Hydrology Commons^™

Modeling Transport Of Colloid-Bound Herbicides And Heavy Metals To Groundwater, Anastasios D. Karathanasis, R. E. Phillips, A. K. Seta

KWRRI Research Reports

Recent studies have suggested that contaminant transport to groundwater may be enhanced by association with colloidal particles. This study evaluated the role of water dispersible colloids with diverse mineralogical composition in co-transporting selected herbicides and heavy metals through intact soil columns. Colloid recovery in the eluents ranged from 45-90% for the herbicides and 10-60% for the heavy metals. The presence of colloids enhanced the transport of atrazine by 2-18%, and metolachlor by 8-30%. The corresponding increase for Cu and Zn was 2-150 and 5-30 times, respectively. For Pb, there was essentially no elution in the absence of colloids, suggesting nearly …

Flash-Flood Monitoring And Modeling In Kentucky, Mark French, Nageshwar Bhaskar, George K. A. Kyiamah

KWRRI Research Reports

This research project focused on the evaluation of hydrologic issue of flash-flooding in the state of Kentucky. The primary objectives of this project were the following:
(1) to initiate the establishment of a hydrologic database archive necessary for characterizing rainfall and runoff associated with flash-flooding;
(2) identification of appropriate modeling approaches for evaluating site-specific flash-flood runoff behavior.

Specific tasks accomplished to meet the objectives include the following:
(1) development of a rainfall and streamflow data archive using existing measurement gages and identification of the rain gage data from two sources for preliminary quality control;
(2) identification of the spatial and …

Chloroform Contamination In The Louisville Aquifer: An Investigation Of Its Occurrence And Propagation, Sergio E. Serrano

KWRRI Research Reports

This report presents the main results of an investigation on the nature and propagation of an accidental spill of chloroform in the Louisville aquifer, Kentucky. Much of the effort is concentrated on the development of mathematical models to either reconstruct the history of evolution of the plume, or forecast its propagation in the future. Chloroform is a dense halogenated solvent which exhibits a special migration pattern in porous media: Because of this and the relative absence of a conceptual theory on its hydrodynamics in porous media, meaningful predictive models will have to deal with many unresolved theoretical aspects of contaminant …

Modeling Mass Transport In Aquifers: The Distributed Source Problem, Sergio E. Serrano

KWRRI Research Reports

This report presents a new methodology to model the time and space evolution of groundwater variables in a system of aquifers when certain components of the model, such as the geohydrologic information, the boundary conditions, the magnitude and variability of the sources or physical parameters are uncertain and defined in stochastic terms. This facilitates a more realistic statistical representation of groundwater flow and groundwater pollution forecasting for either the saturated or the unsaturated zone. The method is based on applications of modern mathematics to the solution of the resulting stochastic transport equations. This procedure exhibits considerable advantages over the existing …

Effects Of Aromatic Concentration On Methane Fermentation, Yi-Tin Wang, Pin-Chieh Pai, H. David Gabbard

KWRRI Research Reports

The anaerobic biodegradability and toxicity of fourteen aromatic compounds were evaluated over a wide range of concentrations using a serum bottle technique. Benzene, toluene, and all three isomers of xylene were not significantly degraded to methane in a phenol-enriched culture. Complete degradation of 1000 mg/L phenol, 800 mg/L catechol, 100 mg/L 2-NP, 100 mg/L 3- NP, and 100 mg/L 4-NP was observed within two months while depletion of 100 mg/L resorcinol and 1000 mg/L hydroquinone required more than six and eight months incubation, respectively. None of the three isomers of chlorophenol were degraded in the phenol-enriched culture. Batch toxicity assay …

Development Of Dynamic Non-Hortonian Watershed Models For Steeply Sloping Forested Watersheds: Application To Eastern Kentucky, Lindell E. Ormsbee, Abdul Q. Khan

KWRRI Research Reports

A comprehensive conceptual watershed model is developed to simulate the hydrologic response of steeply sloping forested watersheds. Two non-Hortonian and two Hortonian models were first tested with data from selected watersheds in West Virginia and eastern Kentucky in order to understand the different mechanisms of flow responsible for storm hydrograph generation in this type of watersheds. The two non-Hortonian models tested were the kinematic storage model (Sloan et al. 1983) and the saturation deficit model (Beven and Wood, 1983). Both models were unable to adequately reproduce the observed hydrographs in the four forested watersheds considered in this research. The two …

Development Of General Guidelines For The Planning Of Stormwater Management Facilities: Application To Urban Watersheds In Kentucky, Lindell E. Ormsbee, Vincent T. Reinert

KWRRI Research Reports

This report provides a planning methodology and a design tool to help determine the appropriate location and volume of detention basins required to control critical storm events. The technique involves using watershed characteristics including the SCS curve number, time of concentration, peak outflow rate, watershed area and the storage recurrence interval to help predict these detention volumes.

Historical rainfall records are used in a revised continuous simulation program (SYNOP, Hydroscience, Inc,) to determine the rainfall excess from which runoff hydrographs are produced. Various combinations of the watershed characteristics were input and computer analyses done to obtain the required data base. …

Modeling Of Overland Flow By The Diffusion Wave Approach, Rao S. Govindaraju, S. E. Jones, M. L. Kavvas

KWRRI Research Reports

One of the major issues of present times, i.e. water quality degradation and a need for precise answers to transport of pollutants by overland flow, is addressed with special reference to the evaporator pits located adjacent to streams in the oil-producing regions of Eastern Kentucky. The practical shortcomings of the state-of-the-art kinematic wave are discussed and a new mathematical modeling-approach for overland flows using the more comprehensive diffusion wave is attempted as the first step in solving this problem. A Fourier series representation of the solution to the diffusion wave is adopted and found to perform well. The physically justified …

Finite Element Simulation Of Saturated-Unsaturated Subsurface Flow, George E. Blandford

KWRRI Research Reports

A two-dimensional transient model for flow through saturated-unsaturated porous media is developed, The model numerically solves the pressure head dependent or moisture content dependent form of Richard's equation. The model code uses isoparametric quadratic triangular and/or quadrilateral finite elements for the geometric representation and for the weak Galerkin spacial integrations. An implicit, unconditionally stable single-step numerical time integration scheme with an oscilliatory noise reduction option is utilized for the temporal discretization. The highly efficient symmetric skyline (profile) solution scheme is used to solve the resulting simultaneous equations. The nonlinear subsurface flow parameters are approximated using cubic spline interpolation. The element …

Discharge And Travel Time Determinations In The Royal Spring Groundwater Basin, Kentucky, John Thrailkill, Douglas R. Gouzie

KWRRI Research Reports

Groundwater flow in many karst regions, including the Inner Bluegrass Karst Region of central Kentucky in which the study area was located, is unlike groundwater flow in granular aquifers. At least the major flows are turbulent and often with a free surface in large conduits, and applying concepts based on Darcy's Law to describe and model these flows is inappropriate. Parameters such as linear velocity, channel geometry, and conveyance used to describe surface streamflows are more applicable, and the primary objective of the project was to estimate these in a groundwater basin using the travel time of dye slugs and …

Identification Of Soil-Water Chemical Parameters For The Prediction And Treatment Of Suspended Solids In Surface Water Reservoirs Of Coal Mine Lands, V. P. Evangelou, J. H. Grove, R. I. Barnhisel

KWRRI Research Reports

High concentrations of suspended solids in coal mine sedimentation ponds are a factor in lowering water quality. This study focuses on the influence dissolved solids have on concentration and settling of suspended solids. Water samples from sedimentation ponds in Eastern and Western Kentucky were used to evaluate water composition in such ponds. Spoil samples from surface mine sites in both parts of the state were used to evaluate water composition released from the spoils upon introducing water.

The results demonstrate that water quality emanating from coal spoils of Eastern and Western coal mines is dependent on the type of spoil …

Water Requirement For Coal Slurry Transportation, David T. Kao, Sandra L. Rusher

KWRRI Research Reports

The amount of water required for coal slurry transportation is a function of the coal properties and the magnitude of coal movement. The pipeline system characteristics and the method of slurry preparation also affects the overall water requirement of the system. In the present study methodologies are developed based on reported and modified coal slurry flow correlation equations to determine the quantity of water needed under various coal transport and flow conditions. Auxiliary water requirements including start-up and flushing water storage; related evaporation and seepage losses are also included. A computer program and several monographs are presented to provide a …

Predicting Infiltration And Surface Runoff From Reconstructed Spoils And Soils, Larry G. Wells, Andrew D. Ward, Ronald E. Phillips

KWRRI Research Reports

A laboratory system was fabricated to measure infiltration and runoff from spoil and soil profiles constructed in rectangular bins. Construction, calibration and operation of a rainfall simulator is discussed and instrumentation used to measure transient infiltration and transmittance of water through experimental profiles is described.

Spoil and soil materials from surface mines in Eastern and Western Kentucky were transported to the laboratory and used in constructing experimental profiles in rectangular bins (0.91 x 1.83 x 1.07 m). An extensive series of infiltration experiments were conducted utilizing a rainfall simulator and soil moisture monitoring instrumentation. A dual probe gamma density gauge …

Studies In Dye-Tracing Technologies In Karst Hydrogeology, John Thrailkill, Phillip E. Byrd, Stephen B. Sullivan, Lawrence E. Spangler, Charles J. Taylor, Greta K. Nelson, Kevin R. Pogue

KWRRI Research Reports

Information on fluorescent dyes used for water tracing and the results of six studies are reported. Optical brightener, direct yellow, fluorescein, rhodamine (WT), and other dyes are described and the procedures employed in their use ·in the field and in equilibration experiments are discussed. Three of the six studies consisted of investigations of the equilibration with passive detectors of three of the dyes. The absorption of optical brightener on fabric detectors was apparently linear with concentration and with immersion time, while detectors became rapidly saturated with direct yellow. Equilibrium of fluorescein on charcoal detectors with an elutriating solution was not …

Movement Of Bacteria Through Macropores To Ground Water, M. Scott Smith, Grant W. Thomas, Robert E. White

KWRRI Research Reports

Effects of soil type, flow rate, antecedent soil moisture and other factors on transport of E. coli through soils was measured on disturbed and intact columns 20 cm in diameter by 25 to 30 cm in depth. Added E. coli were distinguished from indigenous microbes using an antibiotic resistance marker. Transport of Cl^- and ³H₂O was also measured. Up to 96 percent of the bacteria irrigated onto the surface of intact columns were recovered in the effluent. Soil structure appeared to be related to the extent of transport. Columns prepared from mixed, repacked soil were much …

Groundwater In The Inner Bluegrass Karst Region, Kentucky, John Thrailkill, Lawrence E. Spangler, William M. Hopper Jr., Michael R. Mccann, Joseph W. Troester, Douglas R. Gouzie

KWRRI Research Reports

The hydrogeology of about 12% of the 5600 km² Inner Bluegrass Karst Region of central Kentucky was investigated by water tracing and other techniques. Using fluorescent dyes adsorbed on fabric and charcoal detectors, 96 traces (average length 2.7 km, maximum length 15 km) resulted in the identification of 38 groundwater basins (with areas up to 15 km²). Within the basins, subsurface flow is in a dendritic conduit system at depths up to 30 m below the surface, while in the interbasin areas which separate them flow is generally less than 5 m deep. Each groundwater basin discharges …

Mathematical Model For Water Quality In Streams Impacted By Point And Nonpoint Source Pollution, Michael E. Meadows

KWRRI Research Reports

Modeling the impacts of stormwater runoff on small streams, requires that the prediction model has the capability of simulating the behavior of the hydrologic and water quality components of the stream system. Development of such a model involves coupling the equations for pollutant transport during unsteady flow with the appropriate flood routing equations. The decision on which equations to choose requires a full understanding of the pollutant transport and hydrograph dispersion processes.

This research was undertaken to develop a rigorous theoretical evaluation of the pollutant transport and hydrograph dispersion processes during unsteady flow, and to recommend a suitable model for …

Hydrology And Water Quality In The Central Kentucky Karst: Phase 1, James F. Quinlan, Donald R. Rowe

KWRRI Research Reports

Study of springs and cave streams has shown that heavy metal-rich effluent from a wastewater treatment plant can be traced to Hidden River Cave (beneath the city of Horse Cave) and thence 4 to 5 miles north to a group of 39 springs at 14 locations along a 5-mile reach of Green River. Nickel, chromium, copper and zinc in these effluent-bearing springs are in concentrations of as much as 30 times greater than other springs upstream and downstream from this reach, 20 times greater than the Green River, and 60 times greater than in shallow domestic wells between Horse Cave …

Hydrodynamic Separation Of Solids From Solid-Liquid Mixtures, Harry J. Sterling Jr., Don J. Wood

KWRRI Research Reports

Several schemes for separating solid pollutants from water flowing in a closed conduit were examined. Separation based on the momentum differential between the solids and liquids and the centrifugal movement of a conveying liquid were both examined under turbulent flow conditions. The study indicated these processes to have limited applications, primarily due to the difficulties in withdrawing a significant fraction of separated flow and the deleterious effects of turbulent mixing. However, utilization of the differential momentum of solid particles and water when flowing laminarly through a pipe was found to be a viable separation scheme. Significant experimental separations (greater than …

Analysis Of Unsteady Flow Toward Artesian Wells By Three-Dimensional Finite Elements, Yang H. Huang, Shen-Jyh Wu

KWRRI Research Reports

A three-dimensional finite element computer program was developed for analyzing unsteady flow toward artesian wells. The program is designed especially for determining the drawdown around an artesian well penetrating fully or partially a nonhomogeneous and anisotropic aquifer of irregular shape and cross section. It can also be used as a general program for aquifer simulation and evaluation. A major advantage of the program lies in the minimum amount of input data required. By assuming the top and bottom boundaries of the aquifer as two arbitrary planes, the aquifer will be divided into six- or eight-node elements, and their nodal coordinates …

Characterization Of Water Movement Into And Through Soils During And Immediately After Rainstorms, C. T. Haan

KWRRI Research Reports

The movement of water into and through soils in the unsaturated state is basic to many water resources problems including rainfall-runoff models, ground water recharge, irrigation, drainage, evapotranspiration and the movement of pollutants in soils. This study was conducted in an effort to determine if the flow equation based on Darcy's Law and the continuity equation could be used to describe watershed infiltration and thus be incorporated into hydrologic models.

The results of the study indicate that even on apparently uniform soils there is a great deal of variability in soil water properties. Handling this variability plus the difficulty of …

The Relation Between Soil Characteristics, Water Movement And Nitrate Contamination Of Ground Water, Grant W. Thomas, Matthew Mcmahon

KWRRI Research Reports

Soils from several areas in Kentucky were placed in columns and leached with Ca(NO₃)₂. Subsoils high in iron oxide were found to retard the leaching of nitrate very significantly. In other soils, the nitrate moved through as fast as or slightly faster than the water.

Field application of nitrogen to corn was most efficient when done in the spring or summer near the time that the corn takes it up. The one exception to this was a red soil, where fall application of nitrogen resulted in little loss due to the retarding effect mentioned in the …

Hydraulic And Sediment Transport Studies In Relation To River Sediment Control And Solid Waste Pollution And Economic Use Of The By-Products, Bruce R. Moore, Michael R. Short

KWRRI Research Reports

The distribution of sediments and conditions of transport were studied in the Kentucky, Big Sandy and Ohio Rivers. The sand and coal were in transport at different flow velocities for the rivers and the deposition of these sediments was a direct function of the flow conditions at a particular locality.

The flow conditions of transport of the sediments were studied in flumes as were the hydraulic conditions in model dredge holes to determine the feasibility of trapping sediment. The conditions of scour and fill were also established and compared with known conditions in a dredge hole in the Ohio River. …

The Generation Of Flood Damage Time Sequences, John P. Breaden

KWRRI Research Reports

There is a need in water resources planning to develop a procedure for determining the time pattern in which flood damages occur as a function of the rise and fall of the flood hydrograph. The widely-used approach for estimation of flood damages does not take into account the fact that the frequency of the annual flood peak may not be the same as the frequency of the total annual flood damages. As examples, several small storms during the year may do more damage than a single larger storm, or flood damages may be reduced by a reduction in flood duration …

Opset Program For Computerized Selection Of Watershed Parameter Values For The Stanford Watershed Model, Earnest Yuan-Shang Liou, L. Douglas James

KWRRI Research Reports

The advent of high-speed electronic computer made it possible to model complex hydrologic processes by mathematical expressions and thereby simulate streamflows from climatological data. The most widely used program is the Stanford Watershed Model, a digital parametric model of the land phase of the hydrologic cycle based on moisture accounting processes. It can be used to simulate annual or longer flow sequences at hourly time intervals. Due to its capability of simulating historical streamflows from recorded climatological data, it has a great potential in the planning and design of water resources systems. However, widespread use of the Stanford Watershed Model …

Solution Geochemistry Of The Water Of Limestone Terrains, John Thrailkill, David B. Beiter, Michael T. Osolnik, Roger H. Postley, William T. Mitchell, Leonard N. Plummer, James R. Riddell, Richard C. Worley, Robert D. Zwicker

KWRRI Research Reports

Limestone groundwater flows mainly in openings it has solutionally enlarged, thus an understanding of the water's state of saturation relative to calcite (the principal mineral component of limestone) is fundamental to an understanding of the nature and evolution of the limestone aquifer. This study investigated the Mammoth Cave-Sinkhole Plain (MCSP) and Cave Hollow (CH) aquifers in Kentucky, both in Missippian limestones.

Both aquifers were always undersaturated with calcite. Except for completely ventilated vadose flows (usually) and some vadose seepage (occasionally), all recharges sampled (sinking streams, vadose flows, and vadose seepage) were also undersaturated. The lack of saturation in the MCSP …

The Effects Of Geographical And Climatic Setting On The Economic Advantages Of Alternative Flood Control Measures, Clyde R. Dempsey, L. Douglas James

KWRRI Research Reports

It has long been realized that tributary urban development and channel improvement greatly affect the flow regime in a given watershed. A previous study used the Stanford Watershed Model to derive relationships expressing how the flood peaks in Sacramento, California, might be expected to vary with changing conditions of urbanization, channelization, and tributary drainage area. In order to observe the effects of climatic setting and geographical location on these relationships, the same type of analysis was applied to a drainage area near Louisville, Kentucky.

If reservoir storage is to be considered in a flood control program, it is necessary to …