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Use Of Carbonation For Treatment Of Coal Mine Drainage To Increase Limestone Dissolution And Generate Alkalinity, Dietrich Henry Kuhlmann Iv

Graduate Theses, Dissertations, and Problem Reports

Abstract

Use of Carbonation for Treatment of Coal Mine Drainage to Increase Limestone Dissolution and Generate Alkalinity

Dietrich Kuhlmann IV

Anoxic limestone drains (ALDs) are a common component used within passive treatment systems for coal mine drainage (CMD). Contact between limestone aggregate and CMD results in limestone dissolution, producing carbonate alkalinity. Though ALDs are one of the least expensive CMD treatment technologies, alkalinity generation is limited by limestone solubility. This necessitates a long retention time (>12 hours) and sometimes results in net acidic effluent which requires additional alkalinity generation steps downstream. One way to increase calcite dissolution and alkalinity …

Comparison Of Methods For Estimating Carbon Evasion And Export Associated With A Coal Mine Discharge, Kyle Lee, Dorothy J. Vesper

Presentations

The evasion of CO2 from terrestrial waters plays a role in the global cycling of carbon but there are few datasets that have an accurate accounting of the flux. It has been shown that discharges from coal mines can have elevated concentrations of CO2 due to sulfuric acid-driven dissolution of carbonate rock. In this study, we compared three methods for calculating the export dissolved inorganic carbon (DIC) and the evaluation of CO2 from an abandoned-mine discharge in West Virginia. In Method #1, the source flux is calculated from the discharge and the concentrations at the portal. In Method #2, the …

Quantifying The Contribution Of Solid Precipitates To The Total Alkalinity In A Coal-Mine Discharge, Lili Lei, Dorothy Vesper

Presentations

Flocculates and precipitates from coal mine drainage (CMD) are an integral part of the geochemical setting in mining-impacted streams. The precipitates may be very small, amorphous, and, depending on their chemistry, play a role in the storage and release of alkalinity. To evaluate the potential impact of CMD-solids on alkalinity, we conducted various tests using model and natural solids. Laboratory measurements of alkalinity are operationally defined by a titration to a fixed pH. When the solid-solution mixtures were tested using the standard alkalinity measurement method, no alkalinity could be detected; however, a possible reason for that was that the standard …