildlife Management Area (WMA) in Oak Ridge …

On Interpreting Eddy Covariance In Small Area Agricultural Situations With Contrasting Site Management., Joel Oetting

Doctoral Dissertations

This dissertation examined the carbon sequestration potential of a low C:N soil amendment and its incorporation into the soil over a rolling agricultural field. A segmented planar fit was developed to assess and correct the systematic errors the topography introduces on the carbon dioxide fluxes. The carbon dioxide fluxes were then be partitioned into gross primary productivity and soil respiration to understand the influence of the contrasting management practices, using flux variance partitioning. Concomitant with the partitioning, high resolution temporal and spatial scale remote sensing images were interpolated and standardized to conduct hypothesis testing for treatment effects.

Assessment Of Soil Health Under Native Warm-Season Grasses And Different Grazing Management, Kara Leigh Grosso

Masters Theses

This research uses analysis of soil quality indicators (SQIs) to compare vegetation species and grazing management over the 2021 grazing season. The soil health effect of the native warm-season grasses (NWSG) big bluestem (BB) (Andropogon gerardii) mixed with indian grass (IG) (Sorghastrum nutans) (BBIG), and switchgrass (SG) (Panicum virgatum), inter-seeded with a 12 species biodiversity mix was investigated in a 5 pressure grazing system (no graze (NG), no rest (NR), early, middle, and late rest (ER, MR, LR)). Additionally, there is a need for inexpensive tools for land owners to assess soil quality, and a validation study …

Influence Of Physical Variability Of Highly Weathered Sedimentary Rock On Nitrate In Area 3 Of The Enigma Field Research Site At Y-12, Erin Kelly

Masters Theses

Uranium processing and waste storage in unlined waste ponds leached contaminants into the groundwater at Y-12, Oak Ridge, Tennessee, from the 1950s to 1980s. Groundwater wells near the S-3 ponds have had the highest nitrate concentrations of groundwater anywhere in the world (>10,000 mg/L). For reference, the maximum contaminant level for nitrate in drinking water set by the U.S. Environmental Protection Agency is 10 mg/L. Since 2012, the ENIGMA (Ecosystems and Networks Integrated with Genes and Molecular Assemblies) group has been characterizing, monitoring, and conducting field experiments to understand the interactions between contaminants, microbes, and the subsurface. The goals …

Dissolved Organic Carbon And The Potential Role To Stream Acidity In The Great Smoky Mountains National Park, Jason R. Brown

Masters Theses

A substantial societal shift towards environmental awareness has focused research efforts on the impacts of pollution on natural landscapes. Improvements to pollutant regulations and technology have resulted in sizeable reductions of atmospheric deposition of anthropogenic acids, especially nitrates and sulfates, which has altered the role of these ions in the environment. As such, understandings of environmental chemistry dynamics have required regular updating.

Through the National Park Service Vital Signs monitoring program, increases in precipitation pH observed in Great Smoky Mountains National Park (GRSM) has been attributed to the reduction of inorganic acid concentrations. Unfortunately, these improvements have not been uniformly …

Investigating The Ecology And Behavior Of The Indiana Bat And Tri-Colored Bat During Fall Swarming And Spring Staging, Mallory E. Tate

Masters Theses

White-nose syndrome has devastated bat populations across North America since 2005. Due to declines in Indiana bat (Myotis sodalis) and tri-colored bat (Perimyotis subflavus) populations across the eastern United States, management prescriptions need to consider all seasons of these species annual cycles. However, data is severely lacking on the two seasons surrounding winter hibernation. These include fall swarming, a time period when bats are mating and preparing for hibernation, and spring staging, when bats are emerging from hibernation and preparing for spring migration. Both periods are critical for successful reproduction and survival following white-nose syndrome infection. …

High-Resolution Timeseries Analysis Of Dynamic Geochemistry: A 27-Well Survey Of Contaminated Groundwater Downstream Of The Former S-3 Ponds, Oak Ridge, Tennessee, Emma Dixon

Masters Theses

Spatiotemporal variability of geochemistry of contaminated groundwater has large implications on overall water quality and ability to respond to remedial applications. Gaining knowledge of how geochemistry changes over time in an area can help establish response trends to changing external conditions like weather and level of contamination. In this study, a spatiotemporal survey was performed on 27 wells at the Y-12 Complex in Oak Ridge, Tennessee. This was completed to measure diurnal fluxes in geochemistry from seasonal changes and extreme weather conditions in three areas of historically different contamination levels from a single point contamination source. Measurements were gathered over …

Effects Of Switchgrass Related Land-Use Changes On Aquatic Macroinvertebrates, Latha Malar Baskaran

Doctoral Dissertations

This research examines if switchgrass-based land-management practices have the potential to influence aquatic macroinvertebrates through changes in stream flow and water quality. The number of taxa in Ephemeroptera, Plecoptera, and Trichoptera orders (EPT taxa richness/EPT-TR) is analyzed as an aquatic macroinvertebrate bioindicator in the context of regional environmental effects, and changes in stream flow and water quality. This dissertation is structured as three manuscripts that link together to address the overall research question.

The first manuscript focuses on identifying regional environmental variables that influence EPT-TR across ecoregions in Tennessee. The influences of temperature, precipitation, geology, soil, stream flow and velocity …

Modelling Cash Crop Growth In Tn, Spencer Weston

Chancellor’s Honors Program Projects

No abstract provided.

Characterizing Groundwater Ch4 And 222rn In Relation To Hydraulic Fracturing And Other Environmental Processes In Letcher County, Ky, St. Thomas Majeau Ledoux

Masters Theses

Hydraulic fracturing of shale deposits has greatly increased the productivity of the natural gas industry by allowing it to exploit previously inaccessible reservoirs. However, previous research has demonstrated that this practice can contaminate shallow aquifers with CH₄ [methane] from deeper formations. This study compares concentrations and isotope compositions of CH₄ sampled from domestic groundwater wells in Letcher County, Kentucky in order to characterize its occurrence and origins in relation to neighboring hydraulically fractured natural gas wells. Additionally, this study tests the reliability of ²²²Rn [radon] as an alternative tracer to CH₄ in identifying processes of gas …

Estimating Streambank Erosion Using Gps-Based Watershed-Scale Video Mapping And Usepa Bancs For The Development Of Sediment Tmdls, Kelsey Jo Hensley

Masters Theses

According to the United States Environmental Protection Agency (USEPA), sediment is one of the most common water pollutants in the nation’s rivers. Consequently, the identification of streambank locations with high erosion potential is important in reducing sediment input via management and monitoring practices. Furthermore, the estimation of erosion rates and sediment loads can assist in the development of Total Maximum Daily Loads (TMDLs). The objective of this study was to integrate two USEPA-recommended approaches with the Streambank Video Mapping System (SVMS) in order to predict site-specific Total Daily Sediment Loads (TDSLs) and calculate sediment TMDLs for streambank erosion over several …

Measuring Carbon Dioxide (Co2) Flux Of Agricultural Practices In Sub-Saharan Africa, Debra Blumberg O'Dell

Masters Theses

Agriculture has an important role in addressing two of the world’s most pressing problems: meeting global food demand and mitigating climate change. If agriculture is not practiced sustainably it will fail to meet future food demand and likely intensify the pace of global climate change. There are some agricultural practices, such as Conservation Agriculture, that can produce food sustainably and have the potential to mitigate climate change. However it is not clear which agricultural practices contribute to climate mitigation and by how much. By measuring the carbon dioxide (CO2) emissions of specific agricultural practices, the ability of practices to sequester …

Spatial Co-Variation Between Distance From Mining Activity And Water Chemistry On East Tennessee's Northern Cumberland Plateau, Bryan Benjamin Bozeman

Chancellor’s Honors Program Projects

No abstract provided.

Freshwater Mussels (Bivalvia: Margaritiferidae And Unionidae) Of The Buffalo River Drainage, Tennessee, Matthew Philip Reed

Masters Theses

The Buffalo River in Tennessee once hosted a rich population of freshwater mussels. During the 1980s, monitoring efforts demonstrated evidence of drastic declines and extirpation of entire assemblages. Increases in municipal development in the headwater tributaries and agriculture in the main stem of the Buffalo River are suspected causes for mussel community declines throughout the river. In 2011, collection data documented evidence of recovery in the lower Buffalo River. The aims of this project were: 1) to update the status, distribution, and species composition of mussels in the Buffalo River and its major tributaries through qualitative sampling, and 2) to …

Kingston Fossil Plant Ash Spill & Corbicula Fluminea: Assessing The Effectiveness Of An Invasive Bivalve As A Biomonitor Of Coal Ash Pollution, Hannah Ruth Johnson

Masters Theses

The goal of this study was to assess the effectiveness of using the invasive Asian clam, Corbicula fluminea, as a biomonitor for trace element bioavailability in the river system affected by the Kingston Fossil Plant coal ash spill of December 2008. I collected Corbicula from five different sites (n=20 per site) and analyzed both the soft body tissues and shells via inductively coupled plasma-optical emission spectroscopy (ICP-OES). I then compared the concentrations of a suite of elements in Corbicula fluminea among sampling sites and examined the correlation between soft tissue and shell concentrations. The multiple analysis of variance (MANOVA) …

Linking Stream Sediment Metrics And Aquatic Macroinvertebrate Status In East Tennessee Streams, Grant Thomas Lynch

Masters Theses

Excess sediment is one of the leading causes of impairment of the rivers and streams of Tennessee and in the United States. Sediment acts as a pollutant by degrading the quality of habitat for fish and other aquatic life. The Tennessee Department of Environment and Conservation (TDEC) currently assesses the quality of streams in Tennessee by conducting benthic macroinvertebrate surveys. These surveys use seven biometrics to calculate Tennessee Macroinvertebrate Index (TMI) scores. This method is well tested and reliable, but it has not been shown to directly link changes in stream sediment characteristics to macroinvertebrate status. Finding a stream sediment …

Adsorption Of Antimony By Birnessite And The Impact Of Antimony On The Electrostatic Surface Properties Of Variable-Charge Soil Minerals, Kalyn Alaine Vergeer

Masters Theses

Antimony (Sb) is a toxin that can be found in high concentrations in the soil due to anthropogenic sources. Antimony exists in soil as Sb(V) in the monovalent antimonate hydroxyanion. The adsorption mechanisms of Sb(V) are not well-characterized. The objective of this study was to further elucidate Sb(V) adsorption mechanisms by examining the impact of adsorption on surface charging characteristics of gibbsite, goethite, birnessite, and kaolinite. Also examined was Sb(V), SO₄ [sulfate], and PO₄ [phosphate] adsorption by birnessite. Electrophoretic mobility and potentiometric titrations were employed to examine the ζ-potential [zeta-potential] and net proton surface charge density as a …

Mussel Survivorship, Growth Rate And Shell Decay Rate In The New River Basin Of Tennessee: An Experimental Approach Using Corbicula Fluminea, Grant Andrew Mincy

Masters Theses

The New River Basin (NRB) of Tennessee is home to a number of rare endemic aquatic communities. One such community of particular importance to the area, experiencing a precipitous population decline due to the fouling and pollution of their freshwater systems, is that of freshwater mussels (Bogan 2006). This study in the NRB involves measuring the mortality rates of live Asian clams (Corbicula fluminea) assemblages and the shell decay rates of their death assemblages. This study also examines the decay rates of the native Villosa iris to gather information on molluscan health and the ability of their shells …

A Novel Approach To Assess Environmental Changes In Marine Ecosystems Via Spectroscopic Analyses Of Microalgae, Rebecca Burke Horton

Doctoral Dissertations

Chemical analyses for environmental monitoring encounter many challenges which are imposed by a multitude of chemically complex and interrelated processes. For such investigations, innovative analytical methodologies must be developed which characterize chemical shifts of key environmental parameters in order to deduce insights into their ecological relevance. This dissertation is driven by an analytical chemistry perspective to develop chemical sensing techniques with the ultimate goal of gaining a deeper understanding of environmental changes and their chemical origins.

In order to overcome limitations inherent to any chemical sensor designed for a specific task, new paths are pursued which are based on the …

Capture-Recapture Of White-Tailed Deer Using Dna Sampling From Fecal Pellet-Groups, Matthew James Goode

Masters Theses

Reliable density estimates of game and keystone species such as white-tailed deer (Odocoileus virginianus) are desirable to set proper management strategies and for evaluating those strategies over time. However, traditional methods for estimating white-tailed deer density have been inhibited by behavior, densely forested areas that can hamper observation (detection), and invalid techniques of estimating effective trapping area. We wanted to evaluate a noninvasive method of mark-recapture estimation using DNA extracted from fecal pellets as the individual marker and for gender determination, coupled with a spatial detection function to estimate density (Spatially Explicit Capture-Recapture, SECR). We collected pellet groups …

Evaluating Substrate Metrics For Monitoring Sediment Impairment Of East Tennessee Streams., James Hunter Terrell

Masters Theses

Section 303(d) of the Clean Water Act (CWA) requires states to assess and list all streams that do not meet water quality criteria for their designated use classes. In Tennessee, the Tennessee Department of Environment and Conservation (TDEC) uses macroinvertebrate surveys to assess the condition of streams designated for “fish and aquatic life” and the progress of targeted waterbodies toward meeting established standards for sediment. As of yet, no substrate metric has been established to monitor water quality or to document progress toward water quality improvement with respect to fish and aquatic life in Tennessee. A substrate metric that could …

Wind Regimes In Complex Terrain Of The Great Valley Of Eastern Tennessee, Kevin Ray Birdwell

Doctoral Dissertations

This research was designed to provide an understanding of physical wind mechanisms within the complex terrain of the Great Valley of Eastern Tennessee to assess the impacts of regional air flow with regard to synoptic and mesoscale weather changes, wind direction shifts, and air quality. Meteorological data from 2008–2009 were analyzed from 13 meteorological sites along with associated upper level data. Up to 15 ancillary sites were used for reference. Two-step complete linkage and K-means cluster analyses, synoptic weather studies, and ambient meteorological comparisons were performed to generate hourly wind classifications. These wind regimes revealed seasonal variations of underlying physical …

Phosphorus Distribution In Channel-Bed Sediments In Beaver Creek, Knox County, Tennessee, Angela Nicole Danovi

Masters Theses

Beaver Creek, located in North Knox County, Tennessee, is on the Tennessee 303(d) list as an impaired stream that fails to meet its designated uses. Phosphorus (P) is one of the major pollutants of the stream. High P levels within surface water can lead to water quality problems including low dissolved oxygen, overgrowth of algae, and eutrophication. Two sources, pasture grazing areas and major municipal point sources, have been identified as important contributors of P to Beaver Creek. The objective of this study was to analyze the total P and Mehlich III extractable P concentrations of sediments in Beaver Creek …

The Effects Of Land-Use Change On The Hydrological Properties Of Andisols In The Ecuadorian Paramo, James Joseph Hartsig

Masters Theses

The Ecuadorian páramo is characterized by unique soil properties that allow the ground to hold large amounts of water. These páramo grasslands support Andean cities and communities as a source of water for municipal, industrial, and agricultural use. Although recent research has suggested that changes in land use can decrease the amount of water and affect the water-holding capabilities of the soil, the hydrologic effects of different land uses, including burning for livestock grazing and pine planting for carbon credits, are currently under debate.

This research tested hypotheses about moisture-related properties of páramo soils under different land uses at two …

Effects Of 2000-2050 Global Climate Change On Ozone And Particulate Matter Air Quality In The United States Using Models-3/Cmaq System, Yun-Fat Lam

Doctoral Dissertations

The Models-3/Community Multi-scale Air Quality modeling system (CMAQ), coupled with Goddard Institute for Space Studies (GISS) atmospheric General Circulation Model (GCM), fifth Generation Mesoscale Model system (MM5), and Goddard Earth Observing System-CHEMistry (GEOS-Chem), was used to simulate atmospheric concentration of ozone and particulate matter over the continental United States 12-km and 36-km (CONUS) domains at year 2000 and year 2050. In the study, GISS GCM model outputs interfaced with MM5 were utilized to supply the current and future meteorological conditions for CMAQ. The conventional CMAQ profile initial and boundary conditions were replaced by time-varied and layer-varied GEOS-Chem outputs. The future …

The Effects Of Changes In Water Content On Uranium(Vi) Leaching In Sediment Mixtures Containing Gravel, Andrew Weber Moore

Masters Theses

This study is aimed at understanding the physical and chemical effects that changes in water content have on uranium leaching in sediment containing gravel. It was hypothesized that leaching will be more efficient under unsaturated conditions because flow will be restricted to the smallest pores and will have the most contact with the uranium contaminated sediment. Under saturated conditions, a large portion of the flow will bypass the < 2 mm material, and in turn not come into contact with uranium contaminated material. Batch adsorption and desorption experiments were performed on < 2 mm ERDF sediment to determine the linearity and reversibility of sorption processes and to aid in the interpretation of the leaching experiments. Results of the desorption experiments on aged, contaminated sediments show that the mass percent of sorbed U(VI) released to solution decreased as the sorbed concentration of U(VI) decreased. The opposite trend was observed on freshly contaminated sediments. This indicated that aging increased U(VI) affinity for the solid phase and was attributed to either the crystallization of calcite, which incorporated a portion of the sorbed U(VI) as it crystallized, or the presence of voids in basaltic lithic fragments accessed by diffusion. Column leaching experiments were performed at two water contents on artificially contaminated sediment collected from the Department of Energy’s (DOE) Hanford Site, Washington state. The sediment contained 81.3% gravel (> 2 mm) by mass. Non-reactive tracers were well fit with the convection-dispersion equation (CDE) at both high and low water contents indicating physical equilibrium. The column experimental data were fitted to an …

Aquatic Habitat Mapping Within The Obed Wild And Scenic River For Threatened And Endangered Species Habitat Delineation, Joseph Ross Candlish

Masters Theses

There is a need to define a more efficient and accurate approach to aquatic habitat mapping. Traditional approaches have focused on intense biological/non-biological sampling and observation analysis within specific and restrained scales. Therefore, an underwater video mapping system (UVMS) has been developed in efforts to identify federally protected aquatic species’ habitats within the Obed Wild and Scenic River (OBRI). The UVMS kayak apparatus provides georeferenced video footage correlated with GPS (global positioning systems) for GIS (geographic information systems) mapping applications. Based on its fluvial and geomorphological trends, OBRI was dissected quantitatively and integrated into databases for species-specific GIS habitat queries. …

Ecological Indicator Development, Integration And Knowledge Mapping, Aaron Dean Peacock

Doctoral Dissertations

The overall goals of this project were: (1) to develop a microbiological ecological indicator that would describe military land disturbance, (2) integrate previously collected ecological indicator data from five separate research teams, and (3) produce knowledge maps with the resulting information that illustrates how the selected indicators are involved in ecosystem processes. To address goal one, soil samples were obtained from four levels of military traffic (reference, light, moderate, and heavy) with an additional set of samples taken from previously damaged areas. Using the soil microbial biomass and community composition as ecological indicators, reproducible changes showed increasing traffic disturbance decreases …

Seasonal Variations In Fish Assemblages Of Small Warmwater Streams In Four Southeastern National Parks, Joseph Carl Zimmerman

Masters Theses

Small warm-water streams in the southeastern United States experience significant differences in temperature, as well as changes in physical parameters due to seasonal fluctuations. It has been generally thought that fish assemblage patterns change as a direct result of these seasonal variations. This study was designed to determine the effects of variable flow regimes on fish species composition, diversity, and abundance. Eight small warm-water streams in four national parks (Chickamauga and Chattanooga National Military Park, Fort Donelson National Battlefield, Abraham Lincoln Birthplace National Historic Site, and Russell Cave National Monument) were sampled May-June 2005 for the summer trials, October-November 2005 …