Other Earth Sciences Commons^™

Precambrian Molar-Tooth Structure: Unraveling The Diagenesis Of Ancient Carbonates, Agustin Kriscautzky

Doctoral Dissertations

Molar-tooth structure (MTS) is an enigmatic carbonate fabric that occurs mainly within Proterozoic carbonate host rocks. It is composed of two distinct features: cracks of various morphologies and crack-filling calcite microspar. Although the origins of MTS remain unknown, most previous investigation has focused on the formation of the cracks and mechanisms involved in the void space generation, with less emphasis on the intriguing carbonate fill. In this study I have investigated molar-tooth bearing carbonates from regions that span both paleogeography and geologic time. Analysis at the microscopic scale, including traditional petrography, cathodoluminescence petrography, scanning electron microscopy, and micrometer-scale geochemical analyses …

Fire-Vegetation-Climate Interactions Across The Holocene On The U.S. Southeastern Coastal Plain, Mathew S. Boehm

Doctoral Dissertations

This dissertation research examined multiple proxy indicators in sediment cores from one lake and one wetland to reconstruct long-term relationships between fire, vegetation, and climate in the southeastern U.S.

At Lake Balboa (30.6992 N, 83.2031 W; 48 m elevation), a sinkhole pond located in southern Georgia, Bølling-Allerød conditions were sufficiently wet to maintain a shallow wetland at the site. Evidence for fire was minimal. Between 12,600 and 9200 cal yr BP, water availability declined, leading to a potential hiatus in sedimentation. During the early Holocene moisture availability increased, leading to greater primary productivity within and outside the lake, triggering an …

Characterizing Groundwater Ch4 And 222rn In Relation To Hydraulic Fracturing And Other Environmental Processes In Letcher County, Ky, St. Thomas Majeau Ledoux

Masters Theses

Hydraulic fracturing of shale deposits has greatly increased the productivity of the natural gas industry by allowing it to exploit previously inaccessible reservoirs. However, previous research has demonstrated that this practice can contaminate shallow aquifers with CH₄ [methane] from deeper formations. This study compares concentrations and isotope compositions of CH₄ sampled from domestic groundwater wells in Letcher County, Kentucky in order to characterize its occurrence and origins in relation to neighboring hydraulically fractured natural gas wells. Additionally, this study tests the reliability of ²²²Rn [radon] as an alternative tracer to CH₄ in identifying processes of gas …

Testing A Novel Technique To Improve Aluminum-26 Accelerator Mass Spectrometry Measurements For Earth Science Applications, Meghan Sarah Janzen

Masters Theses

The measurement of cosmogenic ²⁶Al [aluminum-26] in geological samples by accelerator mass spectrometry (AMS) is typically conducted on Al₂O₃ [aluminum oxide] targets. However, Al₂O₃ is not an ideal source material because it does not form a prolific beam of Al^- [negative atomic aluminum ions] required for measuring low-levels of ²⁶Al. This thesis presents the performance of AlN [aluminum nitride], AlF₃ [aluminum fluoride] and mixed AlN + Al₂O₃ as novel alternative source materials for the analysis of ²⁶Al. A negative ion cesium sputtering source at the Holifield …

Characterizing Phyllosilicate Distribution, Abundance, And Origin On Mars, Christina Elizabeth Viviano

Doctoral Dissertations

Secondary phyllosilicates are hydrated minerals formed in the presence of liquid water. On Earth, their formation is often indicative of a neutral, water-rich environment, capable of supporting and preserving organic matter. Different phyllosilicate species may be produced in different pH levels and water-to-rock ratios. The identification of mineralogically diverse phyllosilicates in small, localized exposures on Mars provides a complex record of their formation processes. While discrete outcrops of phyllosilicates have been previously identified in high-resolution visible/near-infrared images of Mars, regional coverage of these phyllosilicate-rich areas at better resolution is limited. Furthermore, spectra of minerals in this wavelength range do not …