Earth Sciences Commons^™

Subaqueous Carbonate Speleothems As Paleotemperature Archives – Clumped Isotope Thermometry And Stable Isotope Compositions Of Inclusion-Hosted Water, Attila Demeny, Ágnes Berentés, László Rinyu, Ivett Kovács, Gergely Surányi, Magdolna Virág

International Journal of Speleology

Clumped isotope measurements of carbonates and stable isotope analyses of water trapped in fluid inclusions are both promising techniques to determine carbonate formation temperatures. Cave-hosted carbonate deposits (speleothems) are excellent targets for such studies, but kinetic fractionations and diagenetic influences frequently deteriorate the temperature data obtained from these methods. However, subaqueous carbonate deposits may provide reliable data, as kinetic fractionations are less significant in underwater environments. In this study, subaqueous speleothems, whose formation temperatures were directly measured in the water, were investigated. Additionally, temperatures calculated from the oxygen isotope fractionations between calcite and fluid inclusion-hosted water were compared with clumped …

Textural And Genetic Investigations Of Gold Mineralization In Fault-Controlled Quartzcarbonate Veins In Bayburt-Zarani Area (Eastern Pontides-Ne Turkey), Necati̇ Tüysüz, Gülten Yaylali Abanuz, Oğuzhan Gümrük, Bahri̇can Ar

Turkish Journal of Earth Sciences

The Eastern Pontides Orogenic Belt (EPOB), geographically corresponding to the northeastern part of Turkey hosts several different types of mineralizations that are closely related to Late Mesozoic-Early Cenozoic arc magmatism. Of these, Zarani gold mineralization, which is located in the southern part of the EPOB occurs as quartz-carbonate veins/veinlets within the Pulur metamorphic massif of Paleozoic age. Mineral textures indicate low-temperature vein-type mineralization. Gold mainly occurs in quartz and pyrite. The presence of calcite, dolomite, and sericite in the mineralization indicates near neutral pH conditions of ore-forming fluid. Geochemical analyses of chlorites in the quartz-carbonate veins reveal a temperature of …

Effect Of Coal Mining Subsidence Fractures On Source Of Water Absorption Of Artemisia Desertorum, Shang Jingxuan, Chen Shi, Liu Qianwen, Guo Xufeng, Guo Junting, Li Mi

Coal Geology & Exploration

Ground fissures caused by coal mining subsidence are not only a serious geological hazard, but also affect the growth and development of vegetation in the mining area and damage the mining ecosystem. To investigate the quantitative influence of coal mining subsidence fractures on the source of water uptaken by Artemisia Desertorum, the simulated precipitation tests of isotopically-labeled water were conducted in three test areas influenced by coal mining subsidence fractures to different degrees on 22312-working face of Huojitu mine field in Shendong mining area. The three test areas were divided according to the distance between Artemisia Desertorum and the fractures, …

Stable Carbon And Nitrogen Isotopes Of Shell Bound Organic Matter, Implications For Modern And Ancient Food Web Dynamics, Shibajyoti Das

Dissertations - ALL

Stable isotopes are an important tool for solving biogeochemical problems and have been increasingly applied in ecosystem studies because of their utility as source-to-sink tracers and for ecological information. Elements like C and N have more than one stable isotope, and their isotopic compositions (δ15N and δ13C) vary in a foreseeable way and are specifically useful in studying global elemental cycles and energy flow through ecosystems. δ15N and δ13C of organic matter (OM) are diagnostic of an organism's diet and have been used as a proxy for trophic level reconstructions. However, because of several analytical constraints, the use of stable …

Isotopic Study Of The Waters From The Sulphur Springs Catchment, Tampa, Florida, Esra Zengin

USF Tampa Graduate Theses and Dissertations

A stable isotope study was carried out using precipitation, spring water, groundwater well sample, and a seawater sample during the wet season in the Sulphur Springs watershed in Tampa, Florida. Studies that track long term isotopic variation over wet seasons are limited in the region. To fill this knowledge gap, this study aims to quantify the contributions of precipitation and diffuse sources to discharge in Sulphur Springs. A three-component mixing model was applied using δ18O and δ2H values to determine different source water contributions to spring water discharge. The three-component mixing model calculations suggest spring water consists mainly of diffuse …

Stable Isotope Analysis Of A Platecarpus Tympaniticus (Squamata, Mosasauridae) With Actinocamax Sternbergi (Mollsuca, Belemnoidea) Reveals Possible Endothermic Thermoregulation, Mitchell Lukens

Master's Theses

Mosasaurs, ancient marine reptiles, dominated the late Cretaceous oceans. However, their ecological success is a contentious topic. Were they ectothermic, like their modern relatives the varanid lizards? Or endothermic like extant marine mammals? Stable isotopes can reveal temperature and physiological variances within skeletons, but do not differentiate between body temperature and ambient environmental temperature. A rare mosasaur specimen from the Smoky Hill Chalk of a partial, articulated Platecarpus tympaniticus with stomach contents of belemnites provides a possible direct temperature contrast between predator and prey. The belemnites, related to modern coleoids, are identified as Actinocamax sternbergi. These animals possessed body …

Reconstructing Carbon Dynamics Of Alpine And Temperate Zone Lakes Using Stable Isotopic Analysis, Rebecca M. Doyle

Electronic Thesis and Dissertation Repository

Lake sediments integrate signals from the catchment, atmosphere and water column, offering a unique window through which to view changes in the carbon cycle. Carbon dynamics in lakes are changing due to nitrogen loading and anthropogenic climate warming (ACW), threatening the water quality of lakes. This thesis identifies how the carbon dynamics of lakes have responded to anthropogenically-driven forcings by comparing pre- and post- AD 1850 records preserved in lake sediments. First, the carbon dynamics of Barry Lake (Ontario, Canada), a low-elevation temperate lake, are investigated. Effective moisture (the net of water inputs and evaporation) is reconstructed using the carbon …

Determination Of The Origin And Recharge Process Of Water Resources In Salda Lake Basin By Using The Environmental, Tritium And Radiocarbon Isotopes (Burdur/Turkey), Simge Varol, Ayşen Davraz, Fatma Aksever, Şehnaz Şener, Erhan Şener, Bülent Kirkan, Ahmet Tokgözlü

Bulletin of the Mineral Research and Exploration

The Salda Lake basin which is in the southwestern Turkey is an important water body in view of environmental values. We used stable isotopes (δD and δ18O), δ3H and 14C composition of the water samples to understand recharge process effective in the groundwater and lake water. Water samples were collected in dry and wet periods and the stable isotope (δD and δ18O) and radiogenic isotope (14C) analysis were made in the basin. The δ18O contents of groundwater and lake water ranged from -9,94‰ to 1,18‰ in dry period and from -10,24‰ to 0,30‰, in wet period. δD contents of groundwater …

Isotopic And Geochemical Tracers Of Groundwater Flow In The Shivwits Plateau, Grand Canyon National Park, Jonathan W. Wilson

Theses and Dissertations--Earth and Environmental Sciences

As the impacts of global climate change on water resources continue to become more apparent, proper understanding and management of groundwater resources will be needed as supplies become more strained. Traditional methods of characterizing groundwater systems are time-intensive, costly, and can be difficult to complete in remote areas. Using ambient geochemical tracers from discrete sampling could aid in characterizing spring systems through determining flow paths, recharge areas, and carbon cycling. However, using discrete seasonal samples to understand the hydrogeology of complex, mixed-lithology aquifers has not been extensively examined. Here we explore using δ¹³C of dissolved organic carbon (DOC), …

Comparison Of Stable Isotope Values Of Quaternary Calcretes From Adana And Mersin Provinces: Implications On Controlling Factors, Muhsi̇n Eren, Meryem Yeşi̇lot Kaplan, Selahatti̇n Kadi̇r, Seli̇m Kapur

Turkish Journal of Earth Sciences

Calcretes are widespread in Adana and Mersin provinces and form under different morphologies. Most calcrete profiles comprise a hard laminated crust/hardpan at the top, gradually intergrading into the nodular and/or tubular/columnar horizon with depth. This study compares the δ18O and δ13C values of calcretes from both provinces and discusses the controlling factors and environmental conditions. The δ18O and δ13C values are characteristic for the pedogenic calcretes. The Adana calcrete mean δ18O values of the hardpan, nodules and tubes, and fractures-infills are 0.69‰, 0.77‰, and 1.04‰ PDB heavier than those of the Mersin calcretes,respectively. The overall difference between the two groups …

Evaluating Stable Isotope And Geochronologic Techniques For Paleoclimate Reconstruction: Case Study Of The Santa Cruz Formation, Argentina, Robin B. Trayler

Boise State University Theses and Dissertations

Stable isotope analysis has become the method of choice for many studies investigating the paleoecology and paleoclimate of fossil mammal faunas. While organic tissues (collagen, keratins, proteins) persist for < 10⁵ years highly mineralized tooth enamel is resistant to alteration and degradation and faithfully preserves its isotopic composition for millions (> 10⁶) years. Reconstructing past climates from these records relies on both understanding both micro-scale mechanisms of isotope incorporation into individual teeth, and macro-scale changes in isotope compositions over hundreds of thousands or millions of years. In this dissertation I address three questions.

First, how does the geometry and …

Holocene Climate Evolution Of Continental Western Eurasia Constrained By Stable-Isotope And Cation Geochemistry Of U-Th-Dated Speleothems And Meteogenic Travertine, Jonathan Lloyd Baker

UNLV Theses, Dissertations, Professional Papers, and Capstones

Reliable reconstructions of global and regional climate during the Holocene (11,700 years ago to present) are vital to constraining the natural range of climate variability and testing state-of-the-art models, which seek to forecast the near- and long-term impact of anthropogenic greenhouse forcing. Much of continental Eurasia is still underrepresented, however, in geological proxy reconstructions of Holocene climate variability, and the vast majority of paleoclimate data only reflect conditions during peak summer months (JJA) or the growing season. The paucity of winter proxy data has therefore been cited as a possible explanation for the current mismatch between geological proxy-based and climate-model …

Groundwater-Surface Water Interaction In The Headwater Of The White River, Manistee National Forest, Michigan, Ziqian Li

Masters Theses

Groundwater is a significant fresh water source in most areas and can be affected by potential changes to climate and precipitation from anthropogenic influences. Considering groundwater and surface water can be regarded as one hydrologic system, it is significant to understand the dynamics between precipitation, shallow groundwater and surface water in order to manage these resources.

Water samples were collected roughly biweekly from July 2016 to June 2017, and analyzed for electrical conductivity and stable isotopes of oxygen and hydrogen. During sample collection site visits, stream discharge and the groundwater heads from different wells were measured.

The stable isotopes of …

Cave Monitoring In The Béke And Baradla Caves (Northeastern Hungary): Implications For The Conditions For The Formation Cave Carbonates, György Czuppon, Attila Demény, Szabolcs Leél-Őssy, Mihály Óvari, Mihály Molnár, József Stieber, Klaudia Kiss, Krisztina Kármán, Gergely Surányi, László Haszpra

International Journal of Speleology

In order to use speleothems in the reconstruction of past climate and environmental changes it is necessary to understand the environmental and hydrological processes that determine the physico-chemical conditions of carbonate precipitation and hence speleothem formation. Therefore, in this study an extended monitoring program was conducted in the Béke and Baradla caves located in the Aggtelek region (Northeastern Hungary). The studied caves are rich in speleothem and flowstone occurrences with great potential for paleoclimatology studies. The monitoring activity included measurements of atmospheric and cave temperatures, CO₂ concentration in cave air, as well as chemical and isotopic compositions of water …

Reexamination Of Ore-Forming Processes In The Emery Mining District, Powell Co., Montana, Jarred Zimmerman

Graduate Theses & Non-Theses

The present investigation was undertaken in collaboration with the Montana Bureau of Mines and Geology to re-evaluate the Emery district using modern methods of ore deposit study including fluid inclusions, stable isotopes, and mineral geochemistry. Results from this thesis will be an aid in reassessing the potential of the Boulder Batholith and surrounding geologic units to host large, undiscovered precious and/or base metal deposits. The Emery (aka Zosell) district was mined from the late 1800s until the early 1950s. Mineralized quartz veins are hosted by basaltic andesite flows of the late Cretaceous Elkhorn Mountain Volcanics (EMV). Two sets of veins …

Isotopic Evidence For Lateral Flow And Diffusive Transport, But Not Sublimation, In A Sloped Seasonal Snowpack, Idaho, Usa, Samantha L. Evans, Alejandro N. Flores, Achim Heilig, Matthew J. Kohn, Hans-Peter Marshall, James P. Mcnamara

Geosciences Faculty Publications and Presentations

Oxygen and hydrogen isotopes in snow were measured in weekly profiles during the growth and decline of a sloped subalpine snowpack, southern Idaho, 2011–2012. Isotopic steps (10‰, δ¹⁸O; 80‰, δD) were preserved relative to physical markers throughout the season, albeit with some diffusive smoothing. Melting stripped off upper layers without shifting isotopes within the snowpack. Meltwater is in isotopic equilibrium with snow at the top but not with snow at each respective collection height. Transport of meltwater occurred primarily along pipes and lateral flow paths allowing the snowpack to melt initially in reverse stratigraphic order. Isotope diffusivities are …

Stable Isotopes Of Hydrothermal Carbonate Minerals In The Butte Porphyry-Lode Deposits, Montana, Ryan Stevenson

Graduate Theses & Non-Theses

The stable isotopic compositions of over 90 hydrothermal carbonate minerals in the Butte porphyry-lode system were analyzed. These samples came from the underground workings as well as the active Continental Pit area. Most material came from polymetallic “Main Stage” veins which post-date the porphyry Cu-Mo mineralization of Butte. Some samples from late calcite-stellerite veins were also included in the study. Rhodochrosite d¹³C and d¹⁸O values range from -8.3 to -2.9‰ (average of -6.7±1.0‰) and -1.8 to 12.8‰ (average of 3.6 ±3.4‰) respectively, while calcite d¹³C and d¹⁸O values range from -9.0 to …

The Speleogenesis Of Vallgornera Cave (Mallorca, Spain): A Mineralogical And Morphological Study, Jacqueline Amelia Diehl

USF Tampa Graduate Theses and Dissertations

Cova des Pas de Vallgornera (CPV) is morphologically and scientifically, the most prominent karst feature of Mallorca Island (Spain). It consists of over 74 km of passages developed within two carbonate lithologies (reef front and back reef facies) of Upper Miocene age. Two distinct cave patterns are recognized, both tightly controlled by the type of facies; spongework mazes and collapse chambers are characteristic for the reef front unit, whereas linear, fracture-guided galleries develop in the back reef carbonates. CPV is abundantly decorated with a variety of speleothems.

The overarching goal of this study is to provide evidence towards the cave's …

Eocene-Oligocene Latitudinal Climate Gradients In North America Inferred From Stable Isotope Ratios In Perissodactyl Tooth Enamel, Alessandro Zanazzi, Emily Judd, Andrew Fletcher, Harold Bryant, Matthew J. Kohn

Geosciences Faculty Publications and Presentations

The Eocene-Oligocene transition (~ 34 Ma) was one of the most pronounced episodes of climate change of the Cenozoic. In order to investigate this episode of global climate cooling in North America, we analyzed the carbon and oxygen stable isotope composition of the carbonate component of 19 perissodactyl (horse and rhino) tooth enamel samples from the Eocene-Oligocene rocks of the Cypress Hills Formation (southwestern Saskatchewan, Canada); we then compared the results with previously published data from the US Great Plains (Nebraska, South Dakota, and Wyoming).

Average (± 1σ) perissodactyl enamel δ¹³C values (vs. V-PDB) in the Eocene (-8.8 …

Linking Mineral Deposits To Speleogenetic Processes In Cova Des Pas De Vallgornera (Mallorca, Spain), Bogdan P. Onac, Joan J. Fornós, Antoni Merino, Joaquín Ginés, Jacqueline Diehl

International Journal of Speleology

Cova des Pas de Vallgornera (CPV) is the premier cave of the Balearic Archipelago. Over 74 km of passages develop within two carbonate lithofacies (reef front and back reef), which ultimately control the patterns of the cave and to some degree its mineral infilling. The diversity of speleothem-forming minerals is four times greater around or within hypogene-related features (vents, rims, cupolas), compared to any other vadose passages in the cave. The mineralogy of speleothems (crusts, nodules, crystals, earthy masses) associated with hypogene features in the seaward upper maze of Sector F is characterized by the presence of aragonite, ankerite, huntite, …

Paleoecology Of Late Pleistocene Megaherbivores: Stable Isotope Reconstruction Of Environment, Climate, And Response, Aubrey Mae Bonde

UNLV Theses, Dissertations, Professional Papers, and Capstones

Late Pleistocene megaherbivore communities of the Pacific and Mountain West states of California and Nevada are under-analyzed in regard to ecological function (diet, mobility, niche partitioning, and range of ecological tolerance). Stable isotope analysis is a powerful tool that is known to recover primary paleodiet and paleoenvironmental information from biogenic materials, such as enamel and dentin. This dissertation explores the use of carbon and oxygen stable isotopes in Late Pleistocene (40-10 Ka) megaherbivore teeth to gain a better understanding of inter- and intra-specific behavior and reconstruct Late Pleistocene ecosystems of California and Nevada. Radiocarbon dates exist for most of the …

Stories Of The Proterozoic Earth: Paleoproterozoic Chuanlinggou Arcitarchs And Neoproterozoic ¹⁷O-Depleted Barite, Yongbo Peng

LSU Doctoral Dissertations

This dissertation consists of two independent topics, both critical to understanding Earth history during the Proterozoic Eon. (1) Paleoproterozoic Chuanlinggou Acritarchs: The eukaryotic affinity of acritarchs from the Chuanlinggou Formation has been questioned because of lack of indisputable morphological evidence. In this study, Chuanlinggou acritarchs were examined by jointly using optical microscopy, scanning electron microscopy, and transmission electron microscopy. In most cases, an ovoidal group of acritarchs represents a half-vesicle following a complete longitudinal rupture, which is a morphological model different from a whole envelope with medial splits, as proposed by earlier studies. This ovoidal group displays a bipolar morphology, …

Radiocarbon Evidence For The Importance Of Surface Vegetation On Fermentation And Methanogenesis In Contrasting Types Of Boreal Peatlands, J. P. Chanton, P. H. Glaser, L. S. Chasar, David J. Burdige, M. E. Hines, D. I. Seigel, L. B. Tremblay, W. T. Cooper

OES Faculty Publications

We found a consistent distribution pattern for radiocarbon in dissolved organic carbon (DOC), dissolved inorganic carbon (DIC), and methane replicated across spatial and temporal scales in northern peatlands from Minnesota to Alaska. The ¹⁴C content of DOC is relatively modern throughout the peat column, to depths of 3 m. In sedge-dominated peatlands, the ¹⁴C contents of the products of respiration, CH₄ and DIC, are essentially the same and are similar to that of DOC. In Sphagnum- and woody plant-dominated peatlands with few sedges, however, the respiration products are similar but intermediate between the ¹⁴C contents of …

Evaluation Of Paleo-Climate For The Boise Area, Idaho, From The Last Glacial Maximum To The Present Based On Delta 2h And Delta 18o Groundwater Composition, Melissa Eileen Schlegel

Theses and Dissertations

There are four distinguishable groundwater systems in the Boise area, Idaho, U.S.A., identified as modern batholith, thermal batholith, Boise frontal fault, and Nampa-Caldwell systems (Figure 1). Modern batholith and thermal batholith groundwaters are located in Tertiary to Cretaceous aged granites and granodiorites of the Atlanta lobe of the Idaho Batholith. The frontal fault system near Boise, ID defines the southeastern edge of the Idaho Batholith, and divides the batholith from the western Snake River Plain. The Nampa-Caldwell system is in the volcanic, fluvial and pluvial sediments of the western Snake River Plain. Groundwater ages for these systems are modern, 5-15 …