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Isotopes Of Carbon In A Karst Aquifer Of The Cumberland Platea Of Kentucky , Usa, Lee J. Florea
Isotopes Of Carbon In A Karst Aquifer Of The Cumberland Platea Of Kentucky , Usa, Lee J. Florea
Lee J Florea, PhD, P.G.
In this study, the concentration and isotopic composition of dissolved organic carbon (DOC) and dissolved inorganic carbon (DIC) are measured in the karst groundwater of the Otter Creek watershed of the Cumberland Plateau of Kentucky, USA. Comparisons among these data and with the geochemistry of carbonate and gypsum equilibrium reactions reveal that DOC concentration is inversely related to discharge, multiple reaction pathways provide DIC with isotopic enrichment that may be directly related to mineral saturation, and oxidation of reduced sulfur is possible for dissolution. DOC is derived from C3 vegetation with an average δ13CDOC of ‒27‰. DIC in groundwater is …