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Full-Text Articles in Soil Science

Competitive Sorption And Transport Of Heavy Metals In Soil And Mn Oxide-Coated Sand, Joshua Tyler Padilla Apr 2022

Competitive Sorption And Transport Of Heavy Metals In Soil And Mn Oxide-Coated Sand, Joshua Tyler Padilla

LSU Doctoral Dissertations

This study investigated the competitive sorption of Ni, Pb, and Zn as well as synergistic interactions between Ni and phosphate (P) in soils and Mn oxide-coated sand. During stirred-flow experiments, the sorption of heavy metal cations by Olivier soil was mutually reduced when applied simultaneously. When applied consecutively, the cation of higher affinity was able to displace the cation of lower affinity from the soil surface, however, no evidence for the reverse case was observed. A novel general exchange kinetics model was able to correctly describe such displacement. Competition between Ni and Zn mutually increased mobility in Olivier and Windsor …


Spatiotemporal Variability Of Soil Water Δ18o And Δ2h Reveals Hydrological Processes In Two Floodplain Soils, Amanda Ceming-Barbato Sep 2021

Spatiotemporal Variability Of Soil Water Δ18o And Δ2h Reveals Hydrological Processes In Two Floodplain Soils, Amanda Ceming-Barbato

LSU Master's Theses

The movement of water through soil is preferential and heterogeneous. Subsurface interactions between mobile flows and the soil matrix are not uniform and are therefore difficult to predict through time and space. The use of stable isotopes of hydrogen (2H) and oxygen (18O) as conservative tracers of water movement is improving understanding of soil hydrological processes, yet field-scale observations of isotopic variability remain scarce despite implications for identifying dominant hydrologic processes. We sampled two adjacent soils at a ridge-swale topography floodplain forest to determine soil water isotopic variability at a 20 cm depth resolution in soils …


Glyphosate In Soils: Retention, Transport, And Effect Of Phosphate, Joshua Padilla Jun 2018

Glyphosate In Soils: Retention, Transport, And Effect Of Phosphate, Joshua Padilla

LSU Master's Theses

Glyphosate [N-(phosphonomethyl) glycine)] (GPS) is currently the most commonly used herbicide worldwide, and is generally considered as immobile in soils. However, numerous reports of the environmental occurrence of the herbicide coupled with recent evidence of human toxicity require further investigation as to the behavior of GPS in the soil environment. The objectives of this study were to quantify GPS sorption and mobility in two Louisiana agricultural soils with varying physiochemical properties; Commerce silt loam and Sharkey clay. Results of batch sorption studies indicated a high affinity of both soils for solvated GPS, with 24-hour Freundlich partitioning coefficients of 158 and …