Open Access. Powered by Scholars. Published by Universities.®

Environmental Monitoring Commons

Open Access. Powered by Scholars. Published by Universities.®

Articles 1 - 3 of 3

Full-Text Articles in Environmental Monitoring

Intercomparison Of Local Hydroxyl Measurements By Radiocarbon And Fage Techniques, Malcolm J. Campbell, Brad D. Hall, John C. Sheppard, Philip L. Utley, Robert J. O'Brien, Thomas M. Hard, Linda Acha George Oct 1995

Intercomparison Of Local Hydroxyl Measurements By Radiocarbon And Fage Techniques, Malcolm J. Campbell, Brad D. Hall, John C. Sheppard, Philip L. Utley, Robert J. O'Brien, Thomas M. Hard, Linda Acha George

Environmental Science and Management Faculty Publications and Presentations

A direct intercomparison of near-surface tropospheric HO concentration measurements by two different techniques was made in October–November 1992 at a rural site near Pullman, Washington. The atmosphere at the site is believed to contain low levels of anthropogenic pollution. The instruments' inlets were located at the same height (3.5 m) above the ground and were separated by 10 m along a line normal to the prevailing wind. Readings of the FAGE3 and radiocarbon instruments showed a high correlation (r² = 0.74) despite HO concentrations that were frequently near the detection limit of the instruments. An unweighted least squares regression shows …


Fage Determination Of Tropospheric Ho And Ho₂, Linda Acha George, Thomas M. Hard, Robert J. O'Brien Apr 1995

Fage Determination Of Tropospheric Ho And Ho₂, Linda Acha George, Thomas M. Hard, Robert J. O'Brien

Environmental Science and Management Faculty Publications and Presentations

FAGE (fluorescence assay with gas expansion) was developed as a sensitive technique for the detection of low-concentration free radicals in the atmosphere. The application of FAGE to tropospheric hydroxyl (H0) and hydroperoxyl (H0₂) radicals has yielded calibrated measurements of both species in both clean air and highly polluted urban air. For HO calibration, a continuously stirred tank reactor provides a uniform external HO concentration, which can be measured by gas chromatography of an HO-reactive hydrocarbon. The aerodynamics of the air-sampling process has been modeled computationally, with results that agree with empirical observations of the effects of nozzle diameter on HO …


Some Relationships Between Sedimentary Trace Metal Concentrations And Freshwater Phytoplankton And Sedimentary Diatom Species Composition, Allan Hayes Vogel Jan 1995

Some Relationships Between Sedimentary Trace Metal Concentrations And Freshwater Phytoplankton And Sedimentary Diatom Species Composition, Allan Hayes Vogel

Dissertations and Theses

Sediments from 21 Oregon lakes were analyzed for seven metals (Fe, Mn, Zn, Cu, Co, Ni, V) in three forms (exchangeable, organic+sulfides, and oxyhydroxides+ oxides+ carbonates) using a sequential fractionation procedure. The summer epilimnetic filterable concentration of an eighth (Mo) was also determined. Sedimentary diatom remains and summer phytoplankton populations of the lakes were correlated with the 22 metal parameters and with conservative water chemistry parameters, estimators of lake productivity, and watershed geology. Both the sedimentary metals and the two populations of primary producers correlated best with the ecoregions of Omernik and Gallant (1986). A number of species possessed correlations …