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Full-Text Articles in Speleology

Reverse Pseudo-Gours: A New Sub-Type Of Folia Observed In The Nerja Cave (Se Spain), Cristina Liñán Baena, Concepción Jiménez De Cisneros, Yolanda Del Rosal, Paolo Forti Dec 2023

Reverse Pseudo-Gours: A New Sub-Type Of Folia Observed In The Nerja Cave (Se Spain), Cristina Liñán Baena, Concepción Jiménez De Cisneros, Yolanda Del Rosal, Paolo Forti

International Journal of Speleology

A new sub-type of folia named “reverse pseudo-gour” has been observed and described in the Nerja Cave, southern Spain. It consists of fairly vertical, thin barriers (about 5 mm high and 2 mm thick) that develop on the underside of a sub-horizontal surface (shelfstone) and grow in the opposite direction to normal gours (rimstone dams), generating sinuous shapes. Their mineral composition is essentially calcium carbonate, although globular aggregates composed of clay and phosphate minerals have also been identified. The genesis and evolution of these reverse pseudo-gours occur just at the air-water interface and are controlled by (1) the sub-horizontality of …


Cryogenic Ridges: A New Speleothem Type, Bogdan P. Onac, Daniel M. Cleary, Oana A. Dumitru, Victor J. Polyak, Ioan Povara, Jonathan G. Wynn, Yemane Asmerom Jan 2023

Cryogenic Ridges: A New Speleothem Type, Bogdan P. Onac, Daniel M. Cleary, Oana A. Dumitru, Victor J. Polyak, Ioan Povara, Jonathan G. Wynn, Yemane Asmerom

International Journal of Speleology

Cryogenic cave carbonates have been described from several formerly or presently glaciated karst caves. In most of these occurrences, they precipitated as loose grains or aggregates with various morphologies and sizes. Here, we report on a new speleothem type (cryogenic ridges) identified in Sohodoalele Mici Cave (SW Romania) within a large chamber near the entrance shaft. This study was motivated by the presence of a network of calcite ridges over the stalactites’ surface and by the observation that during winter, these speleothems are covered by a thin ice layer. The higher δ18O (−3.5 to –1‰) and …


Low Impact Sampling Of Speleothems – Reconciling Scientific Study With Cave Conservation, Claire L.V. Macgregor, John C. Hellstrom, Jon D. Woodhead, Russell N. Drysdale, Rolan S. Eberhard Nov 2021

Low Impact Sampling Of Speleothems – Reconciling Scientific Study With Cave Conservation, Claire L.V. Macgregor, John C. Hellstrom, Jon D. Woodhead, Russell N. Drysdale, Rolan S. Eberhard

International Journal of Speleology

Speleothems are increasingly valued as important paleoclimate archives and yet the removal of samples from caves can come at a cost to natural heritage, impacting delicate environments with limited mechanisms for repair. Conservation of cave environments is a key responsibility for scientists and, with this in mind, we are working to develop and implement techniques that allow us to extract valuable scientific data, with minimal impact. In this study, we demonstrate the utility of low-impact reconnaissance dating surveys on caves in southern Tasmania and southwest Western Australia as a precursor to the removal of stalagmites for paleoclimate reconstruction. Small flakes …


Continuous Color Model As A Tool To Improve Speleothem Age Model Development, Celia Campa-Bousoño, Ángel García-Pérez, Ana Moreno, Miguel Iglesias, Hai Cheng, R Lawrence Edwards, Heather Stoll Oct 2021

Continuous Color Model As A Tool To Improve Speleothem Age Model Development, Celia Campa-Bousoño, Ángel García-Pérez, Ana Moreno, Miguel Iglesias, Hai Cheng, R Lawrence Edwards, Heather Stoll

International Journal of Speleology

Because they can archive a variety of geochemical proxies and be precisely and accurately dated with the U-Th decay series chronometer, stalagmites are widely used for paleoclimate reconstructions. However, limitations in the use of this chronometer arise because U-Th dating is analytically time consuming, expensive, and requires a relatively large sample size. These limitations restrict the number of absolute dates usually obtained, which can result in significant uncertainties in the age model and inhibit the ability to archive high resolution records of environmental variability, particularly in those stalagmites where there are variations in growth rate not constrained by U-Th dates. …


The Impact Of Burning On The Structure And Mineral Composition Of Bat Guano, Joyce Lundberg, Donald A. Mcfarlane May 2021

The Impact Of Burning On The Structure And Mineral Composition Of Bat Guano, Joyce Lundberg, Donald A. Mcfarlane

International Journal of Speleology

Here we addressed the question of whether burning of guano produces a characteristic suite of morphological changes and/or unique mineralogical products. The changes observed in our experimental burning of guano (both fresh and decayed) included colour change (blackening), grain size and morphological change (grain size generally reduced, morphology rendered generally less distinct), alteration of minerals by dehydration (e.g., gypsum to anhydrite, brushite to whitlockite), and production of new minerals or compounds (e.g., augelite, bayerite, giniite, graphite, oldhamite, strontium apatite, tridymite). The key morphological feature we found that may be diagnostic of burning was severe damage to crystals from rapid dehydration …


On The Genesis Of Aluminum-Rich Speleothems In A Granite Cave Of Nw Spain, Jorge Sanjurjo-Sanchez, Carlos Arce Chamorro, Juan Ramón Vidal Romaní, Marcos Vaqueiro-Rodríguez, Victor Barrientos, Joeri Kaal Feb 2021

On The Genesis Of Aluminum-Rich Speleothems In A Granite Cave Of Nw Spain, Jorge Sanjurjo-Sanchez, Carlos Arce Chamorro, Juan Ramón Vidal Romaní, Marcos Vaqueiro-Rodríguez, Victor Barrientos, Joeri Kaal

International Journal of Speleology

Granite massifs often contain caves, with dimensions ranging from a few meters up to 1,000 m, also referred to as pseudokarst. The speleothems in such caves are mostly composed of either Si-rich (commonly opal-A) or Al-rich authigenic mineraloids. Whereas the formation and geochemical composition of opal-A biospeleothems have been studied and are fairly well understood, knowledge on the Al-rich analogues is scarce. This work reports for the first time a study on the composition, accretion process, age and growth rate of an Al-rich speleothem type flowstone from the A Trapa Cave System (Galicia, NW Spain), developed in a granite cave. …


Active Growth Of Non-Hydrothermal Subaqueous And Subaerial Barite (Baso4) Speleothems In Lechuguilla Cave (New Mexico, Usa), Max Wisshak, Hazel A. Barton, Katey E. Bender, Harvey R. Duchene Jan 2020

Active Growth Of Non-Hydrothermal Subaqueous And Subaerial Barite (Baso4) Speleothems In Lechuguilla Cave (New Mexico, Usa), Max Wisshak, Hazel A. Barton, Katey E. Bender, Harvey R. Duchene

International Journal of Speleology

Barite (BaSO4) speleothems have been reported from caves around the globe and interpreted to have chiefly formed in phreatic, hypogene, hydrothermal settings. Here we report two contrasting types of barite speleothems (bluish tabular crystals in a shallow pool and actively dripping greenish stalactites), which today form at lower temperatures in the non-hydrothermal and vadose environment of Lechuguilla Cave, New Mexico, USA. Scanning electron microscopy analysis, along with energy- and wavelength-dispersive X-ray spectroscopy (EDS, WDS), as well as X-ray diffraction (XRD), characterize the habit and chemical composition as barite. Fractionation of the minor element calcium is related to growth …


Genesis Of Iron And Manganese Sediments In Zoloushka Cave (Ukraine/Moldova) As Revealed By Δ13C Organic Carbon, Piotr Kotula, Viacheslav Andreychouk, Jacek Pawlyta, Leszek Marynowski, Izabela Jendrzejewska Sep 2019

Genesis Of Iron And Manganese Sediments In Zoloushka Cave (Ukraine/Moldova) As Revealed By Δ13C Organic Carbon, Piotr Kotula, Viacheslav Andreychouk, Jacek Pawlyta, Leszek Marynowski, Izabela Jendrzejewska

International Journal of Speleology

Zoloushka Cave is one of the largest maze gypsum caves in the world. Mining of the gypsum bedrock and lowering of the water level due to the pumping of groundwater led to exposure of the cave passages to vadose conditions and changed the hydrochemistry of the karst water. As a result, large quantities of Fe and Mn hydroxides were deposited in the passages. It was found that at least two groups of various organisms were involved in depositing ferrous and manganese sediments. In order to establish the mechanism of deposition, we conducted chemical analyses of the sediments and isotopic analyses …


Morphological And Mineralogical Evidence For Ancient Bat Presence In Cova Des Pas De Vallgornera (Llucmajor, Mallorca, Western Mediterranean), Antoni Merino, Joan J. Fornós, Antoni Mulet, Joaquín Ginés May 2019

Morphological And Mineralogical Evidence For Ancient Bat Presence In Cova Des Pas De Vallgornera (Llucmajor, Mallorca, Western Mediterranean), Antoni Merino, Joan J. Fornós, Antoni Mulet, Joaquín Ginés

International Journal of Speleology

Cova des Pas de Vallgornera is a unique karst cave located at the Llucmajor coastal platform that stands out not only because of its length, more than 78 km, but also for its particular morphological suite, richness and variety of speleothems and mineral infillings. Although the mineralogy of speleothems and minerals related to hypogene morphologies has been studied and described, the existence of minerals derived from guano deposits was still poorly investigated. The cave hosted bat colonies until the collapse of its natural entrances, circa 2.4 My ago, since then until its discovery in 1968, the cave remained sealed. These …


Cave Dripwater Isotopic Signals Related To The Altitudinal Gradient Of Mount-Lebanon: Implication For Speleothem Studies, Carole Nehme, Sophie Verheyden, Fadi H. Nader, Jocelyne Adjizian-Gerard, Dominique Genty, Kevin De Bont, Benedicte Minster, Ghada Salem, David Verstraten, Philippe Clayes Mar 2019

Cave Dripwater Isotopic Signals Related To The Altitudinal Gradient Of Mount-Lebanon: Implication For Speleothem Studies, Carole Nehme, Sophie Verheyden, Fadi H. Nader, Jocelyne Adjizian-Gerard, Dominique Genty, Kevin De Bont, Benedicte Minster, Ghada Salem, David Verstraten, Philippe Clayes

International Journal of Speleology

An important step in paleoclimate reconstructions based on vadose cave carbonate deposits or speleothems is to evaluate the sensitivity of the cave environment and speleothems to regional climate. Accordingly, we studied four caves, located at different altitudes along the western flank of Mount-Lebanon (Eastern Mediterranean). The objectives of this study are to identify the present-day variability in temperature, pCO2, and water isotopic composition and to assess the possible influence of the altitudinal gradient on cave drip waters and cave streams. We present here an overview of the spatial variability of rainwater based on local and regional data, and …


On Biospeleothems From A Venezuelan Tepui Cave: U-Th Dating, Growth Rates, And Morphology, Joyce Lundberg, Charles Brewer-Carías, Donald A. Mcfarlane Oct 2018

On Biospeleothems From A Venezuelan Tepui Cave: U-Th Dating, Growth Rates, And Morphology, Joyce Lundberg, Charles Brewer-Carías, Donald A. Mcfarlane

International Journal of Speleology

Seven silica biospeleothems from Cueva Charles Brewer, Chimantá Plateau, Venezuela have been successfully U-Th dated despite very low U and high detrital Th concentrations. Growth rates are low, between ~100 to ~800 µm/ka, and are greater closer to water level. Dates in unaltered material are in good stratigraphic order, but secondary silicification may compromise the U-Th system, yielding unreliable sequences of ages. Detritally-enriched layers correlate with global climate cycles of the Late Quaternary, in particular the cooler, drier phases of MIS 5d, 5a, and 4. SEM studies indicate that the peloidal material is made up of silica nano-particles assembled to …


Extremely High Diversity Of Sulfate Minerals In Caves Of The Irazú Volcano (Costa Rica) Related To Crater Lake And Fumarolic Activity, Andrés Ulloa, Fernando Gázquez, Aurelio Sanz-Arranz, Jesús Medina, Fernando Rull, José María Calaforra, Guillermo E. Alvarado, María Martínez, Geoffroy Avard, J. Maarten De Moor, Jo De Waele Jun 2018

Extremely High Diversity Of Sulfate Minerals In Caves Of The Irazú Volcano (Costa Rica) Related To Crater Lake And Fumarolic Activity, Andrés Ulloa, Fernando Gázquez, Aurelio Sanz-Arranz, Jesús Medina, Fernando Rull, José María Calaforra, Guillermo E. Alvarado, María Martínez, Geoffroy Avard, J. Maarten De Moor, Jo De Waele

International Journal of Speleology

The caves of the Irazú volcano (Costa Rica), became accessible after the partial collapse of the NW sector of the Irazú volcano in 1994, offering the opportunity to investigate active minerogenetic processes in volcanic cave environments. We performed a detailed mineralogical and geochemical study of speleothems in the caves Cueva los Minerales and Cueva Los Mucolitos, both located in the northwest foothills of the main crater. Mineralogical analyses included X-ray diffraction (XRD) and Raman spectroscopy, while geochemical characterization used Energy Dispersive X-ray spectroscopy (EDX) coupled to Scanning Electron Microscopy (SEM). In addition, measurements of environmental parameters in the caves, …


Unusual Internal Structure Of Cm-Sized Coldwater Calcite: Weichselian Spars In Former Pools Of The Zinnbergschacht Cave (Franconian Alb/Se Germany), Detlev K. Richter, Rolf D. Neuser, Martin Harder, Hardy Schabdach, Denis Scholz Apr 2018

Unusual Internal Structure Of Cm-Sized Coldwater Calcite: Weichselian Spars In Former Pools Of The Zinnbergschacht Cave (Franconian Alb/Se Germany), Detlev K. Richter, Rolf D. Neuser, Martin Harder, Hardy Schabdach, Denis Scholz

International Journal of Speleology

The investigation of the internal structure of calcite crystals is a new focus in speleothem science, especially in the range of crystallization temperatures close to 0°C. Recently found calcite spars from Zinnbergschacht Cave of the Franconian Alb (SE Germany) are ideal for multi-method investigation. The elongated calcites (up to 6 cm in length) with three to six lateral faces and basal triangular faces at the ends are observed in collapse-zones in the cave. 230Th/U-ages of 38.9 ka suggest formation during the periglacial Weichselian, between the Scandinavian and Alpine Glaciations. The δ18O and δ13C values of …


Phosphate Speleothems In Caves Developed In Iron Ores And Laterites Of The Carajás Mineral Province (Brazil) And A New Occurrence Of Spheniscidite, Alan R.L. Albuquerque, Rômulo S. Angélica, Daniele F. Gonçalves, Simone P.A. Paz Dec 2017

Phosphate Speleothems In Caves Developed In Iron Ores And Laterites Of The Carajás Mineral Province (Brazil) And A New Occurrence Of Spheniscidite, Alan R.L. Albuquerque, Rômulo S. Angélica, Daniele F. Gonçalves, Simone P.A. Paz

International Journal of Speleology

The Carajás Mineral Province has one of the largest concentrations of caves in Brazil, and its iron ore is among the country’s main exports. As a result of iron ore intense extraction, new environmental policies have been implemented. In an attempt to balance economic activity and environmental conservation, an inventory and a relevance-based classification of caves were implemented in 2008 as criteria for environmental licensing of mining ventures. This implementation motivated the present study of phosphate speleothems in Carajás’ caves developed in ferriferous rocks. The objectives of this study are to describe the phosphate minerals and their formation processes based …


Cave Monitoring In The Béke And Baradla Caves (Northeastern Hungary): Implications For The Conditions For The Formation Cave Carbonates, György Czuppon, Attila Demény, Szabolcs Leél-Őssy, Mihály Óvari, Mihály Molnár, József Stieber, Klaudia Kiss, Krisztina Kármán, Gergely Surányi, László Haszpra Nov 2017

Cave Monitoring In The Béke And Baradla Caves (Northeastern Hungary): Implications For The Conditions For The Formation Cave Carbonates, György Czuppon, Attila Demény, Szabolcs Leél-Őssy, Mihály Óvari, Mihály Molnár, József Stieber, Klaudia Kiss, Krisztina Kármán, Gergely Surányi, László Haszpra

International Journal of Speleology

In order to use speleothems in the reconstruction of past climate and environmental changes it is necessary to understand the environmental and hydrological processes that determine the physico-chemical conditions of carbonate precipitation and hence speleothem formation. Therefore, in this study an extended monitoring program was conducted in the Béke and Baradla caves located in the Aggtelek region (Northeastern Hungary). The studied caves are rich in speleothem and flowstone occurrences with great potential for paleoclimatology studies. The monitoring activity included measurements of atmospheric and cave temperatures, CO2 concentration in cave air, as well as chemical and isotopic compositions of water …


Timing Of Speleogenesis Of Las Karmidas Cave (Mexico): First Description Of Pseudokarst Developed In Ignimbrite, María Del Pilar Aliaga-Campuzano, Rafael López-Martínez, Pablo Dávila-Harris, Ramón Espinasa-Pereña, Adriana Espino Del Castillo, J.P. Bernal Apr 2017

Timing Of Speleogenesis Of Las Karmidas Cave (Mexico): First Description Of Pseudokarst Developed In Ignimbrite, María Del Pilar Aliaga-Campuzano, Rafael López-Martínez, Pablo Dávila-Harris, Ramón Espinasa-Pereña, Adriana Espino Del Castillo, J.P. Bernal

International Journal of Speleology

Las Karmidas Cave (Puebla State, Mexico) is an unusual type of pseudokarstic cavity generated by piping and erosive processes within the contact of a diamicton and an overlying Quaternary ignimbrite. Morphological evidence suggests that the cave was developed in two stages: a phreatic stage and a vadose stage. The latter was characterized by the formation of carbonate speleothems. The absolute upper-age limit for the cave (168 +7.1/-7.5 ka) was established by U-Th dating of zircons grains extracted from the overlying ignimbrite, whilst a minimum age for the transition from a phreatic to vadose regime (95.6 ± 2.1 ka) was constrained …


Petrographical And Geochemical Changes In Bosnian Stalagmites And Their Palaeo-Environmental Significance, Veronica Chiarini, Isabelle Couchoud, Russell Drysdale, Petra Bajo, Simone Milanolo, Silvia Frisia, Alan Greig, John Hellstrom, Jo De Waele Jan 2017

Petrographical And Geochemical Changes In Bosnian Stalagmites And Their Palaeo-Environmental Significance, Veronica Chiarini, Isabelle Couchoud, Russell Drysdale, Petra Bajo, Simone Milanolo, Silvia Frisia, Alan Greig, John Hellstrom, Jo De Waele

International Journal of Speleology

Detailed petrographic observations have been coupled with trace element and δ13C - δ18O analyses in order to investigate their dynamics in two Holocene Bosnian speleothems. The potential of this multiproxy approach in providing a means to extract palaeo-environmental information from stalagmites whose stable isotope signals are noisy and without obvious trends has been tested. The studied stalagmites are mostly characterized by columnar microcrystalline fabric. At the sub-millimetre scale of lamination, different microcrystalline columnar sub-types (open and closed) have been detected and classified on the basis of the observed porosity and the crystallite size. The presence of …