Earth Sciences Commons^™

Transport Mechanism Of Ammonia Nitrogen In The Simulated Gob Area Packed With Coal Gangue, Li Yusong, Lu Yucan, Cao Qiong, Zhao Li, Zhu Kaipeng, Zhang Qing, Yu Hongfei, Zhang Lei

Coal Geology & Exploration

In many coal mining areas in western China, waste water produced during coal mining is often dominant in mine water, resulting in high ammonia nitrogen content. The pretreatment of mine water by filling gangue in coal mine gob areas has become an important measure for the resource utilization of mine water and gangue. The research took the coal gangue from Baode Coal Mine of Shenhua Shendong Coal Group Corporation as the filling medium and the ammonia nitrogen in mine water as the research object. Based on CXTFIT2.1, column simulation experiments were carried out to study the migration mechanism of ammonia …

Effects Of Biochar Production Methods And Biomass Types On Lead Removal From Aqueous Solution, Paola Granados, Sergio Mireles, Engil Isadora Pujol Pereira, Chu-Lin Cheng, James Jihoon Kang

School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations

Biochar has proven its potential in removing heavy metal ions from water. The objective of this study was to evaluate locally obtained biomass feedstocks for biochar production and their efficiency as a sorbent for aqueous lead (Pb²⁺) removal. The biomass feedstocks consisted of avocado seed, avocado peel, grapefruit peel, and brown seaweed, which represent agricultural and marine biomasses. The biochar materials were produced in two different methods: (1) a laboratory tube furnace at 300 °C and (2) a Do-It-Yourself (DIY) biochar maker, “BioCharlie Log”. The biochars were characterized for selected physicochemical properties, and batch adsorption tests with 10 …

Develop A Multi-Functional Green Pervious Concrete (Mgpc) Pavement With Polycyclic Aromatic Hydrocarbons (Pahs) Removal Function., Hong Shang

Electronic Theses and Dissertations

Stormwater runoff induced Polycyclic Aromatic Hydrocarbons (PAHs) contaminant increasingly imperils the groundwater quality and the sustainable development of human society due to the potential carcinogenic risks. Pavement can be considered as the first line of defense for contaminant removal of the stormwater runoff. New construction materials with stormwater runoff quantity and quality control are in urgent demand for updating the existing pavement system. An innovative material called Multi-functional Green Pervious Concrete (MGPC) was developed in the department of Civil and Environmental Engineering at University of Louisville. This material uses organoclay as the amendment to enhance the PAHs removal capacity of …

Biochar Applications To The Remediation Of Lead And Polychlorinated Biphenyl Contaminated Water, Victory Itua Igberase

Theses and Dissertations

This study investigated the performance of biochar materials as adsorbents to remove Pb and polychlorinated biphenyl (PCB) in aqueous solutions. Batch adsorption and column experiment packed with biochar and geomaterials (pumice) in 1:1 volume ratio was evaluated to address the efficacy of biochar in removing Pb while only batch adsorption was employed for PCB removal with biochar materials. Overall, PT biochars performed the best (42–53 mg g−1) followed by BE biochars (10–32 mg g−1) and AB biochars (17–27 mg g−1) while high temperature biochars were favored in terms of maximum Pb adsorption capacity. Column Pb breakthrough showed similar results, with …

Cr (Iii)-Doped Bentonite: Synthesis, Characterization And Application For Phenol Removal, Widia Purwaningrum, Vilantina Vilantina, Widya Twiny Rizki, Desnelli Desnelli, Poedji Loekitowati Hariani, Muhammad Said

Makara Journal of Science

Study of doping process of metal oxide Cr(III) onto bentonite for phenol removal has been done. The purpose of this study was to increase the capacity and effectiveness of bentonite adsorption.The doped bentonite was characterized using XRD, SEM-EDX and FT-IR spectrophotometer analysis. XRD characterization result showed an angle shift (2θ) characteristic at1.609°. The SEM-EDX characterization result showed that bentonite as control have a more gaps than Cr(III)-doped bentonite. Based on EDX result, the Al element decreased from 7.53% to 3.76%, Si from 19.84% to 10.23% and appeared Cr element 2.06%, The FT-IR characterization result showed no significant friction in the …

Antimony (V) Adsorption At The Hematite–Water Interface: A Macroscopic And In Situ Atr-Ftir Study, Jerzy Mierzwa, Rose Mumbi, Avedananda Ray, Sudipta Rakshit, Michael E. Essington, Dibyendu Sarkar

Agricultural and Environmental Sciences Faculty Research

The environmental mobility of antimony (Sb) is largely unexplored in geochemical environments. Iron oxide minerals are considered major sinks for Sb. Among the different oxidation states of Sb, (+) V is found more commonly in a wide redox range. Despite many adsorption studies of Sb (V) with various iron oxide minerals, detailed research on the adsorption mechanism of Sb (V) on hematite using macroscopic, spectroscopic, and surface complexation modeling is rare. Thus, the main objective of our study is to evaluate the surface complexation mechanism of Sb (V) on hematite under a range of solution properties using macroscopic, in situ …

Lithium Extraction From Geothermal Waters; A Case Study Of Ömer-Gecek(Afyonkarahisar) Geothermal Area, Muhammed Fati̇h Can, Can Başaran, Ahmet Yildiz, Müfi̇t Demi̇rkapi

Turkish Journal of Earth Sciences

Lithium (Li) is the lightest metal, has unique physicochemical properties and is the main component of lithium-ion batteries. Rechargeable lithium-ion batteries play a very important role in maximizing the performance of electric devices and vehicles. It is predicted that the metal and mineral demand for lithium-ion batteries will increase 56 times by 2050. In order to meet the increasing demand, in addition to known methods, lithium recovery from geothermal waters has become a very popular research subject. There are abundant geothermal water resources in the world, especially in Turkey and in Afyonkarahisar. The aim of this study is to produce …

Boron Adsorption In Clay Minerals: Implications For Martian Groundwater Chemistry And Prebiotic Processes, Matthew A. Nellessen, Laura Crossey, Patrick J. Gasda, Horton Newsom, Abdulmehdi Ali, Eric J. Peterson, Nina Lanza, Adriana Reyes-Newell, Dorothea Delapp, Chris Yeager, Andrea Labouriau, Roger C. Wiens, Samuel Clegg, Shelbie Legett, Debarati Das

Earth and Planetary Sciences ETDs

Boron has been detected on Mars [Gasda et al., 2017, Das et al., 2019, 2020] within calciumsulfate veins found within clay-rich rocks on Mars by the Mars Science Laboratory (MSL) rover using Laser Induced Breakdown Spectroscopy (LIBS) analysis. Boron plays a vital role in stabilizing ribose on Earth and has been suggested as a key requirement for life [Scorei et al., 2006, 2012; Furukawa et al., 2013, 2017; Becker et al., 2019]. Additionally, boron readily adsorbs to phyllosilicate clay minerals and is often associated with biologic processes in clay soils. The discovery of boron on Mars in proximity to phyllosilicate …

Removal Of Pb2+ And Cd2+ From Aqueous Solutions Using Pocl3 Cross-Linked Carboxymethyl Derivatives Of Legume Starch, Ayodele Akinterinwa, Ebun Oladele, Albert Adebayo, Olubode Ajayi

Makara Journal of Science

Starch was extracted from Kwakil beans and cross-linked with POCl₃ (1% v/w of starch dry basis [db]). The cross-linked starch (PCS) derivative was carboxymethylated with sodium monochloroacetate (5% to 30% w/w of starch db) to obtain cross-linked carboxymethyl starch (PCCS) derivatives. The derivatives were used in the adsorption of Pb²⁺ and Cd²⁺, and the process was monitored using atomic adsorption spectrometer. Carboxymethylation enhanced adsorption of ions (Cd²⁺, 95% to 96%; Pb, 65% to 94%), and it was more appreciable with Pb²⁺ than Cd²⁺ as degree of substitution increased from 0.008 to 0.052. …

Sand And Pumice Filter Amended With Activated Carbon And Biochar For Phosphorus Retention, James Jihoon Kang, Marissa Davila, Sergio Mireles, Jungseok Ho

School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations

Phosphorus (P) loss via stormwater runoff is a water quality concern. The objective of this study was to investigate two commercial biochars relative to an activated carbon as an additive to geomedia (sand and pumice) for P removal. The batch adsorption experiment was conducted to assess P sorption of the geomedia and carbon materials while the leaching experiment was conducted in sand and pumice columns amended with carbon materials (5 % by weight). The batch adsorption test revealed that only activated carbon showed an appreciable P adsorption up to 19 %. Tested biochar materials showed no adsorption capacity for P …

Water Treatment Residual-Coated Wood Mulch For Addressing Urban Stormwater Pollution, Hanieh Soleimanifar, Yang Deng, Kirk Barrett, Huan Feng, Xiaona Li, Dibyendu Sarkar

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Innovative treatment materials and technologies are demanded to address urban stormwater pollutants that challenge traditional infrastructure. This study aimed to investigate adsorption behaviors of aluminum-based water treatment residual (WTR)-coated mulch for capturing representative runoff pollutants (i.e., P, Cu, Zn, and Pb) and evaluate its treatment performance in a filtration bed. Data from batch studies were fit using the nonlinear least square optimization technique. Adsorption kinetic data followed the pseudo-2 nd -order reaction patterns, while the adsorption isotherm data obeyed the Freundlich models. Model fitting passed the chi-square tests, as a statistical goodness-of-fit criterion, at a 90% confidence level. Column studies …

Analysis Of Diffusion Properties Of Methane In Low Rank Coal, Meng Zhaoping, Zhang Guiyuan, Li Guoqing, Liu Jinrong

Coal Geology & Exploration

Diffusion properties of methane in coal is an important reservoir parameter affecting CBM production. Using the lignite samples from the Xiaolongtan Formation of the Miocene Neogene in southeastern Yunnan Province, the isothermal adsorption experiments of methane in low rank coal were carried out. Based on the relationship between adsorption amount and time obtained from isothermal adsorption experiment, the diffusion coefficient of methane in coal was calculated by using an unipore model of unsteady gas diffusion. The diffusion law of methane in coal and its control mechanism were revealed. The results show that gas diffusion law in coal obeys Langmuir equation; …

Adsorption Of Uv-Quenching Substances (Uvqs) From Landfill Leachate With Activated Carbon, Yang Deng, Chanil Jung, Renzun Zhao, Kevin Torrens, Laying Wu

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Co-treatment of landfill leachate with sewage at publicly owned treatment works (POTWs) is a common leachate management practice. However, the UV absorbing property of UV-quenching substances (UVQS) present in municipal landfill leachate may significantly reduce the efficiency of disinfection at POTWs that adopt ultraviolet irradiation for disinfection. The UVQS represents an emerging concern in the solid waste and wastewater treatment industries. This study aimed to evaluate the performance of activated carbon (AC) for removal of UVQS from landfill leachate in order to address the leachate UV-quenching issue. Results showed that the abatement of leachate UV254 absorbance with AC followed a …

The Impact Of Small Organic Acids On Iron And Manganese Mineral Transformations And The Fate Of Trace Metals, Elaine Denise Flynn

Arts & Sciences Electronic Theses and Dissertations

Iron and manganese oxides are ubiquitous in soils and sediments and play a critical role in the geochemical distribution of trace elements and heavy metals through adsorption and coprecipitation. At redox interfaces, biogeochemical processes generate conditions with coexisting dissolved Fe(II) and solid-phase Fe(III). In such systems, Fe(II) induces the recrystallization of iron oxides through coupled mineral growth and dissolution due to electron transfer as oxidative adsorption of Fe(II) and reductive dissolution of Fe(III) occur. Aqueous Mn(II) adsorption onto Mn(III/IV) oxides also likely involves oxidation although likely through different mechanisms than that of the Fe system because of the potential for …

Surface Oxygenation Of Biochar Through Ozonization For Dramatically Enhancing Cation Exchange Capacity, Matthew D. Huff, Sarah Marshall, Haitham A. Saeed, James Weifu Lee

Chemistry & Biochemistry Faculty Publications

Background

Biochar cation exchange capacity (CEC) is a key property that is central to biochar environmental applications including the retention of soil nutrients in soil amendment and removal of certain pollutants in water-filtration applications.

Results

This study reports an innovative biochar-ozonization process that dramatically increases the CEC value of biochars by a factor of 2. The ozonized biochars also show great improvement on adsorption of methylene blue by as much as a factor of about 5. In this study, biochar samples treated with and without ozone were analyzed by means of pH and CEC assays, water field capacity measurement, elemental …

Nitrate Leaching From Sand And Pumice Geomedia Amended With Pyrogenic Carbon Materials, Jihoon Kang, Marissa Davila, Sergio Mireles, Jungseok Ho

School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations

There is increasing interest in using pyrogenic carbon as an adsorbent for aqueous contaminants in stormwater. The objective of this study was to investigate pyrogenic carbon materials as an amendment to geomedia to reduce nitrate leaching. Batch adsorption and column experiments were conducted to evaluate the performance of a commercial activated carbon and two biochars incorporated (5% by weight) into sand and pumice columns. The batch adsorption with 50 mg L−1 of nitrate solution showed that only activated carbon resulted in a substantial adsorption for nitrate up to 41%. Tested biochars were not effective in removing aqueous nitrate and even …

Comprehensive Silica Removal With Ferric Compounds For Industrial Wastewater Reuse, Ehren D. Baca

Civil Engineering ETDs

Cooling towers, integrated circuit (IC) manufacture and reverse osmosis (RO) generate copious amounts of wastewater high in colloidal and reactive silica inhibiting on-site or synergistic reuse. Silica present in cooling water can reach solubility limits via evaporation and form impervious scale on heat transfer surfaces that decreases efficiency. When water is treated by RO operating at high rejection, silica forms difficult-to-remove scale on the membrane feed side in the form of glassy patches and communities of aggregate particles, inhibiting aspirations for zero liquid discharge. Current methods for silica scale mitigation include abundant dosing with chemical antiscalents or complex operating schemes. …

In-Situ Observation And Transport Modelling Of Arsenic In Gangetic Plain, India, Pankaj Kumar Gupta, Pranjay Joshi, Jahangeer

Daugherty Water for Food Global Institute: Faculty Publications

The focus of this study is to investigate the arsenic movement and impacts on the residual concentrations on groundwater pollution load. The Gangetic plain area in the Ballia, Uttar Pradesh is selected as study area, which is also reported to extreme arsenic pollution in soil-water system. A modelling approach is developed to assess the arsenic flux in partially saturated zone using data of soil texture, soil hydraulic properties and stratigraphy. Soil type, slope, and land-use cover is considered for estimating the transient flux at the top boundary from daily precipitation and evapotranspiration data of the study area. Solute transport in …

Co2 Adsorption On Volcanic Ash: Net Contribution Of Volcanic Eruptions To The Global Carbon Cycle, Lee New

Electronic Theses and Dissertations

Adsorption of co2 on mineral surfaces accounts for a small percentage of the terrestrial co2 sink. Volcanic ash is virtually free of co2 when erupted and has a high surface area resulting in a high capacity for co2 adsorption. Volcanism is commonly assumed to be only a source of co2, but pyroclastic eruptions can also potentially serve as a sink. Adsorption was investigated for 6 volcanic ash samples of andesitic composition from four volcanoes: Okmok, Redoubt, Spurr, and Tungurahua. The eruption of volcano redoubt released 0.75 x 109 metric tons of co2 and 55 x 109 kg of ash throughout …

Adsorption Of Antibiotics By Vermiculite, Mosa J. Ferdous

Dissertations and Theses

The occurrence of residual antibiotics in the environment has been a worldwide issue and warrants the development of inexpensive yet effective methods for antibiotics removal from contaminated water. In this thesis work, the adsorption of four antibiotics, namely chlorotetracycline (CTC), oxytetracycline (OTC), ofloxacin (OFL), and enrofloxacin (ENR), onto natural vermiculite has been studied using batch (static) and column (dynamic) adsorption techniques. The Langmuir and Freundlich isotherm models were initially used to explain the adsorption processes. The separation factor (RL) values derived from the Langmuir model and the 1/n values derived from Freundlich model in the present investigation were less than …

Modeling Of Gas Production From Shale Reservoirs Considering Multiple Transport Mechanisms, Chaohua Guo, Mingzhen Wei, Hong Liu

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Gas transport in unconventional shale strata is a multi-mechanism-coupling process that is different from the process observed in conventional reservoirs. In micro fractures which are inborn or induced by hydraulic stimulation, viscous flow dominates. And gas surface diffusion and gas desorption should be further considered in organic nano pores. Also, the Klinkenberg effect should be considered when dealing with the gas transport problem. In addition, following two factors can play significant roles under certain circumstances but have not received enough attention in previous models. During pressure depletion, gas viscosity will change with Knudsen number; and pore radius will increase when …

Comparative Sorption Of Methylene Blue Onto Hydrophobic Clays, Alvaro D. Sponza, Natalia J. Fernandez, David Yang, Karla A. Ortiz, Abel E. Navarro

Publications and Research

Chemical modifications of clay to remove methylene blue (MB) from aqueous solutions at room temperature were compared. Natural bentonite (NC) was modified by cation exchange with hexadecyltrimethylammonium chloride (HC), bencyltriethylammonium chloride (BC), and tetramethylammonium chloride (TC) to reverse the surface polarity of the hydrophilic bentonite. The adsorption of MB was studied and fitted by the adsorption theories of Langmuir, Freundlich, Dubinin-Radushkevich, and Temkin. Equilibrium parameters were calculated, indicating that chemical modification did not improve the adsorption, due to the electrostatic adsorption mechanism. Specific surface area was determined, reporting the following trend: NC > TC > BC > HC. Isotherms show that TC is …

Rice Husk Derived Engineered Biochar For Glyphosate Removal In Aqueous Media, Indika Herath Mr

21st International Conference on Environmental Indicators (ICEI 2015)

No abstract provided.

Kinetic And Thermodynamic Studies On Adsorption Of Copper (Ii) Ions Onto The Olive Pomace Lignocellulosic In The Region Of Beni Mellal (Morocco), Aziz Menichi, Abdeslam Chagraoui, Abdenajib Moussaoui

21st International Conference on Environmental Indicators (ICEI 2015)

No abstract provided.

Ion Interactions At The Mineral-Water Interface During Biogeochemical Iron And Manganese Cycling, Margaret A. G. Hinkle

Arts & Sciences Electronic Theses and Dissertations

The biogeochemical cycling of iron and manganese involves the reductive dissolution and oxidative precipitation of Fe(III) and Mn(IV/III) oxides. Biogenic Fe(III) and Mn(IV/III) oxides are often characterized by high surface areas and therefore high sorptive capacities. As a result, these minerals can substantially alter the chemistry of natural waters and the availability of micronutrients in soils and sediments by scavenging trace metals. Recent research indicates that the adsorption of aqueous Fe(II) onto Fe(III) oxides involves oxidative adsorption, electron transfer, and subsequent reductive dissolution at another surface site [a process collectively referred to as `electron transfer-atom exchange' (ET-AE)]. Aqueous Mn(II) adsorption …

Chemodynamics Of Chromium Reduction In Soils: Implications To Bioavailability, Girish Choppala, Nanthi Bolan, Belaji Seshadri

Dr Girish Choppala

Chromium toxicity in soils can be mitigated by reduction of Cr(VI) to Cr(III) which is influenced by the presence of free Cr(VI) species in soil solution, and the supply of protons and electrons. In this study, the effects of Cr(VI) adsorption (i.e. availability of free Cr(VI) species in soil solution), soil pH (i.e. supply of protons) and three electron donor carbon sources [black carbon (BC), chicken manure biochar (CMB) and cow manure (CM)] on the reduction of Cr(VI) to Cr(III) in soils were investigated. The results indicated that the rate of Cr(VI) reduction decreased with an increase in Cr(VI) adsorption …

The Interaction Between Arsenic And Struvite During Coprecipitation And Adsorption Processes, Ning Ma

Dissertations, Theses, and Capstone Projects

The formation of struvite, MgNH4PO4*6H2O (MAP), from wastes is one of the methods that can be used to recover P from wastes efficiently. However, since there are usually toxic components in the wastes, like arsenic (As), the possibility of having toxic contaminants in MAP is a big concern. So, the interaction between As and MAP during coprecipitation (CPT) and adsorption (ADS) processes were studied at pH 8-11. MAP precipitated without As at pH 8-11 was also characterized.

During CPT process, the MAP was precipitated from a MgCl2-(NH4)2HPO4-NaCl-H2O system spiked with As at an initial pH (pHi) of 8-11. The batch …

Simultaneous Adsorption Of 11 Volatile Organic Compounds By An Activated Carbon Made From Polystyrene Sulfonic Acid-Based Organic Salt, Alejandro Smith

Dissertations and Theses

Activated carbon is used in water treatment worldwide due to its ability to adsorb many different contaminants from water. The high adsorption capacity of activated carbon is linked to its high internal surface area and micro/meso- porosity. In this work an activated carbon obtained from polystyrene sulfonic acid-based organic salt was examined to simultaneously adsorb eleven volatile organic compounds from aqueous solution. Adsorption data were modeled with different isotherms to determine the equilibrium adsorptive capacities for these compounds. The performance of the polymer-based activated carbon was then compared with that of a commercial wood-based activated carbon. The results indicate that …

Zn(Ii) And Cu(Ii) Adsorption And Retention Onto Iron Oxyhydroxide Nanoparticles: Effects Of Particle Aggregation And Salinity, Rebecca B. Chesne, Christopher S. Kim

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Background: Iron oxyhydroxides are commonly found in natural aqueous systems as nanoscale particles, where they can act as effective sorbents for dissolved metals due to their natural surface reactivity, small size and high surface area. These properties make nanoscale iron oxyhydroxides a relevant option for the remediation of water supplies contaminated with dissolved metals. However, natural geochemical processes, such as changes in ionic strength, pH, and temperature, can cause these particles to aggregate, thus affecting their sorption capabilities and remediation potential. Other environmental parameters such as increasing salinity may also impact metal retention, e. g. when particles are transported …

Adsorption Behavior Of Glucose On Pyrite Surface Investigated By Tg, Ftir And Xrd Analyses, Zhaohui Wang, Xuehui Xie, Shengmu Xiao, Jianshe Liu

Dr Zhaohui Wang

The interaction of glucose with pyrite has been investigated by a series of surface analyses, such as amounts adsorbed, TG, FTIR and XRD measurements. The adsorption experiment reveals that glucose would rapidly adsorb on the pyrite surface within 60 min. However, physical adhesion characterized as multi-molecular layer adsorption may occur based on adsorption isotherm type. All results obtained by TG and FTIR suggest that no adsorption took place after several times of washing. XRD results indicate that crystal structure of pyrite was not obviously destructed after glucose was added. The interplane distances of (111), (400) after interaction between glucose and …