Geology Commons^™

Drivers Of Pb, Sb And As Release From Spent Gunshot In Wetlands: Enhancement By Organic Matter And Native Microorganisms, Anna Potysz, Łukasz J. Binkowski, Jakub Kierczak, Barnett A. Rattner

United States Geological Survey: Staff Publications

In many countries the use of lead-based ammunition is prevalent, and results in exposure and poisoning of waterfowl and other species of birds. In waterfowl hunting areas large quantities of spent shot may be deposited in wetland and terrestrial habitats. These pellets can undergo transformations, which are influenced by various abiotic and biotic factors. In addition to lead (Pb), other elements like antimony (Sb) and arsenic (As) can be leached from Pb shot into the environment. In vitro simulations that included organic matter and microorganisms were utilized to examine elemental leaching from gunshot. We found that leaching efficiency was the …

The Legacy Of Contamination By Lead Smelters In Missouri, Robert S. Armstrong

MSU Graduate Theses

Missouri has a rich history of lead mining. In the smelting process lead particles are emitted, which may be toxic to plants and animals. This study focuses on two primary lead smelters, Herculaneum and Glover, in Missouri. Smelting operations have ceased at these two sites, and unlike Herculaneum, Glover has no reported lead concentrations. Findings from air and sediments of these two sites were compared to background conditions and to each other. Thirty-three samples were collected from Herculaneum and Glover (thirty samples and three replicates) and eleven samples (ten samples and one replicate) for background. For Herculaneum sediment, lead levels …

The Legacy Of Mining In Southwest Missouri: Past And Present Conditions Of The Tri-State Mining District, Anastasia M C Mcclanahan

MSU Graduate Theses

The historic Tri-State Mining District (TSMD) of southwestern Missouri, southeastern Kansas, and northeastern Oklahoma has a history of lead and zinc mining that extended over a hundred years. During the district’s peak production period, the TSMD was one of the world’s largest producers of lead and zinc. The mining activities in the TSMD produced economic growth that supported the local communities and were essential to the victory of the Allied Forces during World War I and World War II. Beginning in the 1920s, the mining activities in the district slowly began to cease due to depletion of metal ores and …

Microscale Controls On Lead Speciation In Soils: A Framework For Sustainable Remediation, Grant Reeder

Graduate College Dissertations and Theses

The potential of a soil to immobilize heavy metal ions is dependent on the presence of adsorption sites, and the stability of metal species over the range of geochemical conditions present in the soil over time. Lead (Pb) is a cumulative toxin that is enriched in much of the urban pedosphere due to historical use of Pb-based paint and Pb-amended gasoline. Because in-situ remediation of Pb is possible if the bioavailable fraction can be rendered inert, understanding Pb-sorbent interactions is necessary to accurately and efficiently alter Pb speciation in soils. The objectives of this study are to 1) determine efficient …

Speciation, Distribution, Prediction, And Mobility Of Lead In Urban Soils: A Multiscale Study, Jennifer Bower

Graduate College Dissertations and Theses

Lead (Pb), a trace metal notorious for its impacts on human health, has achieved worldwide environmental dispersal resulting from centuries of use by human society. The toxicity of Pb is governed largely by its mineral form, which is in turn controlled by pH, localized reactivity and soil processes that differ according to soil type, location and Pb source. Given the context of these localized dependencies, or site specificity, efforts to predict Pb toxicity and refine sustainable remediation techniques are most useful when Pb behavior is constrained and predicted within environments with homogeneous conditions, such as a single soil. I evaluated …

Geochemical Analysis Of Surface Materials Surrounding The Bautsch-Gray Mine Superfund Site Near Galena, Illinois, Ryan Plath

Geology: Student Scholarship & Creative Works

The Bautsch-Gray zinc and lead mine, near Galena, IL, was in operation from the early 1900s until closing in 1975. The mine’s tailings pile has documented elevated lead and zinc concentrations in the surface materials surrounding the site. Numerous floods have caused contaminated sediment to migrate off the mine tailings pile, across Blackjack Road and into an outwash basin, and towards Smallpox Creek. Since this site was designated an EPA priority list Superfund site in 2010, the EPA has conducted numerous remediation efforts. This study attempts to develop a better understanding of the contamination within the soils of the outwash …

Molecular Level Characterization Of Diatom-Associated Biopolymers That Bind 234th, ²³³Pa, ²¹°Pb, And 7be In Seawater: A Case Study With Phaeodactylum Tricornutum, Chia-Ying Chuang, Peter H. Santschi, Chen Xu, Yuelu Jiang, Yi-Fang Ho, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

In order to investigate the importance of biogenic silica associated biopolymers on the scavenging of radionuclides, the diatom Phaeodactylum tricornutum was incubated together with the radionuclides Th-234, Pa-233, Pb-210, and Be-7 during their growth phase. Normalized affinity coefficients were determined for the radionuclides bound with different organic compound classes (i.e., proteins, total carbohydrates, uronic acids) in extracellular (nonattached and attached exopolymeric substances), intracellular (ethylene diamine tetraacetic acid and sodium dodecyl sulfate extractable), and frustule embedded biopolymeric fractions (BF). Results indicated that radionuclides were mostly concentrated in frustule BF. Among three measured organic components, Uronic acids showed the strongest affinities to …

Chemical Contaminants As Stratigraphic Markers For The Anthropocene, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Thousands and even millions of years from now, widespread anthropogenic contaminants in sediments would likely persist, incorporated into the geological record. They would inadvertently preserve evidence of our present era (informally designated as the Anthropocene Epoch) characterized by large human populations engaged in intensive industrial and agricultural activities.

Hypothetical geologists in the distant future would likely find unusually high concentrations of a wide variety of contaminants at stratigraphic levels corresponding to our present time, analogous to the iridium anomaly marking the bolide impact event at the close of the Cretaceous Period. These would include both organic and inorganic substances, such …

The Toll Of Toxics: Investigating Environmental Contaminants, Donald Sparling, Barnett A. Rattner, John S. Barclay

United States Geological Survey: Staff Publications

Two recent events [the Deepwater Horizon oil spill and the Asarco settlement] bring to the fore the work of wildlife toxicologists. Focusing on amphibians, reptiles, birds, and mammals, wildlife toxicology is a component of ecotoxicology--the study of toxic effects caused by natural or synthetic pollutants on living organisms and other constituents of ecosystems (Truhaut 1977). Now a distinct discipline within the wildlife profession-practiced by members of The Wildlife Society's own Wildlife Toxicology Working Group, among others-wildlife toxicology has become increasingly important as human populations and industry have spread, causing contaminants to multiply.

Emerging Environmental Contaminants (EECs) include an array of …

Inhibition Of Erythrocyte Δ- Aminolevulinic Acid Dehydratase (Alad) Activity In Fish From Waters Affects By Lead Smelters, Christopher J. Schmitt, Colleen A. Caldwell, Bill Olsen, Dave Serdar

United States Geological Survey: Staff Publications

We assessed the effects on fish of lead (Pb) released to streams by smelters located in Trail, BC (Canada), E. Helena, MT, Herculaneum, MO, and Glover, MO. Fish were collected by electrofishing from sites located downstream of smelters and from reference sites. Blood from each fish was analyzed for δ-aminolevulinic acid dehydratase (ALAD) activity and hemoglobin (Hb), and samples of blood, liver, or carcass were analyzed for Pb, zinc (Zn), or both. Fish collected downstream of all four smelters sites had elevated Pb concentrations, decreased ALAD activity, or both relative to their respective reference sites. At E. Helena, fish from …

The Migration Of Arsenic And Lead In Surface Sediments At Three Kids Mine Henderson, Nevada, Douglas Brian Sims

Publications (WR)

This study focused on the distribution of arsenic and lead in surface sediments at Three Kids Mine in Henderson, Nevada. The mine site encompasses approximately 470 acres of desert and is situated above two developing communities (Lake Las Vegas and Calico Ridge) and the Las Vegas Valley's water source (Lake Mead).

Transport of arsenic and lead appears to have occurred within a limited range in both the eastern and western washes on the eastern and western sides of Three Kids Mine. Concentrations of arsenic range between 20 mg/kg (ppm) and 1130 mg/kg and between 20 mg/kg and 8400 mg/kg for …