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Isotopes Of Carbon In A Karst Aquifer Of The Cumberland Platea Of Kentucky , Usa, Lee J. Florea
Isotopes Of Carbon In A Karst Aquifer Of The Cumberland Platea Of Kentucky , Usa, Lee J. Florea
Lee J Florea, PhD, P.G.
In this study, the concentration and isotopic composition of dissolved organic carbon (DOC) and dissolved inorganic carbon (DIC) are measured in the karst groundwater of the Otter Creek watershed of the Cumberland Plateau of Kentucky, USA. Comparisons among these data and with the geochemistry of carbonate and gypsum equilibrium reactions reveal that DOC concentration is inversely related to discharge, multiple reaction pathways provide DIC with isotopic enrichment that may be directly related to mineral saturation, and oxidation of reduced sulfur is possible for dissolution. DOC is derived from C3 vegetation with an average δ13CDOC of ‒27‰. DIC in groundwater is …
The Effects Of Evapotranspiration Upon Recharge Using The Stable Isotopes Of Oxygen And Hydrogen In The Carbonate Aquifers Of The Cumberland Plateau In Southeast Kentucky, Lee J. Florea
Lee J Florea, PhD, P.G.
In this brief manuscript, we consider the variation of the stable isotopes of oxygen, δ18O, and hydrogen, δ2H, in samples collected during 2010 and 2011 from precipitation and shallow groundwater along the Cumberland Plateau of southeast Kentucky. These data from the 1,900-ha Redmond Creek karst aquifer lend insight into the source and timing of recharge to shallow groundwater in the epigenic karst of the U.S midcontinent. Specifically, we find that only 43% of precipitation remains as potential recharge after accounting for evapotranspiration, and 85% of this potential recharge occurs during only four two-week sampling periods. The isotopic composition of precipitation …