Earth Sciences Commons^™

Biodegradation Of Bisphenol-A And 17b-Estradiol In Soil Mesocosms Under Alternating Aerobic/Anoxic/Anaerobic Conditions, Won-Seok Kim

USF Tampa Graduate Theses and Dissertations

Soil-aquifer treatment (SAT) has been proposed as a method for reusing treated municipal wastewater. SAT is characterized by alternating cycles of aerobic and anaerobic conditions in the subsurface, in response to alternating cycles of flooding and drainage of a surface impoundment. It is not yet known how these alternating redox conditions affect the removal of potentially harmful endocrine-disrupting compounds (EDCs) from treated effluent.

The overall objective of my doctoral research is to determine the fate of EDCs in alternating aerobic/anoxic/anaerobic conditions under simulated SAT conditions. To assess the fate of EDCs in simulated SAT conditions, I first had to develop …

High-Resolution Event Stratigraphy Of Mm-Scale Laminated Sediments From Coastal Salt Ponds: St. John, Us Virgin Islands, Rebekka Amie Larson

USF Tampa Graduate Theses and Dissertations

A multi-proxy approach is utilized on mm- to cm-scale laminated sediment records in coastal salt ponds on St. John, U.S. Virgin Islands to characterize the sediments, identify their sources and depositional processes/events (heavy rainfall, tropical cyclones, tsunamis). Historical records are combined with high-resolution geochronology (short-lived radioisotopes, ²¹⁰Pb, ¹³⁷Cs, ⁷Be) and scanning elemental techniques (XRF and LA-ICP-MS) to link depositional events to how they are manifested in the sedimentary record. Volcanic rocks are the terrigenous sediment source and the sedimentary signature of terrigenous sediment in the geologic record consists of higher amounts of Al, Fe, Ti, Co, and …

Impacts Of Artificial Reefs On Surrounding Ecosystems, Sarine Manoukian

USF Tampa Graduate Theses and Dissertations

Artificial reefs are becoming a popular biological and management component in shallow water environments characterized by soft seabed, representing both important marine habitats and tools to manage coastal fisheries and resources. An artificial reef in the marine environment acts as an open system with exchange of material and energy, altering the physical and biological characteristics of the surrounding area. Reef stability will depend on the balance of scour, settlement, and burial resulting from ocean conditions over time. Because of the unstable nature of sediments, they require a detailed and systematic investigation.

Acoustic systems like high-frequency multibeam sonar are efficient tools …

A Sedimentary Record Of Regional Land-Use And Climate Change In The Manatee River, Manatee County, Florida, Patrick Schwing

USF Tampa Graduate Theses and Dissertations

The Manatee River Watershed (Manatee County, FL) has experienced heavy anthropogenic development over the last 100 years and was relatively pristine previous to this development. The population growth within the watershed has surpassed the national trends and has doubled in the last 30 years. The heavy anthropogenic development has led to depletion in natural resources, nutrient loading, coastal erosion, and increased pollution. This study constructs records of sedimentological processes to compare the pre-development records to the past 100 years of anthropogenic development. The first portion of this study identifies specific changes in sedimentation attributed to anthropogenic activity in the Manatee …

Late Cretaceous Faunal Dynamics In The Western Interior Seaway: The Record From The Red Bird Section, Eastern Wyoming, Joshua Stephen Slattery

USF Tampa Graduate Theses and Dissertations

Studies examining bioevents (e.g., mass extinctions, faunal turnovers, diversification events) usually only scrutinize a short interval prior to such events, however, understanding their actual paleobiological implications requires a thorough understanding of the background conditions. The objective of this study is to document the background biodiversity dynamics in a single lithofacies of the Upper Cretaceous Pierre Shale that was deposited in an offshore setting of the Western Interior Seaway (WIS) and to place these changes into an environmental context. To assess the background biodiversity dynamics, the concretionary faunas of the Baculites eliasi through B. clinolobatus biozones of the Pierre Shale in …

Modeling Direct Runoff Hydrographs With The Surge Function, Denis Voytenko

USF Tampa Graduate Theses and Dissertations

A surge function is a mathematical function of the form f(x)=ax^pe^-bx. We simplify the surge function by holding p constant at 1 and investigate the simplified form as a potential model to represent the full peak of a stream discharge hydrograph. The previously studied Weibull and gamma distributions are included for comparison. We develop an analysis algorithm which produces the best-fit parameters for every peak for each model function, and we process the data with a MATLAB script that uses spectral analysis to filter year-long, 15-minute, stream-discharge data sets. The filtering is necessary to locate the …

Alternative Statistical Methods For Analyzing Geological Phenomena: Bridging The Gap Between Scientific Disciplines, Joseph Frank Van Gaalen

USF Tampa Graduate Theses and Dissertations

When we consider the nature of the scientific community in conjunction with a sense of typical economic circumstances we find that there are two distinct paths for development. One path involves hypothesis testing and evolution of strategies that are linked with iterations in equipment advances. A second, more complicated scenario, can involve external influences whether economic, political, or otherwise, such as the government closure of NASA's space program in 2011 which will no doubt influence research in associated fields. The following chapters are an account of examples of two statistical techniques and the importance of both on the two relatively …

Urbanization And Land Surface Temperature In Pinellas County, Florida, Bruce Coffyn Mitchell

USF Tampa Graduate Theses and Dissertations

Since the early 1800's, many studies have recognized increased heat in urban areas, known as the urban heat island (UHI) effect, as one of the results of human modification to the natural landscape. UHI is related to differences in land surface temperature (LST) between rural areas and urban areas where factors of the built environment such as the thermodynamic capacities of materials, structural geometry, and heat generating activities cause increased storage and re-radiation of heat to the atmosphere. This thesis examines the correlation between factors of urbanization and differences in land surface temperature (LST) in the subtropical climate of Pinellas …

Seasonal Changes In The Sinking Particulate Flux And In The Nitrogen Cycle Within The Euphotic And Twilight Zones Of The Cariaco Basin, Venezuela, Enrique Montes-Herrera

USF Tampa Graduate Theses and Dissertations

This study explored the effects of seasonal variability on the geochemistry of sinking pthesiss and on the nitrogen cycle of the Cariaco Basin. Pthesis fluxes were measured at the base of the euphotic zone (the depth of 1% of photosynthetically active radiation - PAR) with drifting sediment traps during months of upwelling and non-upwelling regimes from March 2007 to November 2009. Flux estimates were analyzed in the context of seasonal variations in sea surface temperature, primary productivity, and chlorophyll a concentrations using data generated by the CARIACO Time-series Program as well as satellite data. Additionally, nine years (1996-2000 and 2004-2007) …

Stable Isotope Studies Of Paleoenvironment And Paleoclimate From Afar, Ethiopia, Zelalem K. Bedaso

USF Tampa Graduate Theses and Dissertations

The sedimentary deposits of the Hadar Formation at Dikika and the Mount Galili Formation at Galili preserve a wealth of paleoenvironmental and paleoclimatic records spanning the last 5.29 Ma. Stable carbon and oxygen isotopic compositions of herbivore tooth enamel were analyzed for more than 600 specimens of 15 different taxa from 10 stratigraphic intervals. The application of carbon and oxygen isotopes here aims principally at reconstructing shifts in the relative abundance of C₄ grasses, and its implications for climate indicators including temperature, aridity, and seasonality. The full range of δ¹³C_enamel values throughout the Plio-Pleistocene signifies a …

First Year Sedimentological Characteristics And Morphological Evolution Of An Artificial Berm At Fort Myers Beach, Florida, Katherine Brutsche

USF Tampa Graduate Theses and Dissertations

Dredging is often conducted to maintain authorized depths in coastal navigation channels. Placement of dredged sediment in the form of nearshore berms is becoming an increasingly popular option for disposal. Compared to direct beach placement, nearshore berms have fewer environmental impacts such as shore birds and turtle nesting, and have more lenient sediment compatibility restrictions. Understanding the potential morphological and sedimentological evolution is crucial to the design of a nearshore berm. Furthermore, the artificial perturbation generated by the berm installation provides a unique opportunity to understand the equilibrium process of coastal morphodynamics.

Matanzas Pass and Bowditch Point, located on the …

Geochemical Systematics Among Amphibolitic Rocks In The Central Blue Ridge Province Of Southwestern North Carolina, Nathan Collins

USF Tampa Graduate Theses and Dissertations

The Central Blue Ridge sub-province of the southern Appalachian Mountains preserves an unique and complex geologic history. The Cartoogechaye terrane is the westernmost terrane of the Central Blue Ridge sub-province, and is characterized by extensive olistostromal sequences, including mafic-ultramafic massifs, isolated mafic units, and block-in-matrix structures of varying scales. This study investigates the genetic and tectonic relationships, and regional chemical and metamorphic trends of the amphibolitic rocks entrained within units of the Cartoogechaye and nearby terranes, toward constraining the origins of these regional sequences, and examining the rationale for the current Blue Ridge terrane designations.

A distinct compositional variation exists …

Modern Variation In Predation Intensity: Constraints On Assessing Predator-Prey Relationships In Paleoecologic Reconstructions, James Funderburk

USF Tampa Graduate Theses and Dissertations

The complex interaction between predators and their prey is rarely preserved in the fossil record. However, predation of marine mollusks by drilling gastropods leaves a diagnostic hole in the shell of the prey, possibly allowing for quantitative analysis of this ecological interaction. Drilling frequency, as measured in marine mollusks both in the Modern and fossil record, has been heralded as a potential opportunity to quantify these ecological interactions and use these values in the testing of hypotheses.

This study employed the collection, tallying, and analysis of bulk samples derived from shelly deposits on 45 Modern beaches along the contiguous coast …

Variable-Density Flow Models Of Saltwater Intrusion In Coastal Landforms In Response To Climate Change Induced Sea Level Rise And A Chapter On Time-Frequency Analysis Of Ground Penetrating Radar Signals, Swagata Guha

USF Tampa Graduate Theses and Dissertations

Populations residing on and near the world’s coasts have become increasingly dependent on coastal groundwater for their supply of freshwater. Under the conditions of predicted climate changes, the expected rise in global sea level can adversely affect the quality and quantity of freshwater resources in coastal areas as a result of saltwater intrusion.

In this study, a suite of two- and three-dimensional variable-density groundwater flow models of major coastal landforms (e.g. deltas, estuaries and small islands) has been constructed to assess the effects of sea level rise (SLR), using different SLR rates of 0.5 m, 1m and 1.5 m over …

Why We Do It – The University Of South Florida Tampa Library’S Commitment To Open-Access Publishing, Todd A. Chavez

Academic Resources Faculty and Staff Publications

The University of South Florida Tampa Library's support for open-access content is part of the organization's mission to advance scholarly communication generally and an important element of the Karst Information Portal initiative. As the costs associated with journal subscriptions increase and pressures to ensure unfettered access to high-quality, peer-reviewed research mount, research libraries must partner with scholars to establish sustainable open-access publishing models.

Superior Karst Management Through Superior Data Management: The Karst Information Portal, E. Spencer Fleury, George H. Veni, Todd A. Chavez, Penelope J. Boston, Diana E. Northup, H. Len Vacher, Pat Seiser

Academic Resources Faculty and Staff Publications

Effective stewardship of caves and karst areas requires access to and efficient analysis of a diverse range of information. Vital data are scattered throughout specialty mainstream journals, which even for a single project could include fields such as ecology, hydrogeology, contaminant transport, toxicology, engineering geology and law. Additionally, volumes of crucial information often lie in diffi­cult-to-find gray literature. Management recommendations and decisions should be based on assessments of state-of-the-art information, but fall short when im­portant patterns and relationships are overlooked.

The Karst Information Portal (KIP) offers a solution to these problems. Con­ceived in 2005 and launched in June 2007, KIP …

Cost/Effectiveness Analysis Of Obtaining Operational Estimates Of Reference Evapotranspiration, Peninsular Florida, Usa, Michael G. Kittridge

USF Tampa Graduate Theses and Dissertations

The objective of this study is to conduct a cost/effectiveness analysis of the computation of reference evapotranspiration (ETo) in the peninsular of Florida. A meteorological station on the Fort Meade Mine in Polk County, Florida was used to provide data for the calculation of ETo. Five ETo equations were tested to determine the accuracy and cost/effectiveness to the fully measured ASCE Penman-Monteith (Full ASCE-PM) equation on daily, monthly, and annually time steps. The ETo equations ranged in amounts of parameters from the Full ASCE-PM to the Hargreaves. The energy terms accounted for approximately 90% of the total ETo flux. Solar …

Hydrostratigraphy And Groundwater Migration Within Surficial Deposits At The North Lakes Wetland, Hillsborough County, Florida, Jason J. Laroche

USF Tampa Graduate Theses and Dissertations

A wetland in west-central Florida was studied to characterize the local hydrostratigraphic configuration of surficial deposits overlying more-permeable limestones and conceptualize groundwater recharge. Eight continuous cores were drilled through the surficial deposits and partially into the underlying limestone. A total of 111 samples were extracted from the cores for laboratory sediment analyses and testing. The surficial deposits are roughly eight meters thick and made up of upper and lower clean-sand hydrostratigraphic layers (S1 and S3, respectively) separated by a low-permeability layer of clayey sand (S2). Also, a discontinuous low-permeability layer of clayey sand (S4) lies between S3 and the top …

Climatic And Structural Controls On The Geomorphology Of Wadi Sana, Highland Southern Yemen, Joshua Michael Anderson

USF Tampa Graduate Theses and Dissertations

Middle Holocene climate change forced significant environmental response and influenced human activities throughout southern Arabia. Climate models and proxy data indicate that climate along the southern Arabian peninsula changed from a moist phase, spanning the early to middle Holocene, to an arid phase, which persisted for the last ca. 5,000 years. A weakening and southward shift of the Southwest Indian Monsoon System, forced by northern hemisphere insolation variations in the precession band and/or glacial boundary conditions, is suggested as the mechanism for the abrupt shift to more arid conditions. Geoarchaeological evidence suggests that agriculture was more widespread and evolved alongside …

Influence Of Evapotranspiration On Patterns Of Ground-Water Conductivity In Small Basins, Ana Jiménez

USF Tampa Graduate Theses and Dissertations

Ground-water conductivity data were obtained from shallow wells in a 12 km2 stream-basin along a 400 m transect, extending from the divide to the stream. The stream, Pringle Branch, is a second-order perennial stream in Hillsborough County, Florida. The shallow stratigraphy consists of 2-3 m of fine sand over a layer of clayey silt and silty clay. Vegetation cover includes grasses on the upper and middle slope, and riparian woodlands on the foot slope and floodplain. Precipitation is about 1.3 m per year. Shallow ground-water conductivity is about 50 uS/cm at the divide. It increases moderately along the mid slope, …

The Impact Of Grey Literature In Advancing Global Karst Research: An Information Needs Assessment For A Globally Distributed Interdisciplinary Community, Todd A. Chavez, Anna H. Perrault, Pete Reehling, Courtney Crummett

Academic Resources Faculty and Staff Publications

A survey of the global karst community was conducted in 2006. The survey was distributed via the World Wide Web to known karst researchers. The instrument was designed to generate an initial inventory of core grey information types, to assess levels of usage of grey information by the respondents, and to gauge the karst community’s willingness to participate in building and expanding both this collection and the associated controlled vocabularies.

Geophysical Investigations And Groundwater Modeling Of The Hydrologic Conditions At Masaya Caldera, Nicaragua, Richard Eric Macneil

USF Tampa Graduate Theses and Dissertations

Masaya volcano, Nicaragua, has been the site of tremendous Plinian basaltic eruptions. Two eruptions ~6,500 and 2,250 BP formed the 6 kilometer (km) x 11 km, northwest trending Masaya caldera. The present day active Santiago Crater within the caldera is the site of persistent volcano degassing and occasional phreatic explosions. While the mechanism responsible for these phreatic explosions is unclear, one possible explanation is the interaction of groundwater with the shallow magma chamber beneath Masaya. This interaction with meteoric water is supported by the substantial steam discharge from the vent, which is significantly larger than other similar volcanoes in the …

Evaluation Of Geophysical And Thermal Methods For Detecting Submarine Groundwater Discharge (Sgd) In The Suwannee River Estuary, Florida, Matthew Weiss

USF Tampa Graduate Theses and Dissertations

Submarine groundwater discharge (SGD) represents a significant portion of the total discharge from coastal aquifers through diffuse seepage and point source springs, but can be difficult to locate. SGD is important as it can be a source of nutrients to estuaries and other coastal ecosystems. In an effort to evaluate geophysical and thermal methods for detecting SGD on the Florida Gulf coast, a suite of water-borne surveys were run in conjunction with aerial thermal imagery over the lower Suwannee River and estuary in March and September 2005. Thermal imagery exploits temperature differences between discharging groundwater and surface water. Thermal images …

The Reflection Of Karst In The Online Mirror: A Survey Within Scientific Databases, 1960-2005, Lee J. Florea, Beth Fratesi, Todd A. Chavez

Academic Resources Faculty and Staff Publications

The field of cave and karst science is served by a literature that is dispersed across far-flung topical journals, government publications, and club newsletters. As part of an inter-institutional project to globalize karst information (KIP, the Karst Information Portal), the USF Library undertook a structured battery of literature searches to map the domain of karst literature. The study used 4,300 individual searches and four literature databases: GeoRef, BIOSIS, Anthropology Plus, and GPO Access. The searches were based on a list of 632 terms including 321 karst-related keywords culled from three leading encyclopedias and glossaries of cave and karst science. An …