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Full-Text Articles in Polymer Chemistry
The Synthesis And Application Of Polyglyoxylamides, Quinton Ea Sirianni
The Synthesis And Application Of Polyglyoxylamides, Quinton Ea Sirianni
Electronic Thesis and Dissertation Repository
Self-immolative polymers (SIPs) are a subset of degradable polymers that can be triggered to fully depolymerize with a single stimulus event. This amplifying behaviour makes them ideal for real-world applications including sensors, recyclable plastics, and drug delivery vehicles. Polyglyoxylates (PGs) are a class of SIPs that can be synthesized in a one-pot reaction and designed to respond to different stimuli including light, heat, reduction, and oxidation. However, with the exception of poly(ethyl glyoxylate) (PEtG), the various glyoxylate monomers must be prepared and purified before polymerization, which can be difficult. Furthermore, PGs typically possess properties such as water-insolubility and low glass …
Self-Immolative Polymers As A Degradable And Triggerable Class Of Surfactants, Siamak Keshtpour
Self-Immolative Polymers As A Degradable And Triggerable Class Of Surfactants, Siamak Keshtpour
Electronic Thesis and Dissertation Repository
Self-immolative polymers (SIPs) are degradable polymers that undergo end-to-end depolymerization upon triggering. They have potential for the development of degradable surfactants addressing human and environmental toxicity concerns associated with non-degradable surfactants, but they have not yet been investigated as surfactants. Herein, polyglyoxylamide SIPs with different pendent groups and end-caps were synthesized, envisioning they could serve as depolymerizable analogues of poly(vinyl alcohol) and its derivatives. Polyglyoxylamides with pendent hydroxyls stabilized both PEA and PLA particle suspensions. They showed the potential to undergo triggered degradation, resulting in destabilization of the suspensions. However, untriggered suspensions exhibited poor long-term stability, so further structural tuning …
Plant Stimuli-Responsive Biodegradable Polymers For The Use In Timed Release Fertilizer Coatings, Spencer Heuchan
Plant Stimuli-Responsive Biodegradable Polymers For The Use In Timed Release Fertilizer Coatings, Spencer Heuchan
Electronic Thesis and Dissertation Repository
The use of nitrogen-based fertilizers continues to accelerate with human population growth and increases in global food requirements. Enhanced efficiency fertilizers (EEFs) have been developed to improve the synchronization between nutrient supply and crop nutrient demand. However, many of the current controlled release fertilizers are coated with non-degradable polymers that contribute to accumulation of microplastics within ecosystems. This thesis describes research towards the development of a new class of fertilizer coatings using a self-immolative polymer known as poly (ethyl glyoxylate) (PEtG). PEtG itself does not have suitable properties to produce a viable coating but once blended with another degradable polyester …