Earth Sciences Commons^™

Unraveling Sources Of Cyanate In The Marine Environment: Insights From Cyanate Distributions And Production During The Photochemical Degradation Of Dissolved Organic Matter, Rui Wang, Jihua Liu, Yongle Xu, Li Liu, Kenneth Mopper

Chemistry & Biochemistry Faculty Publications

Cyanate is a nitrogen and energy source for diverse marine microorganisms, playing important roles in the nitrogen cycle. Despite the extensive research on cyanate utilization, the sources of this nitrogen compound remain largely enigmatic. To unravel the sources of cyanate, distributions and production of cyanate during photochemical degradation of natural dissolved organic matter (DOM) were investigated across various environments, including freshwater, estuarine, coastal areas in Florida, and the continental and slope regions of the North American mid-Atlantic Ocean (NATL). Cyanate production was also examined during the photochemical degradation of exudates from a typical strain of Synechococcus, an important phytoplankton …

Phosphorus Dynamics In Calcareous Soils Amended With Organic Matter, Logan Banner

All Graduate Reports and Creative Projects, Fall 2023 to Present

Phosphorus (P) is considered immobile in calcareous soils. Organic matter is known to enhance P mobility in these soils. Few studies have considered what role iron oxides might play in P sorption in calcareous soils, especially in the presence of soluble organic matter. This study investigated P sorption dynamics in sand-based, simulated soil systems in the absence or presence of 5 mM carbon (C) as humic acid (HA). Treatments included combinations of dicalcium phosphate dihydrate (DCPD), calcite, and ferrihydrite. Solutions containing 10 mg P L^-1 in a background of 0.01 M CaCl₂were equilibrated with each solid treatment …

Labile Dissolved Nickel (Ni) Concentrations In The North Pacific, Calyn M. Crawford

USF Tampa Graduate Theses and Dissertations

Nickel (Ni) is an important micronutrient for phytoplankton and bacteria that serves as a required co-factor in several metalloenzymes. Despite these known biological uses, total dissolved Ni concentrations remain elevated in global surface waters, in contrast to the surface depletion commonly observed for macronutrients and other nutrient-type trace elements. A prevailing hypothesis for the muted depletion of dissolved Ni concentrations in surface waters is that dissolved Ni in seawater is not in a bioavailable form. The chemical lability of Ni in seawater provides insight into Ni speciation and bioavailability, but few measurements have been made in the open ocean to …

Spatial Variation Characteristics Of Soil Heavy Metal Speciation And Bioavailability In Coal Gangue Accumulation Area—Taking Fengfeng Mining Area As An Example, Sun Tao, Song Shijie, Chang Qing, Wang Chenchen, Zhang Yanjie, Peng Ruisi, Wang Yi

Coal Geology & Exploration

The surface accumulation of coal gangue is a typical form of ecological environment destruction in the eastern coal mining area of China, and the prevention and control of heavy metal pollution in the soil in the accumulation area has become a hot spot in the current research. Taking the shallow soil (with a vertical depth of 40 cm and below) around a coal gangue mountain (within a radius of 300 m) in use in the Fengfeng mining area of Hebei as the research object, the active state, iron manganese oxidation state, organic state and residue state of four kinds of …

Particulate And Dissolved Organic Matter In Stormwater Runoff Influences Oxygen Demand In Urbanized Headwater Catchments, Kelly M. Mccabe, Erik M. Smith, Susan Q. Lang, Claudia Benitez-Nelson

Faculty Publications

Increasing inputs of organic matter (OM) are driving declining dissolved oxygen (DO) concentrations in coastal ecosystems worldwide. The quantity, source, and composition of OM transported to coastal ecosystems via stormwater runoff have been altered by land use changes associated with urbanization and subsequent hydrologic flows that accompany urban stormwater management. To elucidate the role of stormwater in the decline of coastal DO, rain event sampling of biochemical oxygen demand (BOD) in samples collected from the outfall of stormwater ponds and wetlands, as well as samples of largely untreated runoff carried by stormwater ditches, was conducted across a range of urban …

A Process-Based Approach To Evaluating The Role Of Organic Ligands In Trace Metal Cycling In The Marine Environment, Travis Mellett

USF Tampa Graduate Theses and Dissertations

In addition to control by major nutrient elements (nitrogen, phosphorous, and silicon) growth and community composition of marine phytoplankton is also regulated by trace element nutrients (iron, copper, manganese, zinc, cobalt, nickel, and cadmium). Of these, iron is the most influential in the modern ocean, regulating phytoplankton growth and carbon export in high-nutrient low-chlorophyll regimes and exerting an important control on the marine nitrogen cycle through its role in di-nitrogen fixation. The distributions of these metals has the capacity to control primary production and phytoplankton community composition through differences in cellular quotas or metal sensitivities amongst species. The relationship between …

Determining Geological Controls On Nutrient Availability At Different Depths In The Soils Of The Pelee Island Winery, Lindsay M. Blythe

Electronic Thesis and Dissertation Repository

Terroir describes a sense of place that can give a unique flavour to wines grown in different environments. We explored the role of soil in the terroir at Canada’s most southern vineyard, Pelee Island Winery. This study examined the abundance of major nutrients, trace and rare earth elements of minerals and plant extractable nutrients from 19 soils across the vineyard to a depth of 2 m. We found that bedrock does not influence the element content of Pelee Island soils, the parent materials of the soils are tills and there are geochemical, mineralogical and grain size differences between the two …

The Effects Of Legacy Sulphur Deposition On Methylmercury Production In Northern Peatlands; Geochemical And Biological Considerations, Jennifer L. Blythe

Electronic Thesis and Dissertation Repository

Mercury is a ubiquitous element with a complex geochemical cycle. Aquatic ecosystems such as wetland soils convert inorganic mercury to organic, neurotoxic methylmercury though the activity of sulphate-reducing bacteria (SRB). Sulphate stimulates the activity of SRB, and the production of methylmercury in these environments. My aim was to investigate the effect that legacy sulphate has on Hg methylation in northern peatlands through a laboratory sulphate addition experiment with differentially sulphate-exposed peats and a field study of peatlands subjected to different levels of sulphate. Results from the laboratory study indicate that peatlands in regions of higher atmospheric sulphate deposition show enhanced …

Understanding The Bioavailability Of Pyrethroids In The Aquatic Environment Using Chemical Approaches, Zhijiang Lu, Jay Gan, Xinyi Cui, Laura Delgado-Moreno, Kunde Lin

Environmental Science and Geology Faculty Research Publications

Pyrethroids are a class of commonly used insecticides and are ubiquitous in the aquatic environment in various regions. Aquatic toxicity of pyrethroids was often overestimated when using conventional bulk chemical concentrations because of their strong hydrophobicity. Over the last two decades, bioavailability has been recognized and applied to refine the assessment of ecotoxicological effects of pyrethroids. This review focuses on recent advances in the bioavailability of pyrethroids, specifically in the aquatic environment. We summarize the development of passive sampling and Tenax extraction methods for assessing the bioavailability of pyrethroids. Factors affecting the bioavailability of pyrethroids, including physicochemical properties of pyrethroids, …

Microscale Controls On Lead Speciation In Soils: A Framework For Sustainable Remediation, Grant Reeder

Graduate College Dissertations and Theses

The potential of a soil to immobilize heavy metal ions is dependent on the presence of adsorption sites, and the stability of metal species over the range of geochemical conditions present in the soil over time. Lead (Pb) is a cumulative toxin that is enriched in much of the urban pedosphere due to historical use of Pb-based paint and Pb-amended gasoline. Because in-situ remediation of Pb is possible if the bioavailable fraction can be rendered inert, understanding Pb-sorbent interactions is necessary to accurately and efficiently alter Pb speciation in soils. The objectives of this study are to 1) determine efficient …

Marsh-Exported Dissolved Organic Matter Fate In Estuaries, Laura Ann Logozzo

Dissertations and Theses

Dissolved organic matter (DOM) is a significant driver of estuarine productivity and nutrient cycling. The colored component of DOM, chromophoric dissolved organic matter (CDOM), impacts coastal optical properties, ocean color, and light attenuation. While marshes are largely considered sinks for carbon due to their high productivity and low soil carbon degradation rates, laterally they are sources of carbon as optically and chemically distinct DOM to surrounding aquatic ecosystems; these inputs are often essential in sustaining a net heterotrophic system. However, the photoreactivity and bioavailability of marsh-exported DOM is largely uncategorized, thus making it difficult to quantify its impacts on estuarine …

Optical Properties And Bioavailability Of Dissolved Organic Matter Along A Flow-Path Continuum From Soil Pore Waters To The Kolyma River Mainstem, East Siberia, Karen E. Frey, William V. Sobczak, Paul J. Mann, Robert M. Holmes

Geography

The Kolyma River in northeast Siberia is among the six largest Arctic rivers and drains a region underlain by vast deposits of Holocene-aged peat and Pleistocene-aged loess known as yedoma, most of which is currently stored in ice-rich permafrost throughout the region. These peat and yedoma deposits are important sources of dissolved organic matter (DOM) to inland waters that in turn play a significant role in the transport and ultimate remineralization of organic carbon to CO2 and CH4 along the terrestrial flow-path continuum. The turnover and fate of terrigenous DOM during offshore transport largely depends upon the composition and amount …

Chapter Two: Chromium Contamination And Its Risk Assessment In Complex Environmental Settings, Girish Choppala, Nanthi Bolan, Jin Hee Park

Dr Girish Choppala

Chromium reaches the soil environment through waste disposal emanating from a number of industrial activities, including coal-fired power production, electroplating, leather tanning, timber treatment, pulp production, and mineral ore and petroleum refining. Of the heavy metals, chromium (Cr) is a major pollutant, poses a great threat to flora and fauna and persists for long time. The most abundant species of Cr—Cr(III) and Cr(VI)—have very different properties. The toxicity, mobility, and bioavailability of Cr mainly depend on its speciation. In the natural environment, Cr(III) is most immobile, less soluble and stable, whereas Cr(VI) is highly mobile, soluble and bioavailable. Redox reactions …

Differential Effect Of Coal Combustion Products On The Bioavailability Of Phosphorus Between Inorganic And Organic Nutrient Sources, Belaji Seshadri, Nanthi Bolan, Girish Choppala, Ravi Naidu

Dr Girish Choppala

In farming systems, all the applied phosphorus (P) is not available to plants because they are either adsorbed in soil or lost to the environment through leaching or runoff. The effect of coal combustion products (CCPs) for enhancing the bioavailability of applied phosphorus (P) in soil was examined separately for inorganic (KH₂PO₄ – PP) and organic (poultry manure – PM) P treatments, where fluidised bed combustion (FBC) ash emerged as the most effective amendment. Greenhouse study was conducted by growing mustard plants on FBC amended soils under leaching and non-leaching setups. The FBC increased the biomass yield …

Chemodynamics Of Chromium Reduction In Soils: Implications To Bioavailability, Girish Choppala, Nanthi Bolan, Belaji Seshadri

Dr Girish Choppala

Chromium toxicity in soils can be mitigated by reduction of Cr(VI) to Cr(III) which is influenced by the presence of free Cr(VI) species in soil solution, and the supply of protons and electrons. In this study, the effects of Cr(VI) adsorption (i.e. availability of free Cr(VI) species in soil solution), soil pH (i.e. supply of protons) and three electron donor carbon sources [black carbon (BC), chicken manure biochar (CMB) and cow manure (CM)] on the reduction of Cr(VI) to Cr(III) in soils were investigated. The results indicated that the rate of Cr(VI) reduction decreased with an increase in Cr(VI) adsorption …

Use Of Esi-Fticr-Ms To Characterize Dissolved Organic Matter In Headwater Streams Draining Forest-Dominated And Pasture-Dominated Watersheds, Yuehan Lu, Xiaping Li, Rajaa Mesfioui, James E. Bauer, R. M. Chambers, Elizabeth A. Canuel, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR-MS) has proven to be a powerful technique revealing complexity and diversity of natural DOM molecules, but its application to DOM analysis in grazing-impacted agricultural systems remains scarce. In the present study, we presented a case study of using ESI-FTICR-MS in analyzing DOM from four headwater streams draining forest-or pasture-dominated watersheds in Virginia, USA. In all samples, most formulas were CHO compounds (71.8-87.9%), with other molecular series (CHOS, CHON, CHONS, and CHOP (N, S)) accounting for only minor fractions. All samples were dominated by molecules falling in the lignin-like region (H/C …

Bioavailability/Toxicity Of Iron From Aerobically Processed Organic Fertilizer, Stacey Marie Wilson

Undergraduate Honors Capstone Projects

For an undergraduate Honor's project, I worked under the direction of Dr. Jeffery Hall to determine the bioavailability and toxicity of iron from Milorganite® fertilizer, an aerobically processed organic fertilizer. The Milorganite® Company is a subsidiary of the Milwaukee Municipal Sewage District and produces a fertilizer of high iron content (approximately 5-7%). The high iron content has resulted in concern about the toxic potential, which until now was unknown. This thesis paper will explain iron chemistry, bioavailability, requirements, absorption, toxicity, and treatments, followed by a description of fertilizer types and contents. This will be followed by a description and reasoning …

The Efficacy Of Plant Residue Degradation Products On Phosphorus, Iron, Iodine, And Fluorine Bioavailability To Plants, Cheryl L. Mackowiak

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Plant and animal wastes degrade in soils to form relatively stable humified compounds, which form ion complexes that affect the bioavailability of elements in the soil solution. Hydroponic studies with wheat and rice were conducted to characterize the effect of humic acid (HA) on phosphorus (P), iron (Fe), fluorine (F), and iodine (I) bioavailability. Ferrihydrite [Fe(OH)₃] precipitation was greater on root surfaces without HA or synthetic chelates. Oxides such as ferrihydrite strongly adsorb P and provide exchange sites for metals. HA reduced this precipitate and increased P and Fe uptake.

Humic acid had no effect on F toxicity …

Classification Of Explosives Transformation Products In Plant Tissue, Steven L. Larson, Robert P. Jones, Lynn Escalon, Don Parker

US Army Corps of Engineers

Explosives contamination in surface or groundwater used for the irrigation of food crops and phytoremediation of explosives-contaminated soil or water using plant-assisted biodegradation have brought about concerns as to the fate of explosives in plants. Liquid scintillation counting, high-performance liquid chromatography, and gel permeation chromatography were utilized to characterize explosives (hexahydro-1,3,5-trinitro-1,3,5-triazine and trinitrotoluene) and their metabolites in plant tissues obtained from three separate studies. Analyzing tissues of yellow nutsedge (Cyperus esculentus), corn (Zea mays), lettuce (Lacuta sativa), tomato (Lyopersicum esculentum), radish (Raphanus sativus), and parrot feather (Myriophyllum aquaticum) …