Other Earth Sciences Commons^™

Geomorphic And Paleoclimatic Implications Of Glacial Extent Records In The Sierra Nevada Del Cocuy, Colombia During Termination 1, Jordan Nickerson Herbert

Dartmouth College Master’s Theses

Reconstructions of past glacial extents using geomorphic mapping and cosmogenic dating provide an opportunity to infer past climates. A record of the past extents of tropical mountain glaciers is particularly useful because there are few other means to reconstruct past temperatures in high-altitude, low-latitude locations. The tropics play an outsized role in mediating global climate, yet there is a lack of understanding of how the tropics may have influenced past climate changes such as the most recent deglaciation (Termination 1, ~18–11.7 ka). Improving reconstructions of tropical mountain glaciers will aid in understanding the role of the tropics in the global …

Geochemical Characterization Of The Bone Spring Formation, Delaware Basin, Using Chemostratigraphy And Integrated Petrophysics, David Tonner

Electronic Theses and Dissertations

The Delaware Basin forms part of West Texas's and New Mexico’s famous petroleum-generating Permian Basin. The Bone Spring Formation is a prolific hydrocarbon producer within this basin, creating one of the world’s richest oil shales. This formation has lithological sequences that are characterized by repeating carbonate and siliciclastic intervals of a third-order cycle which can largely be correlated to highstand and lowstand systems tracts, respectively. Lithological complexity and facies change are manifested by debris flows, turbidites, and slumps. In addition to glacio-eustasy, both tectonism and broader Milankovitch cycles have influenced the depositional history. Previous investigations have utilized cores and wireline …

Precambrian Molar-Tooth Structure: Unraveling The Diagenesis Of Ancient Carbonates, Agustin Kriscautzky

Doctoral Dissertations

Molar-tooth structure (MTS) is an enigmatic carbonate fabric that occurs mainly within Proterozoic carbonate host rocks. It is composed of two distinct features: cracks of various morphologies and crack-filling calcite microspar. Although the origins of MTS remain unknown, most previous investigation has focused on the formation of the cracks and mechanisms involved in the void space generation, with less emphasis on the intriguing carbonate fill. In this study I have investigated molar-tooth bearing carbonates from regions that span both paleogeography and geologic time. Analysis at the microscopic scale, including traditional petrography, cathodoluminescence petrography, scanning electron microscopy, and micrometer-scale geochemical analyses …

Glaciochemical Investigations In Three Southern Hemisphere Mountain Sites, Mariusz Potocki

Electronic Theses and Dissertations

The research presented in this dissertation focuses on glaciochemical records of trace elements, major ions, and stable water isotopes from three mountain regions: the Antarctic Peninsula, the Central Chilean Andes, and South Georgia Island.

The first section reports a significant increase in U concentration over 27 years on Detroit Plateau, Antarctic Peninsula. U concentrations in the ice core increase by as much as 102 between the 1980s and 2000s, accompanied by increased variability in recent years. The U concentration increase coincides with expanded open pit mining in the Southern Hemisphere, most notably Australia. Since other land-source dust elements do not …

Oxygen Speciation In Potassium Silicate And Potassium Aluminosilicate Glasses: Insights From X-Ray Photoelectron Spectroscopy, Ryan Sawyer

Electronic Thesis and Dissertation Repository

In a geological context, glasses are useful analogues for silicate melts as they are more readily studied in the laboratory using a wide range of techniques that are impractical for molten liquids. Understanding the structure of binary silicate glasses can help us understand more about the magmatic processes that affect terrestrial planetary bodies.

Potassium silicate glasses ranging in composition from 10 mol% to 35 mol% K₂O were studied using X-ray Photoelectron Spectroscopy (XPS). From high resolution O 1s XPS spectra, Bridging Oxygen (BO) mole fractions were calculated and compared with those of previous ²⁹Si MAS NMR studies. …

Fate And Transport Of Toxoplasma Gondii Oocysts In Saturated Porous Media: Effects Of Electrolytes And Natural Organic Matter, Christian Pullano

All Theses

Toxoplasma gondii is a pathogenic microorganism that is currently a threat to public health. Understanding the fate and transport of T. gondii through the soil and groundwater is vital in determining the risk it poses to water resources and human health. The physico-chemical interactions between the groundwater and the bio colloid within an aquifer will dictate its mobility and its ability to infect humans. This research examines how various naturally occurring groundwater chemistries containing organic compounds and monovalent and divalent salt solutions will alter the fate and transport of T. gondii. Solutions containing various concentrations of humic acid, fulvic …

Evaluating Alternative Ebullition Models For Predicting Peatland Methane Emission And Its Pathways Via Data–Model Fusion, Shuang Ma, Lifen Jiang, Rachel M. Wilson, Jeff P. Chanton, Scott Bridgham, Shuli Niu, Colleen M. Iversen, Avni Malhotra, Jiang Jiang, Xingjie Lu, Jason Keller, Xiaofeng Xu, Daniel M. Ricciuto, Paul J. Hanson, Yiqi Luo

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Understanding the dynamics of peatland methane (CH₄) emissions and quantifying sources of uncertainty in estimating peatland CH₄ emissions are critical for mitigating climate change. The relative contributions of CH₄ emission pathways through ebullition, plant-mediated transport, and diffusion, together with their different transport rates and vulnerability to oxidation, determine the quantity of CH₄ to be oxidized before leaving the soil. Notwithstanding their importance, the relative contributions of the emission pathways are highly uncertain. In particular, the ebullition process is more uncertain and can lead to large uncertainties in modeled CH₄ emissions. To improve model simulations …

Evaluating Alternative Ebullition Models For Predicting Peatland Methane Emission And Its Pathways Via Data–Model Fusion, Shuang Ma, Lifen Jiang, Rachel M. Wilson, Jeff P. Chanton, Scott Bridgham, Shuli Niu, Colleen M. Iversen, Avni Malhotra, Jiang Jiang, Xingjie Lu, Yuanyuan Huang, Jason Keller, Xiaofeng Xu, Daniel M. Ricciuto, Paul J. Hanson, Yiqi Luo

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Understanding the dynamics of peatland methane (CH4) emissions and quantifying sources of uncertainty in estimating peatland CH4 emissions are critical for mitigating climate change. The relative contributions of CH4 emission pathways through ebullition, plant-mediated transport, and diffusion, together with their different transport rates and vulnerability to oxidation, determine the quantity of CH4 to be oxidized before leaving the soil. Notwithstanding their importance, the relative contributions of the emission pathways are highly uncertain. In particular, the ebullition process is more uncertain and can lead to large uncertainties in modeled CH4 emissions. To improve model simulations of CH4 emission and its pathways, …

Investigation Of Sulphide-Poor Gold Mineralization At The Deep A Zone, Kiena Complex, Québec, Stephanie A. Kobylinski

Electronic Thesis and Dissertation Repository

The Kiena Complex is located halfway between Malartic and Val d’Or in Québec, within the Abitibi Greenstone belt in the Superior Province. This study examined mineralization at the Kiena Complex using detailed core logging, geochemical analysis of wall rock, petrography, EPMA, and gold deportment studies. The analysis and interpretations indicate that the unique sulphide-poor gold-rich quartz veins of the Deep A Zone at the Kiena Complex contain 500 μm²) are located at the contact of quartz and corroded albite grains, and fine gold grains (5-500 μm²) are hosted within the corroded albite.

The Mineralogy And Geochemistry Of Illinois Basin Paleosols: Recognizing Detrital, Pedogenic, And Diagenetic Minerals, Julia A. Mcintosh

Earth Sciences Theses and Dissertations

The geochemical compositions of minerals in paleosols are assumed to be homogenous and attained through chemical weathering processes during episodes of pedogenesis in the geologic past. As such, the geochemical composition of minerals from paleosols may be used to reconstruct ancient climates and environments. One problem with this assumption is that paleosols were initially clastic sedimentary rocks or substrate prior to pedogenesis, thus it is likely that some portion of the paleosol is still composed of detrital minerals. Secondly, conditions may change in a sedimentary basin as the basin is buried and later uplifted, potentially triggering new mineralization or transformation …

Chemical Characterization Of Clastic Cave Sediments And Insights Into Particle Transport And Storage In Karst Aquifers, Jill L. Riddell

Graduate Theses, Dissertations, and Problem Reports

Abstract

Chemical characterization of clastic cave sediments and insights into particle transport and storage in karst aquifers

Jill L. Riddell

Cave sediments can be divided into two groups: precipitates and clastics. Precipitates are speleothems, or lithologic or mineral features that are chemically precipitated in the cave environment. Clastic cave sediments are frequently described by depositional facies, sorting, and particle size (Bosch and White, 2004). Robust analytical chemical analyses of these sediments to quantify their physical and chemical components is rarely performed although some chemical characterization of mineralogy and paleomagnetism has become prevalent in recent years (Chess et al., 2010; Sasowsky …