Glaciology Commons^™

Glaciochemical Investigations In Three Southern Hemisphere Mountain Sites, Mariusz Potocki

Electronic Theses and Dissertations

The research presented in this dissertation focuses on glaciochemical records of trace elements, major ions, and stable water isotopes from three mountain regions: the Antarctic Peninsula, the Central Chilean Andes, and South Georgia Island.

The first section reports a significant increase in U concentration over 27 years on Detroit Plateau, Antarctic Peninsula. U concentrations in the ice core increase by as much as 102 between the 1980s and 2000s, accompanied by increased variability in recent years. The U concentration increase coincides with expanded open pit mining in the Southern Hemisphere, most notably Australia. Since other land-source dust elements do not …

An Ice-Core Proxy For Northerly Air Mass Incursions Into West Antarctica, Daniel D. Dixon, Paul Andrew Mayewski, Ian D. Goodwin, Gareth J. Marshall, Rhaelene Freeman, Kirk A. Maasch, Sharon B. Sneed

Earth Science Faculty Scholarship

A 200-year proxy for northerly air mass incursions (NAMI) into central and western West Antarctica is developed from the examination of 19 shallow (21–150 m deep) Antarctic ice-core non-sea-salt (nss) Ca2+ concentration records. The NAMI proxy reveals a significant rise in recent decades. This rise is unprecedented for at least the past 200 years and is coincident with anthropogenically driven changes in other large-scale Southern Hemisphere (SH) environmental phenomena such as greenhouse gas (GHG) induced warming, ozone depletion, and the associated intensification of the SH westerlies. The Hysplit trajectory model is used to examine air mass transport pathways into West …

State Of The Antarctic And Southern Ocean Climate System, Paul Andrew Mayewski, M. P. Meredith, C. P. Summerhayes, J. Turner, A. Worby, P. J. Barrett, G. Casassa, Nancy Bertler, T. Bracegirdle, A. C. Naveira Garabato, D. Bromwich, H. Campbell, Gordon S. Hamilton, W. B. Lyons, Kirk A. Maasch, S. Aoki, C. Xiao, Tas Van Ommen

Earth Science Faculty Scholarship

This paper reviews developments in our understanding of the state of the Antarctic and Southern Ocean climate and its relation to the global climate system over the last few millennia. Climate over this and earlier periods has not been stable, as evidenced by the occurrence of abrupt changes in atmospheric circulation and temperature recorded in Antarctic ice core proxies for past climate. Two of the most prominent abrupt climate change events are characterized by intensification of the circumpolar westerlies (also known as the Southern Annular Mode) between ∼6000 and 5000 years ago and since 1200–1000 years ago. Following the last …

Sources And Deposition Processes Linking Atmospheric Chemistry And Firn Records From Four Glacier Accumulation Zones In The Mcmurdo Dry Valleys, Antarctica, Bruce R. Williamson

Electronic Theses and Dissertations

Samples of snow and firn from accumulation zones on the Victoria Upper Glacier, the Clark Glacier, the Commonwealth Glacier and the Blue Glacier in the McMurdo Dry Valleys (~77 to 78º S and 161 to 164º E), Antarctica, are evaluated chemically and isotopically to determine the relative importance of local (site-specific) factors versus regional-scale climatic influences in defining regional glaciochemistry. Two approaches for distinguishing these controls are examined: comparing chemical concentrations using multivariate statistical analysis, and examining the effect of physical filtration (capturing particulate material largely originating in close proximity to each site) on sample values. These techniques provide constraints …

The International Trans-Arctic Scientific Expedition (Itase): An Overview, Paul Andrew Mayewski, Massimo Frezzotti, Nancy Bertler, Tas Van Ommen, Gordon S. Hamilton, Tim H. Jacka, Brian Welch, Markus Frey, Dahe Qin, Jiawen Ren, Jefferson Simões, Michel Fily, Hans Oerter, Fumihiko Nishio, Elisabeth Isaksson, Robert Mulvaney, Per Holmund, Volodya Lipenkov, Ian Goodwin

Earth Science Faculty Scholarship

From its original formulation in 1990 the International Trans-Antarctic Scientific Expedition (ITASE) has had as its primary aim the collection and interpretation of a continent-wide array of environmental parameters assembled through the coordinated efforts of scientists from several nations. ITASE offers the ground-based opportunities of traditional-style traverse travel coupled with the modern technology of GPS, crevasse detecting radar, satellite communications and multidisciplinary research. By operating predominantly in the mode of an oversnow traverse, ITASE offers scientists the opportunity to experience the dynamic range of the Antarctic environment. ITASE also offers an important interactive venue for research similar to that afforded …

Antarctic Oversnow Traverse-Based Southern Hemisphere Climate Reconstruction, Paul Andrew Mayewski

Earth Science Faculty Scholarship

On 2 January 2003, the U.S. component of the International Trans Antarctic Scientific Expedition (U.S. ITASE) (Figure 1) arrived at the South Pole after completing more than 5000 km of oversnow traverses that included much of west Antarctica and a portion of east Antarctica (Figure 2). During the traverses, which were performed from 1999 through 2003, U.S. ITASE focused on collecting data that will allow the reconstruction of sub-annual scale climate variability and changes in the chemistry of the atmosphere over the last 200+ years.

ITASE is a multi-disciplinary research program supported by 19 nations and endorsed by the Scientific …

Chemical Composition Of Fresh Snow On Xixabangma Peak, Central Himalaya, During The Summer Monsoon Season, Shichang Kang, Dahe Qin, Paul Andrew Mayewski, Sharon B. Sneed

Earth Science Faculty Scholarship

The physical and chemical analysis of ice cores recovered from glaciers in the Himalaya provide some of the best records of past climate change in the region (e.g. Qin and others, 2000; Thompson and others, 2000; Kang and others, 2001, 2002). In order to better understand the climatic and environmental records preserved in snow and ice, studies have investigated the precipitation chemistry in the high Himalaya, notably that the northern slopes of the central Himalaya (Mayewski and others, 1986; Jenkins and others 1987) and the southern slopes of the central Himalaya (Shrestha and others, 1997; Marinoni and others, 2001).

Methanesulfonate In The Firn Of King George Island, Antarctica, Jiankang Han, Zichu Xie, Xinping Zhang, Dongsheng Dai, Paul Andrew Mayewski, M. S. Twickler

Earth Science Faculty Scholarship

Methanesulfonate was investigated as a potential contributor to the sulfur budget, based on analysis of a firn core from Collins Ice Cap, King George Island, Antarctica (62°10' S, 58°50' W). The anion was found to be present at a mean concentration of 0.17 μeq L^-1, with a maximum of 0.73 μeq L^-1. Dating based on the δ¹⁸O profile suggests that the principal peaks of methanesulfonate are associated with snow deposited in summer and autumn. A careful examination of MSA, SO₄^2-and nssSO₄^2- profiles indicates that two of the three peaks …

Monsoon And Dust Signals Recorded In Dasuopu Glacier, Tibetan Plateau, Kang Shichang, Cameron P. Wake, Qin Dahe, Paul Andrew Mayewski, Yao Tandong

Earth Science Faculty Scholarship

During summer 1997, a 15m firn core was recovered from Dasuopu glacier (28°23'N, 85° 44' E; 7000 m a.s.l.) on the northwest margin of Xixabangma Feng in the central Himalaya. Oxygen isotope values and concentrations of Ca²⁺, Mg²⁺, NH₄⁺, SO₄^2- and NO₃^- were measured over the 10 years of snow accumulation captured in the firn core. The seasonal variations of δ¹⁸O values and major-ion concentrations in the Dasuopu core indicated that summer monsoon and dust signals are clearly recorded in Dasuopu glacier. Annual variations in the δ …

Maximum Temperature Trends In The Himalaya And Its Vicinity: An Analysis Based On Temperature Records From Nepal For The Period 1971-94, Arun B. Shrestha, Camerson P. Wake, Paul Andrew Mayewski, Jack E. Dibb

Earth Science Faculty Scholarship

Analyses of maximum temperature data from 49 stations in Nepal for the period 1971-94 reveal warming trends after 1977 ranging from 0.06° to 0.12°C yr¹ in most of the Middle Mountain and Himalayan regions, while the Siwalik and Terai (southern plains) regions show warming trends less than 0.03°C yr¹. The subset of records (14 stations) extending back to the early 1960s suggests that the recent warming trends were preceded by similar widespread cooling trends. Distributions of seasonal and annual temperature trends show high rates of warming in the high-elevation regions of the country (Middle Mountains and Himalaya), …

Antarctic's Role Pursued In Global Climate Change, Paul Andrew Mayewski, I. Goodwin

Earth Science Faculty Scholarship

The impact of Antarctica on global climate change and the impact of global climate change on Antarctica are the focal points of a current series of expeditions there, and an international, interdisciplinary array of researchers met this past spring to go over the expeditions' progress. Advances were reported in describing the impact of the seasonal cycle, semiannual oscillation, and the El Niño-Southern Oscillation (ENSO) cycle on Antarctic accumulation in recent decades.

Difficulties still remain, however, in explaining fully the history and forcing of the Antarctic climate and the links between tropical forcing and high-latitude response. The difficulties arise largely because …

Spatial Variability Of Climate And Past Atmospheric Circulation Patterns From Central West Antarctic Glaciochemistry, David B. Reusch, Paul Andrew Mayewski, Sallie I. Whitlow, Iqbal I. Pittalawa, Mark S. Twickler

Earth Science Faculty Scholarship

Atmospheric circulation patterns and the spatial variability of atmospheric chemistry and moisture transport in central West Antarctica are investigated using new 40 year long (1954–1994 A.D.) glaciochemical and accumulation rate records developed from four firn cores from this region. The core sites lie on a 200 km traverse from 82° 22′ S, 119° 17′ W to 81° 22′ S, 107° 17′ W. The glaciochemical records represent the major ionic species present in Antarctic snow: Na⁺, K⁺, Mg²⁺, Ca²⁺, Cl⁻, NO₃⁻, and SO₄²⁻. High spatial …

Climatological Significance Of Δ18O In Precipitation And Ice Cores: A Case Study At The Head Of The Ürütnqi River, Tien Shan, China, Hou Shugui, Qin Dahe, Paul Andrew Mayewski, Yang Qinzhao, Ren Jiawen, Li Zhongqin, Xiao Cunde

Earth Science Faculty Scholarship

Stable-oxygen-isotope ratios (δ¹⁸O) collected from the headwaters of the Ürümqi river, Tien Shan, China, were used to test the relationship between δ¹⁸O temporal relationship is found between δ¹⁸O monthly averages which remove synoptic-scale influences such as changes in condensation level, condensation temperature and moisture sources (Yao and others, 1996). Linear fits as high as 0.95‰°C^-1 for precipitation events and 1.23‰°C^-1 for monthly averages are found. Although the δ¹⁸O (∼2 km from the precipitation sampling site) decreased dramatically compared to the precipitation samples , the ice-core records of annually averaged δ …

Soluble Species In Aerosol And Snow And Their Relationship At Glacier 1, Tien Shan, China, Junying Sun, Dahe Qin, Paul Andrew Mayewski, Jack E. Dibb, Sallie Whitlow, Zhongqin Li, Qinzhao Yang

Earth Science Faculty Scholarship

Simultaneous sampling of aerosol (n = 20) and snow (n = 114) was made at Glacier 1, Tien Shan, between May 19 and June 29, 1996. Similar temporal patterns of some major ion (calcium, magnesium, potassium, sodium, chloride, and sulfate) concentrations between snow and aerosol show that snow chemistry basically reflects changes in the chemistry of the atmosphere. This gives us confidence in the reconstruction of past atmospheric change using some snow data. There are no significant correlations between aerosol and snow samples for ammonium and nitrate. This suggests that postdepositional and/or postcollection processes may alter ammonium and …

Assessment Of The Record Of The 1982 El Chichón Eruption As Preserved In Greenland Snow, Gregory A. Zielinski, Jack E. Dibb, Qinzhao Yang, Paul Andrew Mayewski, Sallie Whitlow, Mark S. Twickler, Mark S. Germani

Earth Science Faculty Scholarship

Variability in the SO 4 2 - and Cl⁻ time series for the 1980s from 12 shallow snow pits across the Greenland ice sheet is used to evaluate the record of the 1982 El Chichón eruption and the potential for recording a moderate northern equatorial eruption in a single Greenland ice core. Composition of volcanic glass found in spring 1983 snow in one of the pits in the Summit region matches that from El Chichón glass, thereby verifying the deposition of material from the eruption. High Na⁺ and Cl⁻ concentrations in this same layer probably represent deposition …

A 110,000-Year History Of Change In Continental Biogenic Emissions And Related Atmospheric Circulation Inferred From The Greenland Ice Sheet Project Ice Core, L. D. Meeker, Paul Andrew Mayewski, M. S. Twickler, S. I. Whitlow, D. Meese

Earth Science Faculty Scholarship

The 110,000-year record of ammonium concentrations from the Greenland Ice Sheet Project 2 (GISP2) ice core provides the basis for an analysis of terrestrial biological production and atmospheric circulation patterns involved in the transport of biologically produced ammonium to the Greenland atmosphere. The directly measured concentration series was selected for analysis, rather than that of estimated ammonium flux, after a detailed analysis of the relationship among ice core glaciochemical concentrations and a high-resolution simultaneous record of snow accumulation from the GISP2 core. Analysis of the ammonium concentration series shows that maxima in background levels of ammonium in the Greenland atmosphere …

The Co2 Concentration Of Air Trapped In Greenland Ice Sheet Project 2 Ice Formed During Periods Of Rapid Climate Change, H. J. Smith, M. Wahlen, D. Mastroianni, K. Taylor, Paul Andrew Mayewski

Earth Science Faculty Scholarship

The CO₂ content of air occluded in Greenland Ice Sheet Project 2 (GISP2) ice formed over two separate intervals of rapidly changing climate, centered at approximately 46 and 63 kyr B. P., is as much as 90 ppm more during warm periods (interstadials) than during cold periods (stadials). These CO₂ variations are superimposed on changes in annual layer thickness and δ¹⁸O of the ice and do not show the 200- to 700-year offsets which would be expected for concurrent variations in the atmosphere and the ice. The CO₂ concentrations during the stadials are similar to …

Electrical Measurements On The Greenland Ice Sheet Project 2 Core, Kendrick C. Taylor, Richard B. Alley, Gregg W. Lamorey, Paul Andrew Mayewski

Earth Science Faculty Scholarship

The Greenland Ice Sheet Project 2 (GISP2) electrical conductivity measurement (ECM) record is an indication of the concentration of H+ in the core. The ECM detected seasonal variations in the nitrate concentration of the core which were used to assist in dating the core by annual layer counting. Volcanic eruptions that produce acidic aerosols are recorded in the ECM record. Evidence of biomass burning is detected by the ECM because fire-related ammonium emissions neutralize the acids in the core. Rapid climate transitions associated with the Younger Dryas and Dansgaard/Oeschger interstadial events alter the concentration of alkaline dust and are detected …

Paleoclimatic Variability Inferred From The Spectral Analysis Of Greenland And Antarctic Ice-Core Data, R. Yiou, K. Fuher, L. D. Meeker, J. Jouzel, S. Johnsen, Paul Andrew Mayewski

Earth Science Faculty Scholarship

Paleoclimate variations occur at various time scales, between a few centuries for the Heinrich events and several hundreds of millenia for the glacial to interglacial variations. The recent ice cores from Greenland (Greenland Ice Core Project and Greenland Ice Sheet Project 2) and Antarctica (Vostok) span at least one glacial oscillation and provide many opportunities to investigate climate variations with a very fine resolution. The joint study of cores from both hemispheres allows us to distinguish between the sources of variability and helps to propose mechanisms of variations for the different time scales involved. The climate proxies we analyze are …

The Greenland Ice Sheet Project 2 Depth-Age Scale: Methods And Results, D. A. Meese, A. J. Gow, R. B. Alley, G. A. Zielinski, P. M. Grootes, M. Ram, K. C. Taylor, Paul Andrew Mayewski, J. F. Bolzan

Earth Science Faculty Scholarship

The Greenland Ice Sheet Project 2 (GISP2) depth-age scale is presented based on a multiparameter continuous count approach, to a depth of 2800 m, using a systematic combination of parameters that have never been used to this extent before. The ice at 2800 m is dated at 110,000 years B.P. with an estimated error ranging from 1 to 10% in the top 2500 m of the core and averaging 20% between 2500 and 2800 m. Parameters used to date the core include visual stratigraphy, oxygen isotopic ratios of the ice, electrical conductivity measurements, laser-light scattering from dust, volcanic signals, and …

Volcanic Aerosol Records And Tephrochronology Of The Summit, Greenland, Ice Cores, Gregory A. Zielinski, Paul Andrew Mayewski, L. David Meeker, Karl Grönvold, Mark D. Germani, Sallie Whitlow, Mark S. Twickler, Kendrick Taylor

Earth Science Faculty Scholarship

The recently collected Greenland Ice Sheet Project 2 (GISP2) and Greenland Ice Core Project ice cores from Summit, Greenland, provide lengthy and highly resolved records of the deposition of both the aerosol (H₂SO₄) and silicate (tephra) components of past volcanism. Both types of data are very beneficial in developing the hemispheric to global chronology of explosive volcanism and evaluating the entire volcanism-climate system. The continuous time series of volcanic SO₄²⁻ for the last 110,000 years show a strong relationship between periods of increased volcanism and periods of climatic change. The greatest number of volcanic …

Major Features And Forcing Of High-Atitude Northern Hemisphere Atmospheric Circulation Using A 110,000-Year-Long Glaciochemical Series, Paul Andrew Mayewski, Loren D. Meeker, Mark S. Twickler, Sallie Whitlow, Qinzhao Yang, W. Berry Lyons, Michael Prentice

Earth Science Faculty Scholarship

The Greenland Ice Sheet Project 2 glaciochemical series (sodium, potassium, ammonium, calcium, magnesium, sulfate, nitrate, and chloride) provides a unique view of the chemistry of the atmosphere and the history of atmospheric circulation over both the high latitudes and mid-low latitudes of the northern hemisphere. Interpretation of this record reveals a diverse array of environmental signatures that include the documentation of anthropogenically derived pollutants, volcanic and biomass burning events, storminess over marine surfaces, continental aridity and biogenic source strength plus information related to the controls on both high- and low-frequency climate events of the last 110,000 years. Climate forcings investigated …

Methanesulfonate In The Greenland Ice Sheet Project 2 Ice Core, E. S. Saltzman, P-Y. Whung, Paul Andrew Mayewski

Earth Science Faculty Scholarship

In this paper we present measurements of methanesulfonate in the Greenland Ice Sheet Project 2 (GISP2) ice core. Methanesulfonate is an atmospheric oxidation product of dimethylsulfide. The GISP2 methanesulfonate record contains information about the atmospheric loading of biogenic sulfur over the past 110 kyr and its relationship to climate change. The GISP2 data set supports the inferences made from the Renland ice core from Greenland that the glacial atmosphere over Greenland had reduced concentrations of biogenic sulfur compared with the present day [Hansson and Saltzman, 1993]. We conclude that the flux of biogenic sulfur from the North Atlantic Ocean …

Glaciochemistry Of Polar Ice Cores: A Review, Michel Legrand, Paul Andrew Mayewski

Earth Science Faculty Scholarship

Human activities have already modified the chemical composition of the natural atmosphere even in very remote regions of the world. The study of chemical parameters stored in solid precipitation and accumulated on polar ice sheets over the last several hundred thousand years provides a unique tool for obtaining information on the composition of the preindustrial atmosphere and its natural variability over the past. This paper deals with the chemistry of polar ice focused on the soluble mineral (Na⁺, NH₄⁺, K⁺, Ca⁺⁺, Mg⁺⁺, H⁺, F⁻, Cl …

Chemical Species Spatial Distribution And Relationship To Elevation And Snow Accumulation Rate Over The Greenland Ice Sheet, Q. Yang, Paul Andrew Mayewski, E. Linder, S. Whitlow, M. Twickler

Earth Science Faculty Scholarship

Major chemical species (Cl⁻, NO⁻₃, SO²⁻₄, Na⁺, K⁺, Mg²⁺, Ca²⁺) from 24 snowpits (sampled at a resolution of 3 cm, total 2995 samples) collected from northern, central, and southern Greenland were used for this investigation. The annual and seasonal (winter and summer) concentration of each chemical species was calculated and used to study the spatial distribution of chemical species over the central portion of the Greenland Ice Sheet. A two-sided t-distribution test (α=0.05) suggests that concentrations of major chemical species in snow do …

Twin Ice Cores From Greenland Reveal History Of Climate Change, More, R. Alley, Paul Andrew Mayewski, D. Peel, B. Stauffer

Earth Science Faculty Scholarship

Two projects conducted from 1989 to 1993 collected parallel ice cores—just 30 km apart— from the central part of the Greenland ice sheet. Each core is more than 3 km deep and extends back 110,000 years. In short, the ice cores tell a clear story: humans came of age agriculturally and industrially during the most stable climatic regime recorded in the cores. Change—large, rapid, and global—is more characteristic of the Earth's climate than is stasis.

Ice-Core Glaciochemical Reconnaissance In Inland West Antarctica, Karl J. Kreutz, Paul Andrew Mayewski, Mark S. Twickler, Sallie I. Whitlow

Earth Science Faculty Scholarship

To date, the highest resolution ice cores have come from Greenland [the U.S. Greenland Ice Sheet Project 2 (GISP2) and European Greenland Ice Core Project (GRIP)]. The ability to determine annual layering in these cores over at least the past 50,000 years has allowed the reconstruction of a detailed environmental history covering major glacial and interglacial climatic events (e.g., Mayewski et aI. 1994; O'Brien et al. 1995). Although these cores have significantly advanced our understanding of paleoclimatic change in the Northern Hemisphere, questions remain as to whether the two hemispheres have responded synchronously to climate forcing through time. Determining the …

Global Perspective Of Nitrate Flux In Ice Cores, Qinzhao Yang, Paul Andrew Mayewski, Sallie Whitlow, Michael Morrison, Robert Talbot, Jack Dibb, Ernst Linder

Earth Science Faculty Scholarship

The relationships between the concentration and the flux of chemical species(Cl^-, NO₃^-, SO₄^2-, Na⁺, K⁺, NH₄⁺, Mg²⁺, Ca²⁺) versus snow accumulation rate were examined at GISP2 and 20D in Greenland, Mount Logan from the St. Elias Range, Yukon Territory, Canada, and Sentik Glacier from the northwest end of the Zanskar Range in the Indian Himalayas. At all sites, only nitrate flux is significantly(α = 0.05) related to snow accumulation rate. Of all the chemical series, only nitrate concentration data are normally …

Record Drilling Depth Struck In Greenland, Paul Andrew Mayewski, M. S. Twickler, J. E. Dibb, M. Wumkes, J. Klinck, J. S. Putscher, K. C. Taylor, D. A. Meese, E. D. Waddington, R. B. Alley, P. M. Grootes, M. Ram, M. Wahlen, A. T. Wilson

Earth Science Faculty Scholarship

On July 1, 1993, after 5 years of drilling, the Greenland Ice Sheet Project (GISP2) penetrated several meters of silty ice and reached bedrock at a depth of 3053.4 m. It then penetrated 1.5 m into the bedrock, producing the deepest ice core ever recovered (Figure 1).

In July 1992, a nearby European ice coring effort, the Greenland Ice Core Project (GRIP), reached an ice depth of 3028.8 m, providing more than 250,000 years of record. Comparisons between these ice core records have already demonstrated the remarkable reproducibility of the upper ∼90% of the records unparalleled view of climatic and …

Two-Hundred-Year Record Of Biogenic Sulfur In A South Greenland Ice Core (20d), P. Y. Whung, E. S. Saltzman, M. J. Spencer, Paul Andrew Mayewski, N. Gundestrup

Earth Science Faculty Scholarship

The concentration of methanesulfonic acid (MSA) was determined in a shallow south central Greenland ice core(20D). This study provides a high-resolution record of the DMS-derived biogenic sulfur in Greenland precipitation over the past 200 years. The mean concentration of MSA is 3.30 ppb(σ = 2.38 ppb,n = 1134). The general trend of MSA is an increase from 3.01 to 4.10 ppb between 1767 and 1900, followed by a steady decrease to 2.34 ppb at the present time. This trend is in marked contrast to that of non-sea-salt sulfate (nss SO₄^2-), which increases dramatically after 1900 due to …