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Physical Chemistry Commons

Open Access. Powered by Scholars. Published by Universities.®

2010

Air Force Institute of Technology

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Full-Text Articles in Physical Chemistry

Calculation Of Collisional Cross Sections For The ²P3/2 > ²P1/2 Transition In Alkali-Noble Gas Systems, Samuel D. Butler Mar 2010

Calculation Of Collisional Cross Sections For The ²P3/2 > ²P1/2 Transition In Alkali-Noble Gas Systems, Samuel D. Butler

Theses and Dissertations

Collisional cross sections were calculated as a function of energy for two coupled one dimensional, spherically symmetric potentials. The Split Operator Method was used to propagate an initial Moller state, chosen to be a Gaussian in the asymptotic limit, through a potential. The correlation between the wave packet and Moller final state was calculated at each time step. Using the Channel Packet Method, the correlation function was used to obtain scattering matrix elements. From scattering matrix elements for several different effective potential values and using the Method of Partial Waves, the collisional cross section is calculated for the transition from …