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Physical Chemistry Commons

Open Access. Powered by Scholars. Published by Universities.®

2010

Nicholas Whiting

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Full-Text Articles in Physical Chemistry

Interdependence Of In-Cell Xenon Density And Temperature During Rb/129xe Spin-Exchange Optical Pumping Using Vhg-Narrowed Laser Diode Arrays, Nicholas Whiting, Panayiotis Nikolaou, Neil A. Eschmann, Michael J. Barlow, Boyd M. Goodson Dec 2009

Interdependence Of In-Cell Xenon Density And Temperature During Rb/129xe Spin-Exchange Optical Pumping Using Vhg-Narrowed Laser Diode Arrays, Nicholas Whiting, Panayiotis Nikolaou, Neil A. Eschmann, Michael J. Barlow, Boyd M. Goodson

Nicholas Whiting

The 129Xe nuclear spin polarization (PXe) that can be achieved via spin-exchange optical pumping (SEOP) is typically limited at high in-cell xenon densities ([Xe]cell), due primarily to corresponding reductions in the alkali metal electron spin polarization (e.g. PRb) caused by increased non-spin-conserving Rb–Xe collisions. While demonstrating the utility of volume holographic grating (VHG)-narrowed lasers for Rb/129Xe SEOP, we recently reported [P. Nikolaou et al., JMR 197 (2009) 249] an anomalous dependence of the observed PXe on the in-cell xenon partial pressure (pXe), wherein PXe values were abnormally low at decreased pXe, peaked at moderate pXe (~300 torr), and remained surprisingly …